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Former Town& Country Chevron, -2- ' ' _ _ a - 2/11198 <br /> San Joaquin County •.. rN� <br /> xylene. Therefore, water in the vadose zone is leaching contamination from the soil at 7.5 to 9.0 ft bgs," <br /> and spreading the contamination.to,16 ft bgs where it is reabsorbed onto ihe'soil above detectable levels. <br /> The soil data show a definite decreasing trend in the concentration of contaminants from the waste oil <br /> tank..Measurable amounts of petroleum contaminants probably occur in this water at depths greater than <br /> 16 ft bgs. However, the concentration of contaminants is too low to be absorbed onto the soil in 1 <br /> measurable amounts- Therefore,the concentration in the vadose zone water is probably too low to <br /> impact ground water(70 to 100 ft bgs). ` <br /> Soil samples were collected from the bottom of the gasoline tank excavation atk13 ='1'4 ft bgs, and at 5 ft <br /> intervals while advancing the borings. The analytical results of these samples shows that contaminated <br /> soil remains from 13 ft bgs to greater than 26 ft bgs.-At the bottom of the gasoline tanks, soil samples <br /> had an average concentration of 553 mg/kg TPH-g, 0.42 rng/kg benzene, 7.98 mg/kg_ toluene, 2.56 <br /> mg/kg ethylbenzene, and 34.$0 mg/kg xylene.,,The samples were nondetect for,lead and ethylene <br /> dibromide.- At 20 ft bgs contamination:varies from nondetect to.3,200 mg/kg TPH-g, 0.005 - 6.7 mglkg <br /> benzene,nondetect to 32 mg/kg toluene,non detect to 58 mg/kg ethylbenzene, and 0.008 -,220 mg/kg <br /> xylene. The concentration of petroleum contaminants increases with depth within the sandy clay bed. ; <br /> One soil sample, collected from boring B-1 in the clayey sand layer at 29 ft bgs had 2.3 mg/kg TPH-g, <br /> 0.49 mg/kg benzene, 0.074 mg/kg toluene, 0.066 mg/kg ethylbenzene, and 0.24 mg/kg xylene. The <br /> increase in the concentration of contamination within the sandy clay bed at depth, indicates the original <br /> contamination may.have extended through this clay bed to an unknown depth within the vadose zone or <br /> to the water table. Because petroleum contaminants do not adhere to sand and silt as readily as clay, <br /> water percolating through the vadose zone would leach the petroleum contaminates from the sand and <br /> silt beds more readily than from the.clay bed. This is possibly the reason the soil sample from the clayey <br /> sand bed showed a significant decrease in the concentration of petroleum contaminants. Yet, significant <br /> contamination may remain in deeper deposits where petroleum contaminants may have been absorbed <br /> onto the surface of the "saprolitic"bed or migrated through fractures in this bed and contaminated the <br /> groundwater. <br /> Conclusions: The extent of soil contamination beneath the waste oil tank has been determined. Soil <br /> contamination was detected in the deepest analyzed samples from borings, B-1 and B-5, and the <br /> concentration of contamination increases with depth within the.sandy clay.bed.. Therefore,the extent of <br /> _ _ .- _ - - - -- - i <br /> contamination was-not determined beneath the gasoline tanks. , <br /> Recommendations: The lateral and vertical extent of contamination needs to be determined beneath the <br /> gasoline tanks. Additional soil samples should be collected at 5 ft intervals or at lithologic changes from <br /> the depth of the last petroleum contaminated sample through the "saprolitic"bed. These samples should <br /> be analyzed for petroleum contaminants to determine the vertical extent of contamination. If water is <br /> i <br /> not encountered, a computer,model (ex. VLEACH or SESOIL) and.Waste Extraction Test (WET) or <br /> Toxicity Characteristic Leaching Procedure (TCLP)tests analyses are needed to determine the w <br /> probability this contamination will impact groundwater..If water is encountered, samples should be <br /> collected and analyzed.for petroleum contaminants including methyl tertiary-butyl ether(MTBE_ ) and the <br /> other oxygenates using EPA Method 8260. This additional information is required to calculate the mass <br /> of contamination remaining on-site. ~ W.•. L., <br />