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Musco Family Olive Company - 18 - 12 December 2006 <br /> Staff's evaluation of on-site constitutent occurrences is discussed above. The Report <br /> evaluates well MW-1, MW-3, MW-5, MW-11, MW-13 through MW-16, and W-2. The primary <br /> COCs evaluated are TDS, chloride, and sodium. Many of the wells discussed in the Report <br /> indicate increasing trends of COCl: Wells MW-1, MW-3, MW-5, MW-14, MW-16, and W-2. <br /> Those with no significant changes in COCs were MW-11, MW-13, and MW-15. The Report <br /> does not offer any explanation of the elevated concentrations of several constituents in the <br /> wells and fails to address the issue of long-term degradation of groundwater due to spray <br /> irrigation. The Report does not address the fact that Musco has been land applying high <br /> strength wastewater to their fields since at least 1991, which has elevated the COCs in <br /> groundwater above background groundwater concentrations. <br /> The Report identifies well MW-1 with increasing trends of COCs that cannot be explained <br /> without up-gradient data_ When the Time Series Plot and TDS plot of MW-1 are reviewed it <br /> appears that concentrations of COCs were initially low. However, as the well was purged and <br /> sampled over time and more formation water was brought into the well, the COCs began to <br /> rise sharply as indicated in the plots. It is staff's opinion the Reports explanation is invalid and <br /> an approximate 800 mg/L increase in TDS from early 2002 to mid-2003 is not representative <br /> of natural background conditions. The Report does not mention impacts of groundwater by <br /> spray irrigation as a possible source of contaminants to well MW-1. <br /> The Report discusses increasing trends in wells MW-3, MW-5, MW-14, MW-16, and W-2. <br /> The Report's discussion provides little understanding as to the source of constituents detected <br /> in groundwater. It provides no comparison to groundwater outside the impact zone nor does it <br /> look at other possible constituents such as bicarbonate as a chemical signature of wastewater. <br /> According to the Report, wells MW-11, MW-13, and MW-15 show no significant changes over <br /> time. Again, the Report's only focus is on the constituent trend and not the elevated TDS, <br /> chloride, and sodium concentrations and provides no explanation for the elevated <br /> concentrations in groundwater. It makes no comparison to offsite groundwater quality nor <br /> does it look at other possible constituents such as bicarbonate as a chemical signature of <br /> wastewater_ <br /> Groundwater quality was also evaluated by plotting isoconcentration maps for the COCs <br /> detected in the shallow/intermediate zones (as one) and deep zone. Upon review of the <br /> primary COCs (TDS, chloride, and sodium) isoconcentration maps, it is evident'that elevated <br /> concentrations exist in groundwater. The Report suggests these concentration levels are <br /> "both naturally occurring and some of them are detected in the process water." However, the <br /> Report does not provide any information of naturally occurring concentrations or background <br /> water quality. The isoconcentration maps indicate elevated concentrations of CDCs in a <br /> pattern that stretches from the uplands to the lowlands. Based upon review of the June 2006 <br /> Potentiometric map, the shallow groundwater flow is not completely defined offsite, and <br /> although the current wells appear to have elevated COCs, the current well network is <br /> inadequate for defining the limits of the contaminants. <br /> The Reports overall theme concerning constituents of concern is that the swale funnels <br /> groundwater and is holding the CDCs, allowing them to buildup over time. The Report asserts <br /> that background concentrations are more accurately defined as "ambient concentrations. <br /> "Ambient concentrations include both naturally occurring constituents in aquifers and changes <br />