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<br /> MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br /> Asana XL Insecticide possible- Call a poison control center or doctor for pilot lights,cigarettes and tum off other sources of ig-
<br /> M0000191 further treatment advice. Witton prior to use and until all vapors are gone. Do
<br /> Revised 07-01-02 IF IN EYES:Hold eye open and rinse slowly and gently I not cut,drill,grind or weld on or near container: even
<br /> j with water for 15-20 minutes. Remove contact lenses, I emptied containers can contain explosive vapors.
<br /> CHEMICAL PRODUCT/COMPANY IDENTIFICA- if present,after the first 5 minutes,then continue rinsing Personal Protective Equipment
<br /> TION eye.Call a poison control center or doctor for treatment Some materials that are chemical-resistant to this prod-
<br /> Material Identification advice. uct are listed below. If you want more options,follow
<br /> e. "Asana"is a registered trademark of DuPont. IF ON SKIN OR CLOTHING:Take off contaminated the instructions for category E on an EPA chemical
<br /> Corporate MSDS Number: D0002101 clothing. Rinse skin immediately with plenty of wa- I resistance category selection chart.
<br /> Company Identification ter for 15-20 minutes. Call a poison control center or Applicators and other handlers must wear:
<br /> doctor for treatment advice.
<br /> MAN UFACTURER/DISTRIBUTOR Have the product container or label with you when Long-sleeved shirt and pants
<br /> DuPont calling a poison control center or doctor,or going for Chemical-resistant gloves, such as Barrier Laminate
<br /> ,
<br /> 1007 Market Street or Neoprene Rubber or Nitrile Rubber or Viton.
<br /> Wilmington, DE 19898 treatment. You may also contact 1-800-441-3637 for
<br /> 9 emergency medical treatment information. Shoes plus socks
<br /> PHONE NUMBERS Notes to Physicians i Protective eyewear
<br /> Product Information: 1-800-441-7515(outside the U.S.
<br /> 302-774-1000) NOTE TO PHYSICIAN: If on skin,after drying apply Discard clothing or other absorbent materials that have
<br /> Transport Emergency: CHEMTREC 1-800-424-9300 vitamin E cream or oil if available. If not available, been drenched or heavily contaminated with this prod-
<br /> apply vegetable oil liberally over painful areas. The uct's concentrate. Do not reuse them. Follow manu-
<br /> (outside U.S.703-527-3887) oil or cream may be used repeatedly until relief is facturer's instructions for cleaning/maintaining PPE. If
<br /> Medical Emergency: 1-800-441-3637(outside the U.S. achieved. no such instructions for washables,use detergent and
<br /> 302-774-1000) hot water. Keep and wash PPE separately from other
<br /> COMPOSITIONIINFORMATION ON INGREDIENTS FIRE FIGHTING MEASURES laundry.
<br /> Flammable Properties PPE required for early entry to treated areas that is per-
<br /> Components Flash Point: 66 C(151 F) miffed under the Worker Protection Standard and that
<br /> Method: TCC involves contact with anything that has been treated,
<br /> Material CAS Number y Combustible. Heating can release vapors which can such as plants,soil,or water,is:
<br /> ESFENVALERATE 66230-04-4 6,4 jbe ignited. Coveralls
<br /> ((S)-CYANO(3-PHENOxYPHENYL)METHVI(S)- HaZardOUS gases/vapors produced in fire are toxic and Chemical-resistant gloves, such as Barrier Laminate
<br /> r. 4-CHLORO-ALPHA-(1-%nETHYLETHYL) may include hydrogen cyanide. or Neoprene Rubber or Nitrile Rubber or Viton.
<br /> BENZENEACETATE) Extinguishing Media Shoes plus socks
<br /> INERT INGREDIENTS 91.6 Water Spray,Water Fog,Dry Chemical,CO2. p
<br /> (INCLUDES PERCENTAGES OF Fire Fighting Instructions Protective eyewear
<br /> THE FOLLOWING:) g 9 Exposure Guidelines
<br /> -XYLENE 1330-20-7 <3 Evacuate personnel to a safe area. Wear self- Applicable Exposure Limits
<br /> er 'ETHYLBENZENE 100-41-4 <1 contained breathing
<br /> apparatus. Wear full protective ESFENVALERATE
<br /> Disclosure as a toxic chemical is required under Sec- equipment. Use water spray. Cool tank/container With PEL(OSHA):None Established
<br /> tion 313 of Title III of the Superfund Amendments and water spray.
<br /> TLV(ACGIH):n None Established
<br /> Reauthorization Act of 1986 and 40 CFR part 372.___... . ___ ---
<br /> HAZARDS
<br /> ___ ACCIDENTAL RELEASE MEASURES AEL'(DuPont): 2 mg/m3,8&12 Hr. TWA,Skin
<br /> _ . . .........
<br /> HAZARDS IDENTIFICATION XYLENE
<br /> Safeguards(Personnel) PEL(OSHA):100 ppm,435 mg/m3,8 Hr. TWA
<br /> Emergency Overview NOTE: Review FIRE FIGHTING MEASURES and TLV (ACGIH): 100 ppm, 8 Hr. TWA, A4 STEL 150
<br /> WARNINGI May be fatal if swallowed. Harmful if in- HANDLING(PERSONNEL)sections before proceed- ppm A4haled. Do not get in eyes,on skin,or on clothing. ing with clean-up. Use appropriate PERSONAL PRO- AEL'(DuPont): 100 ppm,8$12 Hr. TWA 150 ppm,
<br /> #Potential Health Effects TECTIVE EQUIPMENT during clean-up. A minute TWA
<br /> Eye contact with Asana XL may cause eye irritation Accidental Release Measures ETHYLBENZENE
<br /> with tearing,pain or blurred vision. CAUTION-COMBUSTIBLE!
<br /> Skin contact with Esfenvalerate may cause a transient LARGE SPILLS:Eliminate potential source of ignition. PEL(OSHA):100 ppm,435 mg/m3,B Hr. TWA
<br /> (several minutes up to approximately 24 hours)per- Wear appropriate respirator and other protective cloth- TLV (ACGIH): 100 ppm, 8 Hr. TWA, A3 STEL 125
<br /> sistent burning or prickling sensation which may be ing. Shut off source of leak only if safe to do so. Dike ppm
<br /> accompanied by visible irritation or rash. Animal data and contain. Remove with vacuum trucks or pump AEL'(DuPont): 25 ppm,8&12 Hr. TWA
<br /> r, suggests that at high doses,Esfenvalerate may be ab- to storage/salvage vessels. Soak up residue with an *AEL is DuPont's Acceptable Exposure Limit. Where
<br /> sorbed through the skin in amounts capable of causing absorbent such as clay, sand,or other suitable ma- governmentally imposed occupational exposure limits
<br /> toxic effects. terial;place in non-leaking containers and seal tightly which are lower than the AEL are in effect,such limits
<br /> Eye contactwith Esfenvalerate may cause eye irritation i for proper disposal. Flush area with water to remove shall take precedence.
<br /> with discomfort,tearing,or blurring of vision. trace residue;dispose of flush solution as above. PHYSICAL AND CHEMICAL PROPERTIES
<br /> Ingestion of Esfenvalerate may cause nonspecific dis- SMALL SPILLS:Take up with absorbent material and
<br /> comfort, such as nausea, vomiting, headache, or place in non-leaking containers for proper disposal. Do Physical Data
<br /> weakness;temporary nervous system effects such as not use alkaline absorbant, pH:5.14 1%V emulsion in Type I reagent water
<br /> muscular weakness,tremors and incoordination. -- Odor. Oily/aromatic
<br /> HANDLING AND STORAGE Form: Liquid
<br /> Due to physical nature of Esfenvalerate, significant
<br /> exposure to vapor is not anticipated. However, the Handling(Personnel) Color: Straw to light amber
<br /> compound may be harmful if inhaled and may produce Do not get in eyes, on skin, or on clothing. Avoid Density: 7.9 Ib/gal @ 20 deg C(68 deg F)
<br /> acute transient nervous system effects at high doses. breathing vapors or mist. Wash thoroughly after han- STABILITY AND REACTIVITY
<br /> Individuals with preexisting diseases of the liver, kid- dling. Wash clothing after use. Discard shoes if con-
<br /> ney,skin or peripheral nervous system may have in- taminated. Do not store or consume food, drink or Chemical Stability
<br /> creased susceptibility to the toxicity of excessive ex- tobacco in areas where they may become contami- Stable at normal temperatures and storage conditions.
<br /> posures. nated with this material. ; Decomposition
<br /> Carcinogenicity Information USERS SHOULD:Wash hands before eating, drink- I Hydrogen cyanide may be formed by thermal decom-
<br /> The following components are listed by IARC, NTP, ing, chewing gum, using tobacco or using the toilet. I position or reaction with alkaline materials.
<br /> OSHA or ACGIH as carcinogens. Remove clothing immediately If pesticide gets inside. Polymerization
<br /> Then wash thoroughly and put on clean clothing. Polymerization will not occur.
<br /> Storage Other Hazards
<br /> Material IARC NTP OSHA ACGIH Store in a secure,dry and temperate area. Store In Incompatibility: Avoid heat, flame and contact with
<br /> ETHYLBENZENE 28 original container. Keep container closed when not in strong oxidizing agents.
<br /> FIRST AID MEASURES use. Do not store near food or feed. Do not use or TOXICOLOGICAL INFORMATION
<br /> store around the home. Avoid contact with water.
<br /> First Aid #Animal Data
<br /> EXPOSURE CONTROLSfPERSONAL PROTECTION
<br /> IF SWALLOWED:Call poison control center or doctor Asana XL
<br /> immediately for treatment advice. Have person sip Engineering Controls Oral LD50: 458 mg/kg in male rats(Moderately toxic)
<br /> a glass of water if able to swallow. Do not induce Use only with adequate ventilation. Keep container i Dermal LD50: > 2000 mg/kg in rabbits(Moderately
<br /> vomiting unless told to do so by the poison control tightly closed. toxic)
<br /> center or doctor. Do not give anything by mouth to an Use explosion-proof ventilation as required to control Inhalation 4 hour LC50: 2.93 mg/L in rats(Moderately
<br /> unconscious person. vapor concentrations. toxic)
<br /> IF INHALED: Move person to fresh air. If person is Keep liquid and vapor away from heat,sparks or flame. Asana XL is a slight eye irritant,but is not a skin irritant
<br /> not breathing, call 911 or an ambulance, then give Surfaces that are sufficiently hot may ignite liquid prod- or skin sensitizer in animal tests.
<br /> artificial respiration, preferably by mouth-to mouth, if uct even in the absence of sparks or flame. Extinguish ESFENVALERATE
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