|
../
<br /> MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br /> BRAVOU LTREX possible. Call Syngenta(800-888-8372),a poison con- be permissible under certain circumstances where air-
<br /> Syngenta Crop Protection,Inc. trol center or doctor for further treatment advice. borne concentrations are expected to exceed expo-
<br /> Post Office Box 18300 Notes to Physician sure limits. Protection provided by air-purifying respi-
<br /> Greensboro,NC 27419 There is no specific antidote if this product is ingested. rators is limited. Use a pressure demand atmosphere-
<br /> In Case of Emergency,Call 1-800-888-8372 Treat symptomatically. supplying respirator if there is any potential for un-
<br /> Persons having a temporary allergic reaction may ! controlled release,exposure levels are not known,or
<br /> 1. PRODUCT IDENTIFICATION respond to treatment with antihistamines or steroid under any other circumstances where air-purifying res-
<br /> creams and/or systemic steroids. pirators may not provide adequate protection.
<br /> Product Name: BRAVO ULTREX Medical Condition Likel to be Aggravated b Ex
<br /> Product No.: A12836A -- —Y pg 9. PHYSICAL AND CHEMICAL PROPERTIES
<br /> EPA Signal Word: Danger sure
<br /> Active Ingredient(%): Chlorothalonil(82.5%) None known. Appearance: Fine granular brown solid
<br /> Odor: Slight
<br /> r CAS No.: 1897-45-6 5. FIRE FIGHTING MEASURES Melting Point: 482'F
<br /> Chemical Name: Tetrachloroisophthalonitrile Fire and Explosion Boiling Point: >662'F
<br /> Chemical Class: Chlorinated Benzonitrile Fungicide Flash Point(Test Method): Not Applicable Speck Gravity/Density: 0.74 g/cm3
<br /> EPA Registration Number(s): 50534-201-100 Flammable Limits(%in Air): pH:8-10
<br /> Section(s)Revised: 14 Lower. %Not Applicable Solubility in H2O
<br /> 2. COMPOSITION/INFORMATION ON INGREDI- Upper: %Not Applicable Chlorothalonil: 0.81 mg/I @ 77'F(25'C)
<br /> ENTS Autoignition Temperature: Not Applicable Vapor Pressure
<br /> Flammability: Not Flammable Chlorothalonil: 5.7 x 10(-7)mmHg @ 77'F(25'C)
<br /> Unusual Fire Explosion and Reactivity Hazards
<br /> �/ During a fire,irritating and possibly toxic gases may be 10. STABILITY AND REACTIVITY
<br /> OOSHA generated by thermal decomposition or combustion. Stability: Stable under normal use and storage condi-
<br /> VAN OSHA AcclH car. In Case of Fire tions.
<br /> Material PEL TLv Other cinogen Use dry chemical, foam or CO2 extinguishing me- Hazardous Polymerization: Material is not known to
<br /> Kaolin Clay 15 nglm3 2 mg/m3 10 mg/m3 No dia. Wear full protective clothing and self-contained polymerize.
<br /> TWA TWA TWA breathing apparatus. Evacuate nonessential person- Conditions to Avoid: None known.
<br /> (rowI)s (res (romps nel from the area to prevent human exposure to fire, Materials to Avoid: None known.
<br /> wn(res p ro) TWA(res- smoke,fumes or products of combustion. Prevent use Hazardous Decomposition Products: Can decompose
<br /> parable) pirable)'• of contaminated buildings, area,and equipment until at high temperatures forming toxic gases.
<br /> Crystalline 10 mg/m 0.1 Not Es- IARC decontaminated. Water runoff can cause environmen- i 11. TOXICOLOGICAL INFORMATION
<br /> silica, (%Si02-2) mm3 tablished Group tal damage. If water is used to fight fire, dike and
<br /> Quartz (respirable (fes 2A collect runoff. Acute Toxicity/Irritation Studies Finished Product
<br /> dust) pirable
<br /> silica) 6. ACCIDENTAL RELEASE MEASURES Ingestion: Practically Non-Toxic
<br /> Chlorotha- Not Estab- Not Es 0.1 IARC Oral(LD50 Rat): >5000 mg/kg body weight
<br /> ION fished tablished mg�3 Group In Case of ao or Leak Dermal: Slightly Toxic
<br /> (82.5%) TWA 2B Control the spill at its source. Contain the spill to pre- Dermal(LD50 Rabbit): >2000 mg/kg body weight
<br /> (skin vent it from spreading,contaminating soil,or entering Inhalation: Moderately Toxic
<br /> sensitizer, sewage and drainage systems or any body of wa- Inhalation(LC50 Animal Not Available): Not Available
<br /> possible
<br /> respite- ter.Clean u spills immediately,observing Precautions
<br /> Eye Contact: Severely Irritating(Rabbit)
<br /> tory sen- outlined in Section 8. If a solid,sweep up material and Skin Contact: Not Available
<br /> sitizer)••• place in a compatible disposal container. If a liquid, Skin Sensitization: A skin sensitizer in animal tests.
<br /> recommended by NIOSH cover entire spill with absorbing material and place Reproductive/Developmental Effects
<br /> Syngenta Occupational Exposure Limit(OEL) into compatible disposal container. Scrub area with Chlorothalonil: No evidence of adverse developmental
<br /> Ingredients not precisely identified are proprietary or hard water detergent(e.g. commercial products such effects in rabbit and rat studies.
<br /> non-hazardous.Values are not product specifications. as Tide, Joy, Spic and Span). Pick up wash liquid Chronic/Subchronic Toxicity Studies
<br /> 3. HAZARDS IDENTIFICATION ! with additional absorbent and place into compatible Chlorothalonil: In dogs,1 years administration caused
<br /> disposal container. Once all material is cleaned up a significant decrease in body weight gain and in-
<br /> Symptoms of Acute Exposure and placed in a disposal container,seal container and I creases in absolute liver and kidney weights.
<br /> An extremely severe irritant to eyes. May cause se- arrange for disposition. Neurotoxicity: No evidence in regulatory studies.
<br /> vere skin irritation and contact dermatitis. A mild skin Carcinogenicity
<br /> sensitizer. 7. HANDLING AND STORAGE
<br /> Chlorothalonil: No evidence of carcinogenicity in dogs
<br /> Hazardous Decomposition Products Store the material in a well-ventilated, secure area after administration for up to one year. Treament re-
<br /> Can decompose at high temperatures forming toxic out of reach of children and domestic animals. Do toted increases in the incidence of renal tubular ade-
<br /> gases. not store food,beverages or tobacco products in the noma and carcinoma were observed in rats and male
<br /> Physical Properties storage area. Prevent eating, drinking, tobacco use, mice. Squamous cell adenomas and carcinomas were
<br /> Appearance: Fine granular brown solid and cosmetic application in areas where there is a also observed in the forestomach of both species.The
<br /> Odor: Slight potential for exposure to the material.Wash thoroughly forestomach tumors seen in rodent studies are not rel-
<br /> Unusual Fire Explosion and Reactivity Hazards with soap and water after handling. evant to human health, as humans do not possess
<br /> During a fire,irritating and possibly toxic gases may be 8. EXPOSURE CONTROLS/PERSONAL PROTEC- an anatomical equivalent of the rodent forestomach.
<br /> generated by thermal decomposition or combustion. TION The relevance of renal tumors to human health is un-
<br /> -
<br /> n-
<br /> clear,although metabolism data suggest that the dog,
<br /> 4. FIRST AID MEASURES THE FOLLOWING RECOMMENDATIONS FOR
<br /> a species that is resistant to chlorothalonil-induced re-
<br /> Have the product container, label or Material Safety EXPOSURE CONTROLS/PERSONAL PROTEC- nal injury,may be more representative of humans than
<br /> Data Sheet with you when calling Syngenta(800-888- TION ARE INTENDED FOR THE MANUFACTURE, the rat. IARC identifies chlorothalonil as a 2B carcino-
<br /> 8372),a poison control center or doctor, or going for i FORMULATION, PACKAGING AND USE OF THIS gen(possibly carcinogenic to humans).
<br /> treatment. PRODUCT. Other Toxicity Information
<br /> Ingestion: If swallowed: Call Syngenta (800-888- FOR COMMERCIAL APPLICATIONS AND/OR ON- Studies on rats and mice have suggested that tech-
<br /> 8372), a poison control center or doctor immediately FARM APPLICATIONS CONSULT THE PRODUCT nical chlorothalonil (97%),when fed at high levels in
<br /> for treatment advice. Have the person sip a glass of I LABEL. the diet, may have oncogenic potential to these lab-
<br /> water if able to swallow. Do not induce vomiting un- Ingestion:Prevent eating,drinking,tobacco usage and oratory animals. However, neither chlorothalonil nor
<br /> less told to do so after calling 800-888-8372 or by a cosmetic application in areas where there is a potential its metabolites interact with DNA and thus are not
<br /> poison control center or doctor. Do not give anything for exposure to the material. Wash thoroughly with mutagenic. Tumor formation has been related to a
<br /> by mouth to an unconscious person, soap and water after handling. non-genotoxic mechanism of action for which thresh-
<br /> Eye Contact: If in eyes: Hold eye open and rinse Eye Contact: Where eye contact is likely,use chem- old levels have been established in rats and mice.
<br /> slowly and gently with water for 15-20 minutes. Re- ical splash goggles. Facilities storing or utilizing this Comprehensive dietary and worker exposure studies
<br /> move contact lenses,if present,after 5 minutes,then material should be equipped with an eyewash facility have shown exposure levels for humans to be well be-
<br /> continue rinsing eye. Call Syngenta (800-888-8372), and a safety shower. low these threshold levels. In addition,surveillance of
<br /> a poison control center or doctor for treatment advice. Skin Contact: Where contact is likely,wear chemical- chlorothalonil plant workers for over twenty years has
<br /> Skin Contact: If on skin or clothing: Take off con- resistant (such as nitrile or butyl) gloves, coveralls, not demonstrated any increase in oncogenic potential
<br /> taminated clothing. Rinse skin immediately with plenty socks and chemical-resistant footwear. For overhead to humans.
<br /> of water for 15-20 minutes. Call Syngenta(800-886- exposure,wear chemical-resistant headgear. Toxicity of Other Components
<br /> 8372),a poison control center or doctor for treatment Inhalation: Use process enclosures,local exhaust ven- Kaolin Clay
<br /> advice. tilation,or other engineering controls to keep airborne Long term exposure to high concentrations of this dust
<br /> Inhalation: If inhaled: Move person to fresh air. If per- levels below exposure limits. A NIOSH-certified com- may produce x-ray evidence of dust in the lungs. Con-
<br /> son is not breathing, call 911 or an ambulance,then bination air-purifying respirator with an N, P or R 95 tinued long term overexposure may affect respiratory
<br /> give artificial respiration,preferably mouth-to-mouth if or HE class filler and an organic vapor cartridge may function in some individuals.
<br /> Database and format copyright @ by Vance Communication Corp..All rights reserved.
<br />
|