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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br /> CONFIRM* 2F a glass of water if able to swallow. Do not induce RESPIRATORY PROTECTION: Atmospheric levels
<br /> INSECTICIDE vomiting unless told to do so by the poison control should be maintained below the exposure guidelines.
<br /> center or doctor. Never give anything by mouth to an When respiratory protection is required for certain op-
<br /> Emergency Phone: 1-800-992-5994 unconscious person. erations,use a NIOSH approved air-purifying respira-
<br /> Dow AgroSciences LLC INHALATION:Move person to fresh air;if effects oc- tor.
<br /> Indianapolis,IN 46268 cur,consult a physician. I APPLICATORS AND ALL OTHER HANDLERS:Re-
<br /> Effective Date: 10-9-03 NOTE TO PHYSICIAN: Administer 100% oxygen to fer to the product label for personal protective clothing
<br /> Product Code: 88808 relieve headache and a general sense of weakness. and equipment.
<br /> MSDS:007702 Determine methemoglobin concentration of blood ev- 9 PHYSICAL AND CHEMICAL PROPERTIES:
<br /> ery 3 to 6 hours for first 24 hours. It should return to
<br /> 1. PRODUCT AND COMPANY IDENTIFICATION: normal within 24 hours.The treatment of toxic methe- COLOR:Off-white
<br /> PRODUCT:Confirm*2F Insecticide moglobinemia may include the intravenous administra- APPEARANCE:Liquid
<br /> tion of methylene blue. If methemoglobin is>10-20% ODOR:
<br /> COMPANY IDENTIFICATION: Musty
<br /> Dow AgroSciences consider methylene blue 1-2 mg/kg body weight as pH:6 to 7.5
<br /> 9330 Zionsville Road 1% solution IV over 5 minutes followed by 15-30 cc VISCOSITY:300 to 600 CPS
<br /> Indianapolis, IN 46268-1189 flush(Price D,Methemoglobinemia,Goldfrank Toxico- SPECIFIC GRAVITY (WATER = 1): 1.05 @ 77'F
<br /> logic Emergencies,5th ed.,1994). Also provide 100% (25-C)
<br /> 2. COMPOSITION/INFORMATION ON INGREDI- oxygen. Methemoglobinemia may aggravate any pre- VAPOR DENSITY(AIR=1): <1 Water
<br /> r ENTS: existing condition sensitive to a decrease in available VAPOR PRESSURE:17 mmHg @ 68'F(20'C)Water
<br /> oxygen,such as chronic lung disease, BOILING POINT:212F
<br /> Tebufenozide: CAS#712470.23-8 22.5% coronary artery '
<br /> (100'C)Water
<br /> 3,5-dimethVbenzoic acid disease or anemias. Treatment of exposure should be SOLUBILITY IN WATER:Dispersible
<br /> 1-(1,1-dimethylemN}2-(4- directed at the control of symptoms and the clinical PERCENT VOLATILITY:72 to 75%
<br /> ethylbervnyi)hydrazide condition of the patient.
<br /> Other Ingredients.Total,Including: 77.5% __ EVAPORATION RATE(BAe=1): <1 Water
<br /> 1010 Glycerine OAS#00005681-5 5. FIRE FIGHTING MEASURES: 10. STABILITY AND REACTIVITY:
<br /> This document is prepared pursuant to the OSHA Haz- FLASH POINT:Non-combustible
<br /> and Communication Standard(29 CFR 1910.1200). In METHOD USED:Not available STABILITY:Stable under normal storage conditions.
<br /> addition, other substances not 'Hazardous' per this FLAMMABLE LIMITS: INCOMPATIBILITY:Avoid contact with strong oxidiz-
<br /> OSHA Standard may be listed. Where proprietary in- LFL:Not applicable ing agents.
<br /> gradient shows,the identity may be made available as HAZARDOUS DECOMPOSITION PRODUCTS:Ther-
<br /> UFL:Not applicable mal decomposition may yield the following: isobu lene
<br /> provided in this standard. P Y Y 9� tY
<br /> p EXTINGUISHING MEDIA: Use the following extin- I HAZARDOUS POLYMERIZATION:Not known to oc-
<br /> 3. HAZARDOUS IDENTIFICATIONS: guishing media when fighting fires involving this mate- cur.
<br /> EMERGENCY OVERVIEW rial: carbon dioxide,dry chemical,or water spray.
<br /> Hazardous Chemical. Off-white liquid with a musty FIRE AND EXPLOSION HAZARDS:Pesticide panic- 11. TOXICOLOGICAL INFORMATION:
<br /> r odor.May cause eye irritation. LD50 far skin absorption ulates can become airborne. Dried product can burn. MUTAGENICITY: For tebufenozide, in-vitro and an-
<br /> is or.May
<br /> mg/kg. Oral LD50. D50 for
<br /> mg/kg. Aerosol FIRE-FIGHTING EQUIPMENT: Wear self-contained mal genetic toxicity studies were negative. For gtycer-
<br /> is> is 0 mg m /L for 4 hours. breathing apparatus(pressure-demand MSHA/NIOSH ine,in-vitro genetic toxicity studies were negative.
<br /> 9 approved or equivalent)and full protective gear.
<br /> EMERGENCY PHONE NUMBER:800-992-5994 SPECIAL PROCEDURES: Remain upwind. Avoid 12. ECOLOGICAL INFORMATION:
<br /> POTENTIAL HEALTH EFFECTS: This section in- breathing smoke. Use water spray to cool containers ENVIRONMENTAL FATE:
<br /> r eludes possible adverse effects,which could occur if exposed to fire. Contain run-off. ECOTOXICOLOGY•
<br /> this material is not handled in the recommended man-
<br /> ner. 6. ACCIDENTAL RELEASE MEASURES: Based on information for tebufenozide:
<br /> EYE: May cause slight temporary eye irritation. ACTION TO TAKE FOR SPILLS/LEAKS: Floor ma I Oyster shell(Crassastrea virginica), Deposition ECSo
<br /> Corneal injury is unlikely. be slippery; use care to avoid falling. Absorb small is 0.64 mg/L
<br /> SKIN:Brief contact is essentially non-irritating to skin. spills with a non-reactive material such as sand or dirt Earthworm, D Day LC50 A Ibee mg/kg
<br /> Did not cause allergic skin reactions when tested in and place in a suitable container for disposal. Dike Honeybee,k,L i0 is>6µ0/bee
<br /> guinea pigs.Prolonged skin contact is unlikely to result the area of large spills and call Dow AgroSciences at Mallard duck,LC50 is>5000 ppm
<br /> in absorption of harmful amounts. The LD50 for sking00-992-5994 for clean up procedures. If exposed to Bobwhite quail,LC50 is>5000 ppm
<br /> absorption in rats is>5000 mg/kg. the material during cleanup,remove all contaminated Bobwhite quail,LD50 is>2150 mg/kg
<br /> INGESTION:Very low toxicity if swallowed. Harmful i clothing promptly. Wash all exposed skin areas with Daphnia magna,48 hour EC50 is 3.8 mg/L
<br /> effects not anticipated from swallowing small amounts. soap and water immediately after exposure. Do not ! Rainbow trout(Salmo gairdned),96 hour LC50 is 5.7
<br /> The oral LD50 for rats is>5000 mg/kg. take clothing home to be laundered. mg/L
<br /> INHALATION:No adverse effects are anticipated from i Bluegill sunfish(Lepomis macrochirus),96 hour LCso
<br /> single exposure to vapor.The aerosol LC5o for rats is7. HANDLING AND STORAGE: is 3.0 mg/L
<br /> >2.7 mg/L for 4 hours. HANDLING:Do not get product in eyes or on clothing. 13. DISPOSAL CONSIDERATIONS:
<br /> SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Avoid breathing vapors or spray mist. Users should
<br /> For tebufenozide, in animals, effects have been re- wash hands before eating,drinking,chewing gum,us-
<br /> DISPOSAL: Do not contaminate water, food or feed
<br /> ported on the following organs: blood, blood-forming ing tobacco,or using the toilet. For handling relative by storage or disposal. Pesticide wastes are toxic.
<br /> organs (bone marrow & spleen), kidney, and liver. to end-use of this product, read the product label for Improper disposal of excess pesticide, spray mixture
<br /> Excessive exposure may cause methemoglobinemia, further information concerning the use of personal pro- or rinsate is a violation of Federal law. If wastes cannot
<br /> thereby impairing the blood's ability to transport Oxy- tective equipment(PPE)under the Worker Protection be disposed of by use according to label instructions,
<br /> ,,. gen. For glycerine,in animals,effects have been re- Standard of 1993. contact your State Pesticide or Environmental Control
<br /> ported on the following organs: gastrointestinal tract, STORAGE:Do not store this material near food,feed Agency,Or the Hazardous Waste representative at the
<br /> kidney,and liver. or drinking water. Keep container tightly closed when nearest EPA regional office for guidance.
<br /> CANCER INFORMATION:Tebufenozide and glycer- not in use. 14. TRANSPORT INFORMATION:
<br /> ine did not cause cancer in laboratory animals. g. EXPOSURE CONTROLS/PERSONAL PROTEC-
<br /> TERATOLOGY (BIRTH DEFECTS): Tebufenozide U.S. DEPARTMENT OF TRANSPORTATION(DOT)
<br /> r and glycerine did not cause birth defects or any other TION: INFORMATION:
<br /> fetal effects in laboratory animals. These precautions are suggested for conditions where This material is not regulated for transportation.
<br /> REPRODUCTIVE EFFECTS:Tebufenozide,in animal the potential for exposure exists. Emergency condi- 15. REGULATORY INFORMATION:
<br /> studies,did not interfere with reproduction. For glyc- tions may require additional precautions.
<br /> erine,reproductive effects seen in female animals are EXPOSURE GUIDELINES: NOTICE:The information herein is presented in good
<br /> believed to be due to altered nutritional states result- Glycerine:ACGIH TLV is 10 mg/M3. OSHA PEL is 15 faith and believed to be accurate as of the effective
<br /> Ing from extremely high doses of glycerine given in mg/M3 total,5 mg/M3 respirable. date shown above. However,no warranty,express or
<br /> the diet. Similar effects have been seen in animals Tebufenozide: Dow AgroSciences Industrial Hygiene implied,is given. Regulatory requirements are subject
<br /> fed synthetic diets. Guide is 1.3 mg/M3,TWA. to change and may differ from one location to another;
<br /> _ ........ ENGINEERING CONTROLS:Provide general and/or it is the buyer's responsibility to ensure that its activi-
<br /> 4. FIRST AID: local exhaust ventilation to control airborne levels be- ties comply with federal,state or provincial,and local
<br /> EYE:Flush eyes thoroughly with water for several min- low the exposure guidelines. laws. The following specific information is made for
<br /> utes. Remove contact lenses after initial 1-2 minutes RECOMMENDATIONS FOR MANUFACTURING, the purpose of complying with numerous federal,state
<br /> and continue flushing for several additional minutesr If COMMERCIAL BLENDING, AND PACKAGING or provincial,and local laws and regulations.
<br /> effects occur,consult a physician,preferably an oph- WORKERS: U.S..REGULATIONS
<br /> thalmologist. EYEIFACE PROTECTION:Use safety glasses. SARA 313 INFORMATION:To the best of our knowl-
<br /> SKIN:Wash skin with plenty of water. SKIN PROTECTION:Use gloves chemically resistant edge, this product contains no chemical subject to
<br /> INGESTION: Call a poison control center or doctor to this material when prolonged or frequently repeated SARA Title III Section 313 supplier notification require-
<br /> immediately for treatment advice. Have person sip contact could occur. ments.
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