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r ( ( r I ( r U r r r f r r F r r [ r Helena Chemical Company 10-DEC-2001 09:34:30 Helena Chemical Company 10-DEC-2001 09:34:30 PH: 901-761-0050 Page 3 Of 5 PH: 901-761-0050 Page 4 Of 5 CHEMTAEC: 800-424-9300 CHEMTREC: 800-424-9300 Material Safety Data Sheet Material Safety Data Sheet Effective Date: 02-NN-2000 Effective Date: 02-NN-2000 DIMETHOATE 4 EC Product: DIMETHOATE 4 EC -_ - Product: ---------- ----------------------- - SYMPTOMATIC AND OFTEN LIFE-SAVING ANTIDOTE. APRON AND FOOTWEAR. "DO NOT GIVE MORPHINE OR TRANQUILIZERS." THIS PRODUCT IS A STRONG CHOLINESTRASE INHIBITOR -------- --------- AFFECTING THE CENTRAL AND PERIPHERAL NERVOUS IX._SPECIAL PRECAUTIONS ____________ _____ SYSTEMS AND PRODUCING CARDIAC AND RESPIRATORY ___ ___________________ DEPRESSION. AT THE FIRST SIGN OF PULMONARY Special precaution: KEEP OUT OF REACH OF CHILDREN. NOT STORE EDEMA, THE PATIENT SHOULD BE GIVEN OR C FOOD, FEED, OR OTHER MATERIAL L TO BE USED SUPPLEMENTAL OXYGEN AND TREATED OR CONSUMED BY HUMANS OR ANIMALS. DO NOT SYMPTOMATICALLY. CONTINUED ABSORPTION OF THE CONTAMINATE WATER SUPPLIES, LAKES, STREAMS, OR POISON MAY OCCUR AND FATAL RELAPSES HAVE BEEN PONDS. KEEP ALL FOOD IN A SEPARATE AREA, AWAY REPORTED AFTER INITIAL IMPROVEMENT. "VERY FROM THE STORAGE/USE LOCATION OF THE CHEMICAL. CLOSESUPERVISION OF THE PATIENT IS INDICATED PREVENT EATING, DRINKING, TOBACCO USAGE AND FOR AT LEAST 48 HOURS." COSMETIC APPLICATION IN AREAS WHERE THERE IS A POTENTIAL EXPOSURE TO THIS MATERIAL. ALWAYS _________________________________________ ________________________________ WASH HANDS PRIOR TO EATING OR USING TOBACCO. STORE DIMETHOATE 4 E.C. ABOVE 40 DEGREES F. VI. REACTIVITY _ - -_--_-_____ Other precaution: A) RCRA HAZARDOUS WASTE NUMBER: DIMETHOATE, _______________ Stability: Stable PO44; CYCLOHEXANONE, U056 Conditions to Avoid: TEMPERATURES ABOVE 150 DEGREES F. B) SARA TITLE III, SECTION 313: 44.8% Polymerization: Will Not Occur DIMETHOATE; 258 CYCLOHEXANONE Conditions to Avoid: NONE CURRENTLY KNOW. C) SARA THRESHOLD PLANNING QUANTITY: 500/10,000 Incompatibility material: THIS PRODUCT IS UNSTABLE IN ALKALINE AND LBS. OXIDIZING MATERIALS. D) CERCLA REPORTABLE QUANTITY: 2.5 GALLON Hazardous Combustion: COMBUSTION MAY PRODUCE OXIDES OF CARBON, E) 49 CFA 172.101, APPENDIX A: HAZARDOUS NITROGEN, PHOSPHORUS, AND SULFUR UNDER FIRE SUBSTANCE CONDITIONS. F) 49 CFR 172.101, APPENDIX B: SEVERE MARINE POLLUTANT _________________________________________________________________________ VI. SPILL OR LEAK PROCEDURES X. SHIPPING INFORMATION _________________________________________________________________________ Spill or Leak Proc: ROPE OFF CONTAMINATED AREA. COVER SPILL WITH -------------------- --------- SODA ASH, LIME, CLAY, OR SAWDUST. WASH FLOORS Shipping name: RQ ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, WITH CAUSTIC OR SODA ASH UNTIL YELLOW STAINS FLAMMABLE,(DIMETHOATE), 6.1, (3), UN 3017, PG CEASE. WOOD CANNOT BE DECONTAMINATED. PLACE ALL III "EAG N 131" MATERIAL IN RECOVERY DRUMS FOR PROPER DISPOSAL. Hazard Class: KEEP FROM FOOD (6) i Waste Disposal Method: THIS MATERIAL MUST BE DISPOSED OF ACCORDING TO Identification No: UN3017 ■` FEDERAL, STATE, OR LOCAL PROCEDURES UNDER THE Labels Required: KEEP FROM FOOD (6) RESOURCE CONSERVATION AND RECOVERY ACT. Placarding: KEEP FORM FOOD (6) Freight Class: INSECTICIDES, AGRICULTURAL, LIQUID, NOIBN(NMFC ITEM 102120, CLASS 60) VIII. SPECIAL PROTECTION INFORMATION Chemical-Nam q Name Equivalent A.Q.___________________-_ _________________________________________________________________________ _ ______________________ _ Respiration: USE ONLY NIOSH/MSHA APPROVED RESPIRATORS WITH DIMETHOATE 10 LBS/(4.54 KG) ORGANIC VAPOR CARTRIDGES CAPABLE OF REMOVING CYCLOHEXANONE 1000 LB/(454 KG) ORGANOPHOSPHATE PESTICIDES. Ventilation: MECHANICAL (GENERAL) SPARK PROOF ------------------------------------------------------------------------- Gloves: IMPERVIOUS XI. GENERAL PRODUCT INFORMATION Eyes: CHEMICAL WORKERS GOGGLES. Other: EMERGENCY SHOWER, EYE WASH STATION, IMPERVIOUS