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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1 DIPELO DF 4. N/D. Not expected to have any 4. FIRST AID MEASURES corrosive properties. MSDS#BIO-0022EYES: Remove from source of exposure. Flush with DERMAL IRRITATION:Transient,slight or mild irrita- Rev. 1 copious amounts of water. If irritation persists or sign I tion noted in a dermal irritation study with this product. ISSUED 11/05/03 of toxicity occur,seek medical attention. Provide symp- EPA Toxicity Category IV. tomatic/supportive care as necessary. OCULAR IRRITATION: Transient, mild to moderate FICATION SKIN: Remove from source of exposure. Flush with y 1. CHEMICAL PRODUCT AND COMPANY IDENTI- irritation was observed in test animals in a stud with copious amounts of water. If irritation persists or signs this product. Rinsing the eyes with water dramatically MATERIAL NAME:DiPel DF Biological Insecticide of toxicity occur,seek medical attention. Provide symp- reduced irritation scores. Classified as a non-irritant. EPA Reg.No.: 73049-39 tomatic/supportive care as necessary. DERMAL SENSITIZATION:In a study with this prod- Code Number: 80250 INGESTION: Remove from source of exposure. If uct no skin sensitization was observed. List Number: 12046 signs of toxicity occur, seek medical attention. Pro- SPECIAL TARGET ORGAN EFFECTS:N/D ' vide symptomatic/supportive xicityry CARCINOGENICITY INFORMATION: N/D. None of SYNONYMS: care as necessa the components are classified as carcinogens. DiPel 2XDF DiPel PRO DF INHALATION: Remove from source of exposure. If DiPel 6.4 WG DiPel WG signs of toxicity occur,seek medical attention. Provide 12. ECOLOGICAL INFORMATION MANUFACTURER: symptomatic/supportive care as necessary. ECOLOGICAL INFORMATION:N/D Valent BioSciences Corporation 5. FIRE FIGHTING PROCEDURES 13. DISPOSAL CONSIDERATIONS 870 Technology Way,Suite 100 FLASH POINT:N/A WASTE DISPOSAL METHODS: Dispose of product Libertyville, Illinois 60048 FLASH POINT METHOD:N/D in accordance with federal,state and local regulations. EMERGENCY TELEPHONE NUMBERS LOWER EXPLOSIVE LIMIT(%): N/D Emergency Health or Spill: UPPER EXPLOSIVE LIMIT(%): N/D 14. TRANSPORTATION INFORMATION Outside the United States: 651-632-6184 AUTOIGNITION TEMPERATURE:N/D DOT Within the United States: 877-315-9819 FIRE&EXPLOSION HAZARDS:Non-flammable. STATUS:Not Regulated 2. COMPOSITION/INFORMATION ON INGREDI- EXTINGUISHING MEDIA: Use appropriate medium PROPER SHIPPING NAME: N/A ENTS for the underlying cause of the fire. HAZARD CLASS:N/A FIRE FIGHTING INSTRUCTIONS: Wear protective UN NUMBER:N/A INGREDIENT NAME: Bacillus thuringiensis, subsp. clothing and self-contained breathing apparatus. PACKING GROUP:N/A kurstaki REPORTABLE QUANTITY:N/A CONCENTRATION:54.00% 6. ACCIDENTAL RELEASE MEASURES IATA/ICAO CAS NUMBER:68038-71-1 SPILL OR RELEASE PROCEDURES:Recover prod- STATUS:Not Regulated OSHA-PEL uct and place in an appropriate container for disposal. PROPER SHIPPING NAME:N/A 8HR TWA:N/L Avoid breathing dust.Ventilate and wash the spill area. HAZARD CLASS:N/A — STEL:N/L 7. HANDLING AND STORAGE UN NUMBER:N/A CEILING:N/L PACKING GROUP:N/A ACGIH-TLV HANDLING:N/D REPORTABLE QUANTITY:N/A 8HR TWA:N/L STORAGE:Store product in closed container in a cool IMO STATUS:Not Regulated STEL:N/L and dry place. PROPER SHIPPING NAME: N/A CEILING:N/L SPECIAL PRECAUTIONS:N/D 1 HAZARD CLASS:N/A OTHER LIMITS 8. EXPOSURE CONTROLS/PERSONAL PROTEC- UN NUMBER: N/A 8HR TWA:N/A TION PACKING GROUP:N/A STEL:N/A ENGINEERING CONTROLS:Use local exhaust. REPORTABLE QUANTITY:N/A CEILING:N/A RESPIRATORY PROTECTION:Not usually required. FLASH POINT:N/D INGREDIENT NAME:Inert/Other Ingredients-identity If necessary,use a MSHA/NIOSH approved(or equiv- 15. REGULATORY INFORMATION a Trade Secret alent)respirator with a dust/mist filter. CONCENTRATION:46.00% SKIN PROTECTION: Impervious gloves, clothing to TSCA STATUS:Exempt CAS NUMBER:NIA minimize skin contact. CERCLA STATUS:N/D OSHA-PEL EYE PROTECTION: Not usually required. If neces- SARA STATUS:N/D 8HR TWA: 15 mg/m3 total dust,5 mg/m3 respirable sary,use safety glasses or goggles. RCRA STATUS: N/D OTHER PROTECTION: Wash thoroughly with soap PROP 65(CA):N/D fraction STEL:N/L and water after handling. 16. OTHER INFORMATION CEILING:N/L g. PHYSICAL AND CHEMICAL PROPERTIES REASON FOR ISSUE: Updated Hazard Information ACGIH-TLV APPEARANCE/PHYSICAL STATE: Yellow to mus- (Section 3)and Toxicological Information(Section 11). — 8HR TWA:2 mg/m3 respirable fraction lard brown fine granules APPROVAL synonyms - el PRO DF and DiPel WG Added DiPel STEL:N/L ODOR:Faint organic/malt odor CEILING:N/L BOILING POINT:N/A SUPERSEDES DATE:06111/01 OTHER LIMITS MELTINGIFREEZING POINT:N/A LEGEND: NIA=Not Applicable 8HR TWA:NIA VAPOR PRESSURE(mm Hg): N/D N/D=Not Determined STEL:N/A VAPOR DENSITY(Air-1): N/D N/L=Not Listed CEILING:N/A EVAPORATION RATE:N/A L=Listed 3. HAZARDS INFORMATION BULK DENSITY:0.473 g/mL C=Ceiling SPECIFIC GRAVITY:N/D S=Short-term EMERGENCY OVERVIEW: Product is non-toxic by SOLUBILITY:Suspends readily in water. ®=Registered Trademark of Valent BioSciences ingestion,skin contact,or inhalation. pH:4.1 (10%slurry @ 24'C) Tr=Registered Trademark of Valent BioSciences ROUTE(S)OF ENTRY: VISCOSITY: N/A The information and recommendations contained Skin: No 10. STABILITY AND REACTIVITY herein are based upon tests believed to be reliable. Inhalation: No However, Valent BioSciences does not guarantee Ingestion: No CHEMICAL STABILITY: Stable. No oxidizing or re- their accuracy or completeness nor shall any of this SKIN CONTACT:Non-irritant ducing properties. information constitute a warranty,whether expressed .� SKIN SENSITIZATION:Non-sensitizer INCOMPATIBILITIES:Alkalinity inactivates product. or implied, as to the safety of the goods, the mer- EYE CONTACT:Non-irritant HAZARDOUS DECOMPOSITION PRODUCTS:None chantability of the goods,or the fitness of the goods TARGET ORGANS:N/D that are known. for a particular purpose. Adjustment to conform with CARCINOGENICITY RATING: HAZARDOUS POLYMERIZATION:Will not occur. actual conditions of usage may be required. Vatent NTP:N/L 11. TOXICOLOGICAL INFORMATION BioSciences assumes no responsibility for results obtained or for incidental or consequential damages .� IARC:N/L Acute Toxicity arising from the use of these data. No freedom from OSHA:N/L ORAL LD50: >5,050 mg/kg(rat)EPA Toxicity Cate- infringement of any patent, copyright or trademark is ACGIH:N/L gory IV to be inferred. None DERMAL LD50: >2,020 mg/kg(rabbit)EPA Toxicity VALENT BIOSCIENCES- CORPORATION SIGNS AND SYMPTOMS: Direct contact with eyes Category III 870 Technology Way,Suite 100 may cause mild irritation. Inhalation of dust may result INHALATION LC50: Due to the non-dusty charac- Libertyville,IL 60048-800-323-9597 in respiratory tract irritation. teristics of the product,the test facility was unable to November 2003 MEDICAL CONDITIONS AGGRAVATED BY EXPO- generate a sufficiently high enough concentration of ©Valent BioSciences Corporation VID 6.28.04 SURE: Impaired respiratory function. respirable particles. Animal test not warranted. Database and format copyright©by Vance Communication Corp.. All rights reserved.