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<br /> MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br /> ETHREL® BRAND Inhalation: Move person to fresh air. If person is not application. Do not enter or allow worker entry into
<br /> breathing,call 911 or an ambulance,then give artificial treated areas during the restricted entry interval(REI)
<br /> ETH E P H O N PLANT respiration,preferably mouth-to-mouth if possible. Call of 48 hours. Do not apply this product through any type
<br /> a poison control center or doctor for further treatment of irrigation system. For any requirements specific to
<br /> advice. your State or Tribe,consult the agency responsible for
<br /> REGULATOR
<br /> Note to Physician pesticide regulation.
<br /> SECTION 1. CHEMICAL PRODUCT AND COMPANY Have the product container or label with you when Min/Max Storage Temperatures: Not Available
<br /> INFORMATION calling a poison control center or doctor or going for
<br /> treatment. SECTION 8. EXPOSURE CONTROLS/PERSONAL
<br /> Product Name: ETHREL® brand Ethephon Plant Probable mucosal damage may contradicate the use PROTECTION
<br /> Regulator of gastric lavage. There is no specific antidote. All Engineering Controls
<br /> Chemical Name: Ethephon treatment should be based on observed signs and Where engineering controls are indicated by use con-
<br /> Synonym symptoms of distress in the patient. Overexposure to ditions of a potential for excessive exposure exists,the
<br /> MSDS Number: 267 materials other than this product may have occurred. following traditional exposure control techniques may
<br /> Chemical Family Victims of severe overexposure by inhalation should be used to effectively minimize employee exposures:
<br /> Chemical Formulation: C2H6CIO3P be kept under medical observation for up to 72 hours When handlers used closed systems,enclosed cabs,
<br /> EPA Registration No.: 264-267 for delayed onset of pulmonary edema. In a victim Of or aircraft in a manner that meets the requirements
<br /> Canadian Registrat. No. overexposure by ingestion,careful gastric lavage is re- listed in the Worker Protection Standard (WPS) for
<br /> Bayer CropScience quired due to the possibility of stomach or esophageal I agricultural pesticides[(40 CFR 170.240(d)(4-6)],the
<br /> 2 T.W.Alexander Drive perforation. This material is an acid, but the use of handler PPE requirements may be reduced or modified
<br /> Research Triangle PK,NC 27709 alkaline substances to neutralize it is contraindicated. as specified in the WPS.
<br /> USA SECTION 5. FIRE FIGHTING MEASURES Eye/Face Protection
<br /> For Product Use Information: (866)-992-2937 Mon- Eye and face protection requirements will vary depen-
<br /> day through Friday(CRLF)8:OOAM-4:30PM(CRLF) Flash Point: Not applicable dent upon work environment conditions and material
<br /> For Medical Emergency contact DART: 1-800-334- Fire and Explosion Hazards: Under fire conditions, handling practices. Appropriate ANSI Z87 approved
<br /> 7577 24 Hours/Day(CRLF) toxic,corrosive fumes are emitted. equipment should be selected for the particular use
<br /> For Transportation Emergency CHEMTREC:1-800- Suitable Extinguishing Media: Not combustible. Use intended for this material.
<br /> 424-9300 24 Hours/Day extinguishing method suitable for surrounding fire. Face contact should be prevented through use of a
<br /> _ Product Use Description: FIFRA regulated use only. Fire Fighting Instructions: Firefighters should wear face shield.
<br /> MSDS Number: 000000000267 NIOSH/MSHA approved self-contained breathing ap- Body Protection
<br /> MSDS Version paratus and full protective clothing. Dike areas to pre- Skin contact must be prevented through use of perme-
<br /> vent runoff and contamination of water sources. Dis- ation resistant clothing,gloves and footwear,selected
<br /> SECTION 2. COMPOSITION/INFORMATION ON IN- pose of fire control water later.
<br /> GREDIENTS with regard for use conditions and exposure potential.
<br /> SECTION 6. ACCIDENTAL RELEASE MEASURES Consideration must be given both to durability as well
<br /> General and Disposal as permeation resistance.An emergency shower must
<br /> Concentration be readily accessible to the work area.
<br /> Component Name CAS No. %by weight Evacuation Procedures and Safety: Wear appropriate Applicators and other handlers must wear: Long-
<br /> Minimum Maximum gear for the situation. See Personal Protection infor- j sleeved shirt and long pants chemical resistant gloves
<br /> ETHEPON 16672-87-0 21.7000 mation in Section 8. made of any waterproof material such as polyethylene
<br /> i ((2-CH�OETHYL) Cleanup and Disposal of Spill: Pump any free liquid or polyvinyl chloride,shoes plus socks protective eye-
<br /> PHOSPONIC ACID) IMO an appropriate closed container. Soak up with ,,gear.
<br /> Other ingredients 78.3000 inert absorbent material. Sweep up and place in an Respiratory Protection
<br /> (Trade secret) appropriate closed container(see Section 7: Handling When respirators are required, select NIOSH/MSHA
<br /> SECTION 3. HAZARDS IDENTIFICATION and Storage). Clean up residual material by washing approved equipment based on actual or potential air-
<br /> area with water. Collect washings for disposal. De- borne concentrations and in accordance with the a
<br /> NOTE:Please refer to Section 11 for detailed tOxiCO- contaminate tools and equipment following cleanup. p
<br /> logical information. Land Spill or Leaks propriate regulatory standards and/or industrial recom-
<br /> Emergency Overview: Danger! Keep out of the Containment of Spill: Dike spill using absorbent or im- mendations.
<br /> reach of children. Hazard to humans and domestic pervious materials such as earth,sand or clay. Follow Under normal conditions,in the absence of other air-
<br /> animals. procedure under Cleanup and Disposal of Spill. borne contaminants,the following should provide pro-
<br /> Physical State: liquid Environmental and Regulatory Reporting: Do not flush lection from this material , the con WHMIS or the ANSI stan-
<br /> speci-
<br /> -- Odor: neutral to drain. If spilled on the ground, the affected area fled by the appropriate OSHA,
<br /> Appearance: clear should be removed to a depth of one or two inches dard(s): Air-purifying (half-mask/full-face) respirator
<br /> Immediate Effects and placed in an appropriate container for disposal. with cartridge/canister approved for use against dusts,
<br /> Eye: Corrosive-causes irreversible eye damage. Do Prevent material from entering mists and fumes,pesticides.
<br /> y y g g public sewer system or
<br /> not get in eyes. any waterway. Under conditions immediately dangerous to life or
<br /> Skin: Harmful if absorbed through the skin. Do not health,or emergency conditions with unknown concen-
<br /> get on clothing. Avoid contact with skin. SECTION 7. HANDLING AND STORAGE trations, use a full-face positive pressure air-supplied
<br /> Ingestion: Harmful if swallowed. Handling Procedures: Do not get on skin or in eyes. respirator equipped with an emergency escape air sup-
<br /> Inhalation: Do not inhale vapors as this product will Avoid breathing vapors and mists.Do not ingest.Avoid ply unit or use a self-contained breathing apparatus
<br /> irritate mucous membranes. getting material on clothing. Do not contaminate water unit.
<br /> Chronic or Delayed Long-Term: This product does sources,food or feedstuffs when disposing of left-over General Protection
<br /> not contain any ingredients designated by IARC,NTP, material These recommendations provide general guidance for
<br /> ACGIH or OSHA as probable or suspected human car- Storing Procedures:Store in an area away from food, handling this product. Because specific work environ-
<br /> cinogens. Prolonged contact can cause chronic bron- feedstuffs,fertilizers,seed and water sources. Do not ments and material handling practices vary,safety pro-
<br /> chitis. contaminate water, food, or feed by storage or dis- cedures should be developed for each intended appli-
<br /> Medical Conditions Aggravated by Exposure: In- posal. cation. While developing safe handling procedures,do
<br /> -� halation of product may aggravate existing chronic Work/Hygienic Procedures not overlook the need to clean equipment and piping
<br /> respiratory problems such as asthma,emphysema or Wash hands before eating, drinking, chewing gum, systems for maintenance and repairs. Waste resulting
<br /> bronchitis. Skin contact may aggravate existing skin '', using tobacco or using the toilet. from these procedures should be handled in accor-
<br /> disease. Remove clothing immediately if pesticide gets inside. dance with Section 13: Disposal Considerations.
<br /> of
<br /> .
<br /> Then wash thoroughly and put on clean clothingWash Assistance with selection, use and maintenance
<br /> SECTION 4. FIRST AID MEASURES worker protection equipment is generally available from
<br /> contaminated clothing before reuse. equipment manufacturers.
<br /> Eye: Hold eye open and rinse slowly and gently with Remove Personal Protective Equipment(PPE)imme-
<br /> water for 15-20 minutes. Remove contact lenses, if diately after handling this product. Then wash thor- Exposure Limits: None Established
<br /> present,after the first 5 minutes,then continue rinsing oughly and put on clean clothing. Wash the outside of SECTION 9. PHYSICAL AND CHEMICAL PROPER-
<br /> eye.Call a poison control center or doctor for treatment gloves before removing. TIES
<br /> advice. Discard clothing and other absorbent materials that
<br /> r_ Skin: Take off contaminated clothing. Rinse skin im- have been drenched or heavily contaminated with this Appearance: clear
<br /> mediately with plenty of water for 15-20 minutes. Call product's concentrate. Do not reuse them. Follow Physical State: liquid
<br /> a poison control center or doctor for treatment advice. manufacturer's instructions for cleaning/maintaining Odor: neutral
<br /> Ingestion: Immediately call a poison control center Personal Protective Equipment(PPE). If no such in- pH:1.9 at 1 wVwt%.
<br /> or doctor for treatment advice. Do not induce vomit- structions for washables,use detergent and hot water. Vapor Pressure: << 0.01 mmHg at 25'C
<br /> _ ing unless told to do so by a poison control center or Keep and wash PPE separately from other laundry. Vapor Density(air=1): Not available
<br /> doctor. Have a person sip a glass of water if able to Do not apply this product in a way that will contact Specific Gravity: 1.106 at 25'C
<br /> swallow. Do not give anything by mouth to an uncon- workers or other persons, either directly or through ! Boiling Point: Not available
<br /> scious person. drift.Only protected handlers may be in the area during Melting/Freezing Point: --5.0'C
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