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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br /> GLYPHOMAX* 5. FIRE FIGHTING MEASURES: 12. ECOLOGICAL INFORMATION:
<br /> HERBICIDE FLASH POINT: >235'F(>112'C) ENVIRONMENTAL FATE:
<br /> Emergency Phone: 800-992-5994 METHOD USED:Setaflash MOVEMENT & PARTITIONING: Based largely or
<br /> Dow AgroSciences LLC FLAMMABLE LIMITS: completely on information for glyphosate. Bioconcen-
<br /> Indianapolis,IN 46268 LFL:Not applicable tration potential is low(BCF<100 or Log Pow<3).
<br /> Effective Date: 4/8/02 UFL:Not applicable Expected to be relatively immobile in soil(Koc>5000).
<br /> Product Code: 74373 EXTINGUISHING MEDIA:Foam,CO2,or Dry Chem- DEGRADATION&PERSISTENCE:
<br /> MSDS:006693 ical i Based largely or completely on information for
<br /> 1. PRODUCT AND COMPANY IDENTIFICATION: FIRE AND EXPLOSION HAZARDS:Foam fire extin- I glyphosate. Degradation is expected in the soil
<br /> guishing system is preferred because uncontrolled wa- environment.
<br /> PRODUCT:Glyphomax•Herbicide ter can spread possible contamination. Toxic irritating ECOTOXICOLOGY:
<br /> COMPANY IDENTIFICATION: gases may be formed under fire conditions. Material is practically non-toxic to aquatic organisms
<br /> Dow AgroSciences on an acute basis(LC50/EC50>100 mg/L in the most
<br /> 9330 Zionsville Road FIRE-FIGHTING EQUIPMENT:Use positive-pressure,equipment. sensitive species).
<br /> Indianapolis, IN 46268-1189 self-contained breathing apparatus and full protective Acute LC50 in rainbow trout(Oncorhynchus mykiss)is 2. COMPOSITIONfINFORMATION ON INGREDI- 109 mg/L.
<br /> Acute immobilization EC n water flea (Daphnia
<br /> ENTS: 6. ACCIDENTAL RELEASE MEASURES: 50 ( P
<br /> magna)is 105 mg/L.
<br /> Glyphosate: CAS#038641-94-0 41.3% ACTION TO TAKE FOR SPILLS:Absorb small spills Material is practically non-toxic to birds on an acute
<br /> 14-(phosphono- with an inert absorbent material such as Hazorb,Zor- basis(LD50 is>2000 mg/kg).
<br /> metnyl)gwne. ball, sand, or dirt. Report large spills to Dow Agro- Acute oral LD in bobwhite Colinus vir inianus Is
<br /> Isopropylamine 50 ( g )
<br /> San Sciences on 800-992-5994. >2000 mg/kg.
<br /> Inert Ingredients,Total 56.7°6 7. HANDLING AND STORAGE: The LC50 in earthworm (Eisenia foetida) is >1000
<br /> This document is prepared pursuant to the OSHA Haz- mg/kg.
<br /> and Communication Standard(29 CFR 1910.1200). In PRECAUTIONS TO BE TAKEN IN HANDLING AND Acute contact LD50 in honeybee (Apis mellifera) is
<br /> addition, other substances not 'Hazardous' per this STORAGE: Keep out of reach of children. Do not >100µg/bee.
<br /> OSHA Standard may be listed. Where proprietary in- swallow. Avoid contact with eyes,skin,and clothing. Acute oral LD50 in honeybee (Apis mellifera)is>100
<br /> gredient shows,the identity may be made available as Avoid breathing vapors and spray mist. Handle con- pg/bee.
<br /> provided in this standard. centrate in ventilated area. Wash thoroughly with soap Growth inhibition EC50 in green alga (Selenastrum
<br /> 3. HAZARDOUS IDENTIFICATIONS: and water after handling and before eating, chewing capricomutum)is 2.50 mg/L.
<br /> gum,using tobacco,using the toilet or smoking. Keep Growth inhibition ECso in duckweed (Lemna sp.) is
<br /> EMERGENCY OVERVIEW away from food,feedstuffs,and water supplies. Store 48.4 mg1L.
<br /> Hazardous Chemical. Clear amber liquid with a faint in original container with the lid tightly closed. 13. DISPOSAL CONSIDERATIONS:
<br /> amine odor. May cause eye irritation. LD50 for skin
<br /> absorption in rabbits is >5000 mg/kg. Oral LD50 for 8. EXPOSURE CONTROLS/PERSONAL PROTEC- DISPOSAL METHOD: Do not contaminate water,
<br /> rats is >5000 mg/kg. Aerosol LC50 for rats is>5.00 TION: food,or feed by storage or disposal. Excess wastes
<br /> mg/L for 4 hrs. Slightly toxic to aquatic organisms. These precautions are suggested for conditions where resulting from the use of this product may be disposed
<br /> EMERGENCY PHONE NUMBER:800-992-5994 the potential for exposure exists. Emergency condi- of on site according to label directions or at an ap-
<br /> �. POTENTIAL HEALTH EFFECTS: This section in- tions may require additional precautions. proved waste disposal facility. Follow all local, state,
<br /> cludes possible adverse effects,which could occur if EXPOSURE GUIDELINES:None established and federal requirements for disposal.
<br /> this material is not handled in the recommended man- ENGINEERING CONTROLS: Good general ventila- 14. TRANSPORT INFORMATION:
<br /> ner. tion should be sufficient for most conditions. Local
<br /> EYE:May cause slight eye irritation. Corneal injury is exhaust ventilation may be necessary for some oper- U.S.DEPARTMENT OF TRANSPORTATION INFOR-
<br /> unlikely. MATION:
<br /> ations.
<br /> SKIN:Essentially non-irritating to skin. Prolonged skin For all package sizes and modes of transportation:
<br /> contact is unlikely to result in absorption of harmful RECOMMENDATIONS FOR MANUFACTURING, This material is not regulated for transportation.
<br /> amounts. The LD50 for skin absorption in rabbits is COMMERCIAL BLENDING, AND PACKAGING
<br /> >5000 mg/kg. Did not cause allergic skin reactions WORKERS: 15. REGULATORY INFORMATION:
<br /> when tested in guinea pigs. EYE/FACE PROTECTION:Use safety glasses. NOTICE:The information herein is presented in good
<br /> r. INGESTION:Very low toxicity if swallowed. Harmful SKIN PROTECTION:No precautions other than clean faith and believed to be accurate as of the effective
<br /> d
<br /> d
<br /> should b
<br /> h
<br /> clothing in
<br /> dy-coverg cong soue needed.effects not anticipated from swallowing small amounts. bodate shown above. However,no warranty,express or
<br /> The oral LD for rats is>5000 mg/kg. RESPIRATORY PROTECTION:For most conditions, implied,is given. Regulatory requirements are subject
<br /> LD50 9 g' no respiratory protection should be needed;however, p 9 9 ry q I
<br /> INHALATION:A single brief(minutes)inhalation expo- to change and may differ from one location to another;
<br /> sure is not likely to cause adverse effects.The aerosol if discomfort is experienced, use a NIOSH approved it is the buyer's responsibility to ensure that its activi-
<br /> air-purifying respirator.
<br /> � LC50 for rats is>5.00 mg/L for 4 hours. ties comply with federal,state or provincial,and local
<br /> SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: APPLICATIONS AND ALL OTHER HANDLERS: laws. The following speck information is made for
<br /> For the active ingredient,in animals,effects have been Please refer to the product label for personal protective the purpose of complying with numerous federal,state
<br /> reported on the following organ: liver. clothing and equipment. or provincial,and local laws and regulations.
<br /> CANCER INFORMATION:The active ingredient did 9. PHYSICAL AND CHEMICAL PROPERTIES: U.S.REGULATIONS
<br /> not cause cancer in laboratory animals. SARA 313 INFORMATION:To the best of our knowl-
<br /> �' TERATOLOGY(BIRTH DEFECTS):For the active in- APPEARANCE:Clear amber liquid edge, this product contains no chemical subject to
<br /> gredient,birth defects are unlikely. Exposures having DENSITY:9.5-10.0 lbs./gallon SARA Title III Section 313 supplier notification require-
<br /> no effect on the mother should have no effect on the ODOR:Faint amine ments.
<br /> fetus. Did not cause birth defects in animals; other SPECIFIC GRAVITY:1.165 gm/mL SARA HAZARD CATEGORY:This product has been
<br /> effects were seen in the fetus only at doses which SOLUBILITY IN WATER:Miscible reviewed according to the EPA"Hazard Categories"
<br /> caused toxic effects to the mother. FREEZING POINT: —14'F-—17'F(-25'C-—27-C) promulgated under Sections 311 and 312 of the Su-
<br /> REPRODUCTIVE EFFECTS: For the active ingredi- pH:4.8-5.0 perfund Amendment and Reauthorization Act of 1986
<br /> ent,in laboratory animal studies,effects on reproduc- (SARA Title III) and is considered, under applicable
<br /> tion have been seen only at doses that produced sig- 10. STABILITY AND REACTIVITY: definitions,to meet the following categories:
<br /> nificant toxicity to the parent animals. CONDITIONS TO AVOID)Stable under An immediate health hazard
<br /> STABILITY:
<br /> ( A delayed health hazard
<br /> r 4. FIRST AID: normal conditions. TOXIC SUBSTANCES CONTROL ACT(TSCA): All
<br /> EYE:Flush eyes thoroughly with water for several min- INCOMPATIBILITY: (SPECIFIC MATERIALS TO ingredients are on the TSCA inventory or are not re-
<br /> utes. Remove contact lenses after initial 1-2 minutes AVOID)Galvanized or unlined steel(except stainless quired to be listed on the TSCA inventory.
<br /> and continue flushing for several additional minutes. If steel)containers or spray tanks may produce hydro- STATE RIGHT-TO-KNOW:This product is not known
<br /> effects occur,consult a physician,preferably an oph- gen gas which may form a highly combustible gas to contain any substances subject to the disclosure
<br /> ... thalmologist. mixture. requirements of
<br /> SKIN:Wash skin with plenty of water. HAZARDOUS DECOMPOSITION PRODUCTS:None New Jersey
<br /> INGESTION:No emergency medical treatment neces- known. Pennsylvania
<br /> sary. HAZARDOUS POLYMERIZATION:Not known to oc- OSHA HAZARD COMMUNICATION STANDARD:
<br /> INHALATION:Move person to fresh air;if effects oc- cur. This product is a "Hazardous Chemical" as defined
<br /> cur,consult a physician. 11. TOXICOLOGICAL INFORMATION: by the OSHA Hazard Communication Standard, 29
<br /> NOTE TO PHYSICIAN: No specific antidote. Treat- CFR 1910.1200.
<br /> ment of exposure should be directed at the control of ! MUTAGENICITY: Animal mutagenicity studies were NATIONAL FIRE PROTECTION ASSOCIATION
<br /> symptoms and the clinical condition of the patient. negative. (NFPA)RATINGS:
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