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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br /> L A N N A TE SP
<br /> ' by-products more toxic than the original material. If
<br /> INSECTICIDE FIRST AID MEASURES product is on fire,wear self-contained breathing appa-
<br /> First Aid ratus and full protective equipment. Use water spray.
<br /> M0000388 THIS PRODUCT IS AN N-METHYL CARBAMATE IN- Control runoff.
<br /> Revised 12-21-03 SECTICIDE. ACCIDENTAL RELEASE MEASURES
<br /> INGESTION: Safeguards(Personnel)
<br /> CHEMICAL PRODUCT/COMPANY IDENTIFICA- IF SWALLOWED:Call a poison control center or doc- NOTE: Review FIRE FIGHTING MEASURES and
<br /> TION for immediately for treatment advice. Drink 1 or 2 HANDLING (PERSONNEL)sections before proceed-
<br /> Material Identification glasses of water and induce vomiting by touching back ing with clean-up. Use appropriate PERSONAL PRO-
<br /> "LANNATE" is a registered trademark of DuPont. of throat with finger. Do not induce vomiting or give TECTIVE EQUIPMENT during clean-up.
<br /> DuPont. anything by mouth to an unconscious person. Emergency Response-Chemical resistant coveralls,
<br /> "DuPont" is a trademark of D
<br /> Corporate MSDS Number: D uPont. 1 EYE CONTACT: waterproof gloves,waterproof boots and face/eye pro-
<br /> Grade: A 90%FORMULATION IF IN EYES:Hold eye open and rinse slowly and gently tection. If dusting occurs,use NIOSH approved respi-
<br /> with water for 15-20 minutes. Remove contact lenses, rator protection.
<br /> Tradenames and Synonyms if present,after the first 5 minutes,then,continue rins- Initial Containment
<br /> "Lannate" 90-WD ing eye. Call a poison control center or doctor for Remove source of heat,sparks,flame,impact,friction
<br /> 90-WD treatment advice. or electricity.
<br /> Yugo INHALATION: Follow applicable Federal, State/Provincial and Local
<br /> "LANNATE" SP IF INHALED:Move person to fresh air. If person is not laws/regulations.
<br /> Company Identification breathing,call 911 or an ambulance,then give artificial Prevent material from entering sewers,waterways,or
<br /> MAN UFACTURER/DISTRIBUTOR respiration,preferably by mouth-to-mouth,if possible. low areas.
<br /> DuPont Call a poison control center or doctor for treatment Accidental Release Measures
<br /> 1007 Market Street advice. Contain spill. Shovel or sweep up powder. Use saw-
<br /> Wilmington, DE 19898 SKIN CONTACT: dust, sand,oil dry or other absorbent material as an
<br /> PHONE NUMBERS IF ON SKIN OR CLOTHING:Take off contaminated aid to removing remaining traces of spilled material.
<br /> Product Information: 1-800-441-7515(outside the U.S. clothing. Rinse skin immediately with plenty of wa- Do not allow the material to enter sewers,waterways
<br /> 302-774-1000) ter for 15-20 minutes. Call a poison control center or or low areas.
<br /> Transport Emergency: CHEMTREC 1-800-424-9300 doctor for treatment advice. If product enters crevices and can not be removed,
<br /> (outside U.S.703-527-3887) ATROPINE IS AN ANTIDOTE-SEEK MEDICAL AT- treat with a sodium hydroxide solution and allow to
<br /> Medical Emergency: 1-800-441-3637(outside the U.S. TENTION AT ONCE IN ALL CASES OF SUSPECTED stand 4 hours.
<br /> 302-774-1000) POISONINGS. NOTE:Sodium hydroxide is caustic and causes bums.
<br /> If warning symptoms appear(see WARNING SYMP- Do not get in eyes,on skin,or on clothing. In case of
<br /> COMPOSITIONIINFORMATION ON INGREDIENTS TOMS),get medical attention. contact,flush eyes or skin with plenty of water and call
<br /> Have the product container or label with you when i a physician. When handling,wear goggles in addition
<br /> �. Components calling a poison control center or doctor,or going for to boots and gloves.
<br /> treatment. You may also call 1-800-441-3637 for emer- HANDLING AND STORAGE
<br /> gency medical treatment information.
<br /> Motorial CAS Number % Notes to Physicians Handling(Personnel)
<br /> METHOMYL 16752-77-5 90 WARNING SYMPTOMS - Methomyl poisoning pro- Do not breathe vapor or mist. Do not get in eyes,on
<br /> (S-METHYL-N-I(METHYLCARBA- duce effects associated with anticholinesterase ac- skin,or on clothing.
<br /> MOYL)OXYITHIOACETIMIDATE)
<br /> INERT INGREDIENTS 10 tivity, which may include weakness, blurred vision, USERS SHOULD:Wash hands before eating, drink-
<br /> INERT
<br /> headache, nausea, abdominal cramps, discomfort in i ing,chewing gum,using tobacco or using the toilet.
<br /> HAZARDS IDENTIFICATION the chest,constriction of pupils,sweating,slow pulse, 11 Remove clothing immediately If pesticide gets inside.
<br /> Emergency Overview and muscle tremors. Then wash thoroughly and put on clean clothing.
<br /> TREATMENT -Atropine sulfate should be used for I Remove personal protective equipment immediately
<br /> DANGER! treatment. Administer repeated doses, 1.2 to 2.0 mg after handling this product.Wash the outside of gloves
<br /> Fatal if swallowed. May be fatal if inhaled or absorbed intravenously every 10 to 30 minutes until full at- before removing. As soon as possible, wash thor-
<br /> through the eyes. Harmful if absorbed through the ropinization is achieved. Maintain atropinization until i oughly and change into clean clothing.
<br /> skin. the patient recovers. Artificial respiration or oxygen Handling(Physical Aspects)
<br /> Do not get in eyes, on skin, or on clothing. Do not may be necessary. Allow no further exposure to any Avoid dust generation. Keep away from heat,sparks
<br /> breathe vapors or spray mist. Pilot should not assist cholinesterase inhibitor until recovery is assured. and flames.
<br /> in the mixing and loading operation. Do not use 2-PAM for exposure to"Lannate"SP alone. Do not open,rip,tear,cut or perforate the inner water
<br /> Potential Health Effects However,for exposure to combinations of"Lannate" i soluble bag.
<br /> WARNING SYMPTOMS SP and organophosphorous insecticides,2-PAM may Storage
<br /> Methomyl poisoning produces effects associated with be used as required to supplement the atropine sulfate Handle this package carefully to prevent breakage of
<br /> anticholinesterase activity which may include weak- treatment as described above. Do not use morphine. inner bag when stored at low temperatures. Allow to
<br /> +� ness, blurred vision, headache, nausea, abdominal For medical emergencies involving this product, call warm above 50 deg F for normal handling. Store prod-
<br /> cramps,discomfort in the chest,constriction of pupils, toll free 1-800-441-3637. uct in original container only. Do not contaminate wa-
<br /> sweating,slow pulse,muscle tremors. FIRE FIGHTING MEASURES ter,other pesticides,fertilizer,food or feed in storage.
<br /> Human health effects from single ingestion of Not for use or storage in or around the home.
<br /> Methomyl at doses of 0.1, 0.2, or 0.3 mg/kg caused Flammable Properties EXPOSURE CONTROLSMERSONAL PROTECTION
<br /> temporary cholinesterase and hematologic effects. Flammable limits in Air,%by Volume
<br /> No other adverse effects were observed.The NOAEL LEL:0.096 g/L Engineering Controls
<br /> was 0.1 mg/kg. Autodecomposition: 136 C(277 F) Use only with adequate ventilation. Keep container
<br /> Skin, eye, inhalation or ingestion exposure to Will ignite if exposed to intense heat or open flame. tightly closed.
<br /> Methomyl may cause acute cholinesterase depres- Dust forms explosive mixture with air. Human flaggers must be in enclosed cabs.Pilot should
<br /> Fire and Explosion Hazards: not assist in the mixing and loading operation.
<br /> as characterized nonspecific discomfort, such
<br /> as nausea, headachee,,weakness,cramps,excessive Fire or intense heat may cause violent rupture of pack-
<br /> Personal Protective Equipment
<br /> sweating, salivation and tearing, constricted pupils, ages. Heating can release vapors which can be ig- Applicators and other handlers must wear:
<br /> blurred vision; muscle twitching, and confusion. nited. Hazardous gases produced in fire under condi- Long-sleeved shirt and long pants.
<br /> Higher exposures may lead to loss of consciousness, tions that produce incomplete combustion may consist Chemical Resistant Gloves Category A(such as butyl
<br /> or convulsions and severe respiratory depression. of SO2,NO2,CO2,HCN,CH3NC0,CO,CS2. Com- rubber,natural rubber,neoprene rubber,or nitrile rub-
<br /> Skin contact with Methomyl may cause skin irritation plate combustion greatly reduces the amounts of CS2, bar)are equal to or greater than 14 mils.
<br /> with discomfort or rash. Evidence suggests that skin CO,HCN,and CH3NCO generated. Shoes plus socks.
<br /> permeation can occur in amounts capable of producing Extinguishing Media
<br /> the effects of systemic toxicity. Water Spray,Water Fog,Dry Chemical,CO2. For exposures vinaenclosed areas, a respirator with
<br /> Eye contact with Methomyl may cause eye irritation Fire Fighting Instructions either an organic vapor-removing cartridge with a pre-
<br /> with discomfort,tearing,or blurring of vision. Evacuate personnel to a safe area. Keep person- roved for pesticides(MSHA/NIOSH approval
<br /> Individuals with preexisting diseases of the central ner- nel removed and upwind of fire. Wear self-contained filter app roved for
<br /> vows system or conditions which lower cholinesterase breathing apparatus. Wear full protective equipment. number-contained
<br /> desr(MSHA/N SHA/NIOSH approvalcanister number prefix TC
<br /> levels may have increased susceptibility to the toxicity Use water spray.Cool tankicontainer with water spray. 14G),or NIOSH approved respirator with an organic
<br /> Isolate area. Fight fire from maximum distance, us
<br /> of excessive exposures. e
<br /> Carcinogenicity information extreme caution as heat may decompose material and vapor(OV)cartridge or a canister with any R,P,or HE
<br /> prefilter.
<br /> None of the components present in this material at rupture containers. permit let For exposures outdoors, Dust/mist filtering respirator
<br /> concentrations equal to or greater than 0.1%are listed If area is exposed to fire 9 nil conditions pe approval number prefix TC-21C), or
<br /> by IARC,NTP,OSHA or ACGIH as a carcinogen. fire burn itself out. Burning chemicals may produce �, (MSHA/NIOSH app
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