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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1 <br /> POAST PLUSO and brownish urine. Inhalation of naphthalene may <br /> a. cause headache,confusion and excitement. Chronic I SECTION 8—ECOLOGICAL INFORMATION <br /> SECTION 1 —CHEMICAL PRODUCT AND COM- overexposure to naphthalene may result in liver/kidney ENVIRONMENTAL TOXICITY:(For active ingredient) <br /> PANY IDENTIFICATION disorders. Hemolysis,anemia, fever, hemoglobinuria 96 hour LC50,Bluegill-265 mg/L <br /> and jaundice may also occur. Those with prior blood 96 hour LC50,Trout-170 mg/L <br /> COMPANY ADDRESS: diseases may be more severely affected. 48 hour EC50,Daphnia-78.1 mg/L <br /> Micro Fla Company LLC A National Toxicology Program(NTP)report states thatMallard Acute LD50->2510 mg/kg <br /> �. P.O.BOX 772099 lifetime inhalation exposure to naphthalene resulted in Mallard Dietary LC m <br /> Memphis,TN 38117 increase in tumors of the nose of rats. In a previous ry 50->5620 pp <br /> EMERGENCY TELEPHONE NUMBERS: Bobwhite Dietary LC50->5620 ppm <br /> NTP study,lifetime inhalation exposure to naphthalene Environmental toxicity data is not available for formu- <br /> (800) 424-9300 (CHEMTREC, transportation and increased lung tumors in female mice. The relevance lated product. <br /> spills) of the rodent findings to humans is questionable. <br /> 800 900-4044 Poison Control Center,human health Active ingredient is not toxic to honeybees when ap- <br /> .. ( ) ( ) CHRONIC OVEREXPOSURE EFFECTS: May result Plied topically up to 10 ug/bee or when sprayed on at <br /> (800)345-4735(RSPCA,animal health) in liver/kidney disorders. Hemolysis, anemia, fever, a concentration simulating g exposure to the maximum <br /> PRODUCT NAME:POAST PLUS <br /> hemoglobinuria and jaundice may also occur. Those recommended use rate 2000 ppm. <br /> CHEMICAL NAME: 2-{1-(ethoxyimino)butyl}-5-{2- with prior blood diseases may be more severely af- SARA TITLE 111 STATUS: <br /> (ethylthio)propyl}-3-hydroxy-2-cyclohexen-1-one fected. <br /> Section 313: Listed <br /> FORMULA:C(17)H(29)0(3)N S <br /> SIGNS AND SYMPTOMS OF OVEREXPOSURE: Fire: Yes <br /> CHEMICAL FAMILY:Cyclohexanone Acute overexposure to solvent naphtha vapors may <br /> PRODUCT CODE:EPA Re No. 7969-88-51036 p P P Y Sudden Pressure: No <br /> 9� cause central nervous system effects, including Reactivity: No <br /> SECTION 2—COMPOSITION, INFORMATION OF headache, dizziness, drowsiness, and confusion. Acute: Yes <br /> INGREDIENTS Ingestion causes nausea, vomiting, blurred vision, Chronic: Yes <br /> and CNS disorder. Aspiration of the liquid into the TPQ:10,000 Ibs <br /> lungs may result in chemical pneumonitis,which may SPILL AND LEAK PROCEDURE: Recover material <br /> COMPONENT PERCENT- CAS OSHA ACIGH '.. be fatal. Prolonged or repeated skin contact may for use according to label whenever possible. Wear <br /> AGE NUMBER PEL TLV cause defatting and dermatitis. gloves, goggles and boots when cleaning up liquid <br /> Sethoxydim 13.0 74051- Not Not The following special studies have been performed for spill. Cover contaminated area with absorbent material <br /> 80-2 Est. Esta the active ingredient: until dry. Spills which cannot be recovered should be <br /> w inerts, 87.0 NIA Terat enol rat and rabbit <br /> including: og ty( )-negative contained,solidified and placed in suitable containers <br /> Naphthalene 1.3 91-20-3 10 PPM 10 ppm Reproductive studies(2 generations rat)-negative for disposal in a licensed facility. <br /> Skin sensitization(guinea pig)-negative HAZARDOUS SUBSTANCE SUPERFUND:Yes <br /> SECTION 3—PHYSICAL AND CHEMICAL PROP- FIRST AID PROCEDURES: WASTE DISPOSAL METHOD:Wastes resulting from <br /> ERTIES IF SWALLOWED-Call a poison control center or doc- the use of this product may be disposed of on site or <br /> - - -- - N p at an approved waste disposal facility. <br /> PHYSICAL DESCRIPTION:Clear Liquid for immediate for treatment advice. Have person sip PP 1 ttY• <br /> ODOR:Mild Aromatic a glass of water if able to swallow. Do not induce vom- I CONTAINER DISPOSAL: Triple rinse container (or <br /> BOILING/MELTING POINT:N/D iting unless told to do so by a poison control center or containers). Then offer for recycling or reconditioning, <br /> doctor. or puncture and dispose of in a sanitary landfill,or by <br /> SPECIFIC GRAVITY:0.906 g/mL 7.56 Ib/gal ricineration,or,if allowed by state or local authorities, <br /> pH:3.21 -3.5(5%Aq.) IF ON SKIN-Take off contaminated clothing. Rinse I by burning. If burned,stay out of smoke. <br /> .., VAPOR PRESSURE mmHg @ 20 C:2 skin immediately with plenty of water for 15-20 minutes. <br /> WATER SOLUBILITY:Farms emulsion Call a poison control center or doctor for treatment SECTION 9—TRANSPORT INFORMATION <br /> --- - advice. <br /> SECTION 4—FIRE&EXPLOSION HAZARD IF IN EYES-Hold eye open and rinse slowly and gently DOT PROPER SHIPPING NAME: <br /> with water for 15-20 minutes. Remove contact lenses, BULK-Combustible Liquid <br /> FLASHPOINT(method): 188'F TCC PACKAGE-None <br /> FLAMMABLE LIMITS(LFL-UFL): if present,after first five minutes,then continue rinsing. DOT HAZARD CLASSIFICATION: <br /> Lower: 1.3 @ 70'C Call a poison control center or doctor for treatment <br /> Primary-BULK-Combustible Liquid(120 gallons or <br /> Upper: 5.3 @ 10TC advice. more) <br /> FIRE AND EXPLOSION HAZARD:None IF INHALED-Move person to fresh air. If person is not PACKAGE-None <br /> EXTINGUISHING MEDIA: Use water fog, foam, breathing,call 911 or an ambulance,then give artificial Secondary-None <br /> CO(2),or dry chemical extinguishing media. respiration,preferably mouth-to-mouth if possible. Call DOT LABELS REQUIRED:None <br /> FIRE FIGHTING EQUIPMENT:Firefighters should be a poison control center or doctor for treatment advice. DOT PLACARDS REQUIRED:Combustible <br /> equipped with self-contained breathing apparatus and NOTE-Have the product container or label with you BILL OF LADING DESCRIPTION: <br /> turnout gear. when calling a poison control center or doctor or going BULK-Combustible liquid, NOS(contains Petroleum <br /> NFPA 704 HAZARD CODES: for treatment. Distillate),NA 1993,RQ(Naphthalene),ERG 128 <br /> Health-2 PACKAGE-Compounds,Tree or Weed Killing NOIBN <br /> Flammable-2 SECTION 6—STABILITY AND REACTIVITY (Herbicides) <br /> Instability-1 CHEMICAL STABILITY:Stable CERCLA REPORTABLE QUANTITY:100 lbs(Naph- <br /> Other-n/a thalene;RQ=76,000 lbs. as product) <br /> ---- CONDITIONS TO AVOID:Heat,air,moisture P ) <br /> SECTION 5—HEALTH DATA CHEMICAL INCOMPATIBILITY:Oxidizing agents SECTION 10—ADDITIONAL INFORMATION <br /> ACUTE TOXICITY: HAZARDOUS DECOMPOSITION PRODUCTS: 7969-88-51036 <br /> Oral LD50(rat)->2200 mg/kg SO(2),NOx during combustion KEEP OUT OF REACH OF CHILDREN <br /> Dermal LD50(rat)->2000 mg/kg HAZARDOUS POLYMERIZATION:Does not occur CAUTION <br /> Inhalation LC5o(rat)(4 hr)->7.6 mg/L CORROSIVE TO METAL:No Complete Label and Directions For Use are attached <br /> Eye Irritation(rabbit)-Slightly irritating OXIDIZER:No to the product <br /> Skin Irritation(rabbit)-Slightly irritating AGRICULTURAL USE REQUIREMENTS <br /> Sensitizer(guinea pig)-Non-sensitizing SECTION 7—PERSONAL PROTECTION Use this product only in accordance with its labeling <br /> EFFECTS OF OVEREXPOSURE: Causes moderate PESTICIDE APPLICATORS&WORKERS: Refer to and with the Worker Protection Standard,40 CFR part <br /> eye injury. Harmful if swallowed or absorbed through the Product Label and Directions for Use attached to 170. Refer to supplemental labeling under"Agricultural <br /> the skin. Avoid contact with skin, eyes, or clothing. the product for Agricultural Use Requirements in ac- Use Requirements" in the Directions for Use section <br /> Inhalation of the mists/vapors results in irritation to the cordance with the EPA Worker Protection Standard in for information about this standard. <br /> nose,throat and lungs. 40 CFR Part 170. DISCLAIMER <br /> A component(petroleum solvent)of this formulation: RECOMMENDATIONS FOR MANUFACTURING, IMPORTANT: WHILE THE DESCRIPTIONS, DE- <br /> Slightly irritating to the eyes. Prolonged contact with COMMERCIAL BLENDING, AND PACKAGING SIGNS, DATA AND INFORMATION CONTAINED <br /> skin may irritate and cause dermatitis. May aggravate HEREIN ARE PRESENTED IN GOOD FAITH AND <br /> an existingskin condition. Inhalation of vapor/aerosol or/aerosol j WORKERS: <br /> P <br /> concentrations(>I 000 ppm)are irritating to eyes and ! RESPIRATORY PROTECTION-Supplied air respira- BELIEVED TO BE ACCURATE, IT IS PROVIDEDFOR YOUR GUIDANCE ONLY. BECAUSE MANY <br /> respiratory tract, may cause headaches, dizziness, tors should be worn if large quantities of vapor are FACTORS MAY AFFECT PROCESSING OR AP- <br /> anesthesia, drowsiness, unconsciousness and other generated or prolonged exposure possible. PLICATION/USE, WE RECOMMEND THAT YOU <br /> central nervous system effects,including death. Small EYE PROTECTION-Chemical goggles when respira- MAKE TESTS TO DETERMINE THE SUITABIL- <br /> amounts aspirated into the respiratory system durihg 1 for does not provide eye protection. ITV OF A PRODUCT FOR YOUR PARTICULAR <br /> ingestion or vomiting may cause mild to severe pul- PROTECTIVE CLOTHING - Gloves and protective PURPOSE PRIOR TO USE. NO WARRANTIES <br /> monary injury,possibly progressing to death. clothing to minimize skin contact. OF ANY KIND, EITHER EXPRESS OR IMPLIED, <br /> A component of this product contains naphthalene. ( VENTILATION-Whenever possible,engineering con- INCLUDING WARRANTIES OF MERCHANTABILITY <br /> Ingestion of naphthalene results in cramps, nausea, trols should be used to-minimize the need for personal OR FITNESS FOR A PARTICULAR PURPOSE, <br /> vomiting, and diarrhea: listlessness, bladder irritation j protective equipment. ARE MADE REGARDING PRODUCTS DESCRIBED <br /> Database and format copyright©by VPC Acquisition Corporation.All rights reserved. <br />