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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREElIF300 C.NET 1
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<br /> ROUNDUPRemove to fresh air. I -_
<br /> ORIGINAL TM g Components Exposure Guidelines
<br /> Ingestion
<br /> Immediate offer water to drink. Isopropylamine salt No speck occupational exposure limit
<br /> Immediately of glyphosate has been established.
<br /> Herbicide Do NOT induce vomiting unless directed by medical
<br /> Surfactant No specific occupational exposure limit
<br /> Version: 1.2 personnel. has been established.
<br /> WO Effective date: 01/25/2001 If symptoms occur,get medical attention-
<br /> Water No specific occupational exposure limit
<br /> 1. PRODUCT AND COMPANY IDENTIFICATION Advice to doctors has been established.
<br /> This product is not an inhibitor of cholinesterase. Engineering controls
<br /> Product name: ROUNDUP ORIGINALne Herbicide Antidote
<br /> EPA Reg. No.: 524-445 i Treatment with atropine and oximes is not indicated. Have eye wash facilities immediately available at lo-
<br /> Product use: Herbicide cations where eye contact can occur.
<br /> Chemical name: Not applicable 5. FIRE FIGHTING MEASURES Eye protection
<br /> Synonyms: None If there is potential for contact:
<br /> Company Flash point Wear chemical goggles.
<br /> MONSANTO Company, 800 N. Lindbergh Blvd., St. Does not flash. I Skin protection
<br /> Louis,MO,63167 Extinguishing media 1 If repeated or prolonged contact:
<br /> ,"e Telephone: 800-332-3111,Fax: 314-694-5557 Recommended: Water, dry chemical,carbon dioxide Wear chemical resistant gloves.
<br /> Emergency numbers (CO2),foam Respiratory protection
<br /> FOR CHEMICAL EMERGENCY,SPILL,LEAK,FIRE, Unusual fire and explosion hazards No special requirement when used as recommended.
<br /> EXPOSURE,OR ACCIDENT Call CHEMTREC-Day None. When recommended, consult manufacturer of per-
<br /> or Night: 1-800-424-9300 toll free in the continental Environmental precautions: see section 6. sonal protective equipment for the appropriate type
<br /> U.S.,Puerto Rico,Canada,or Virgin Islands. For calls Hazardous products of combustion of equipment for a given application.
<br /> originating elsewhere: 703-527-3887(collect calls ac- Carbon monoxide(CO),nitrogen oxides(NOx),phos- 1 9. PHYSICAL AND CHEMICAL PROPERTIES
<br /> cepted). phorus oxides(PxOy) i
<br /> These physical data are typical values based on mate-
<br /> FOR MEDICAL EMERGENCY-Day or Night: 314 Fire fighting equipment fiat tested but may vary from sample to sample. Typ-
<br /> 694 4000(collect calls accepted). Self-contained breathing apparatus. ical values should not be construed as a guaranteed
<br /> 2. COMPOSITION/INFORMATION ON INGREDI- Equipment should be thoroughly decontaminated after analysis of any specific lot or as specifications for the
<br /> r. ENTS use. product.
<br /> Active Ingredient: Isopropylamine salt of N- 6. ACCIDENTAL RELEASE MEASURES
<br /> (phosphonomethyl)gtycine; (Isopropylamine salt of Personal precautions Form: Liquid
<br /> glyphosate} Use personal protection recommended in section 8. odour. Slight
<br /> Composition Environmental precautions
<br /> Flash pant Does not gash.
<br /> SMALL QUANTITIES:
<br /> %by weight
<br /> Low environmental hazard. Specificg � �ravi 1.1655 20'C/15.6'C
<br /> COMPONENT Gas No. (approximate) '. LARGE QUANTITIES:
<br /> ______-__. _----
<br /> Isopropylamine salt of 38641-94-0 41 Minimize spread. pH: 4.4-5.0
<br /> glyphosate Keep out of drains,sewers,ditches and water ways. Partition coefficient <0.000(active ingredient)
<br /> Surfactant s17s1-zs-z a Methods for cleaning up (log Pow):
<br /> SMALL QUANTITIES:
<br /> Water 7732-18-5 51 ! Flush spill area with water. 10. STABILITY AND REACTIVITY
<br /> Trade secret composition. LARGE QUANTITIES: Stability
<br /> OSHA Status:This product is hazardous according to Absorb in earth,sand or absorbent material. Stable under normal conditions of handling and stor-
<br /> the OSHA Hazard Communication Standard,29 CFR Dig up heavily contaminated soil. age.
<br /> 1910.1200. Collect in containers for disposal. Hazardous decomposition
<br /> 3. HAZARDS IDENTIFICATION Refer to section 7 for types of containers. Thermal decomposition: No data.
<br /> Flush residues with small quantities of water. Hazardous products of combustion: see section 5.
<br /> Emergency overview Minimize use of water to prevent environmental con- Materials to avoid/Reactivity
<br /> Appearance and odour(colour/form/odour): /Liq- tamination. Reacts with bases to liberate heat.
<br /> uid I Slight Refer to section 13 for disposal of spilled material. Reacts with galvanised steel or unlined mild steel to
<br /> WARNING! produce hydrogen,a highly flammable gas that could
<br /> Keep out of reach of children. 7. HANDLING AND STORAGE explode.
<br /> CAUSES SUBSTANTIAL BUT TEMPORARY EYE IN- Hazardous polymerization
<br /> JURY Handling Does not occur.
<br /> e. HARMFUL IF SWALLOWED Good industrial practice in housekeeping and personal 11. TOXICOLOGICAL INFORMATION
<br /> HARMFUL IF INHALED hygiene should be followed.
<br /> REFORMULATION IS PROHIBITED Avoid contact with skin and eyes. This section is intended for use by toxicologists and
<br /> SEE INDIVIDUAL CONTAINER LABEL FOR When using do not eat,drink or smoke. other health professionals.
<br /> REPACKAGING LIMITATIONS Wash hands thoroughly after handling or contact. Data obtained on product or on similar products are
<br /> Potential health effects Thoroughly clean equipment after use.
<br /> summarized below. Data obtained on active ingredient
<br /> Likely routes of exposure: Skin contact,eye contact Emptied containers retain vapour and product residue. are summarized below.
<br /> Eye contact,short term: Causes temporary eye irri- Observe all labelled safeguards until container is Acute oral toxici
<br /> ty
<br /> talion. cleaned,reconditioned or destroyed. Rat,LD50(limit test): >5,000 mg/kg body weight
<br /> Skin contact,short term: Not expected to produce Emptied containers retain vapour and product residue. Other effects: breathing difficulty, decreased activity,
<br /> +� significant adverse effects when recommended use FOLLOW LABELED WARNINGS EVEN AFTER CON- soft stools
<br /> instructions are followed. TAINER IS EMPTIED. Practically non-toxic.
<br /> Inhalation,short tens: Not expected to produce sig- Storage FIFRA category IV.
<br /> nificant adverse effects when recommended use in- Compatible materials for storage: stainless steel,alu- No mortality.
<br /> structions are followed. minium, plastic,fibreglass,glass lining Acute dermal toxicity
<br /> Refer to section 11 for toxicological and section 12 for Incompatible materials for storage: galvanised steel, Rat,LD (limit test): > mglkg body weight
<br /> ..r Target organs/systems
<br /> ans/systems: None.
<br /> environmental information unlined mild steel,see section 10. Other effects: None.
<br /> 4. FIRST AID MEASURES Keep out of reach of children.
<br /> Keep away from food,drink and animal feed. Practically non-toxic.
<br /> Eye contact Keep only in the original container. FIFRA category IV.
<br /> Immediately flush with plenty of water. Partial crystallization may occur on prolonged storage No mortality.
<br /> e. Acute Inhalation toxicity
<br /> Continue for at least 15 minutes. below the minimum storage temperature.
<br /> If easy to do,remove contact lenses. If frozen
<br /> If there are persistent symptoms, obtain medical ad- Target organs/systems: None.
<br /> ,place in warm room and shake frequently to Rat,LC50,4 hours,aerosol: 2.6 mg/L
<br /> put back into solution. Other effects: breathing difficulty,decreased activity,
<br /> vice. Minimum shelf life: 5ears.
<br /> Skin contact y local effects
<br /> Wash affected skin with plenty of water. g, EXPOSURE CONTROLS/PERSONAL PROTEC- Practically non-toxic.
<br /> Wash clothes before reuse TION FIFRA category IV.
<br /> Take off contaminated clothing,wristwatch,jewellery. Skin irritation
<br /> Inhalation Airborne exposure limits Rabbit,6 animals,OECD 404 test:
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