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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT VVWW.GREENBOOK.NET 1
<br /> TRIFLURALIN 4 EC AND/OR CHILLS;AND MUSCLE ACHES OR WEAK-
<br /> Helena Chemical Company NESS. IX.SPECIAL PRECAUTIONS
<br /> PH:901-761-0050 Other Hazard: INDIVIDUALS WITH KNOWN HY- Special precaution: KEEP OUT OF REACH OF
<br /> CHEMTREC:1-800424-9300 PERSENSITIVITY TO TRIFLURALIN SHOULD NOT CHILDREN. DO NOT STORE WITH FOOD, FEED.
<br /> Effective Date: 6-12-01 BE EXPOSED. INDIVIDUALS WITH ALLERGIC HIS- OR OTHER MATERIAL TO BE USED OR CON-
<br /> Product: TRIFLURALIN 4 EC TORY OR PRE-EXISTING DERMATITIS SHOULD SLIMED BY HUMANS OR ANIMALS. DO NOT CON-
<br /> USE EXTRA CARE IN HANDLING TRIFLURALIN. TAMINATE WATER SUPPLIES, LAKES, STREAMS,
<br /> I.IDENTIFICATION EMERGENCY AND FIRST AID PROCEDURES OR PONDS. DO NOT MIX WITH ANY MATERIAL
<br /> Chemical Name: TRIFLURALIN Swallowing: DO NOT INDUCE VOMITING!CALL A NOT MENTIONED ON THE PRODUCT LABEL.END-
<br /> Chemical Family: DINITROANILINE PHYSICIAN OR POISON CONTROL CENTER IMME- USE PRODUCT: THIS PESTICIDE IS TOXIC TO
<br /> Formula: NOT APPLICABLE, FORMULATED MIX- DIATELY. DO NOT INDUCE VOMITING OR GIVE FISH.DO NOT APPLY TO WATER OR WETLANDS.
<br /> TURE. ANYTHING BY MOUTH TO AN UNCONSCIOUS DRIFT OR RUN-OFF FROM TREATMENT AREAS
<br /> Synonyms: NONE PERSON- MAY BE HAZARDOUS TO AQUATIC ORGANISMS
<br /> CAS Number: SEE INGREDIENT STATEMENT, Skin: REMOVE CONTAMINATED CLOTHING. IN NEIGHBORING AQUATIC SITES.DO NOT CON-
<br /> SECTION III. WASH AFFECTED AREA WITH SOAP AND WA- TAMINATE WATER WHEN DISPOSING OF EQUIP-
<br /> EPA Number. 5905-519 TER. IF IRRITATION DEVELOPS OR PERSISTS, MENT WASHWATER OR RINSATE.
<br /> CONSULT A PHYSICIAN. Other precaution:
<br /> 11.PHYSICAL DATA Inhalation: REMOVE FROM EXPOSURE AREA. IF A) RCRA HAZARDOUS WASTE NUMBER: NAPH-
<br /> Boiling Point: >363 DEGREES F. BREATHING HAS STOPPED, PERFORM ARTIFI- THALENE(U165)
<br /> Freezing Point: <41 DEGREES F. CIAL RESPIRATION.OBTAIN MEDICAL ATTENTION B) SARA TITLE III, SECTION 313: TRIFLURALIN
<br /> Spec Gravity: 1.068 GMS/CC IMMEDIATELY. (44.50%),NAPHTHALENE(4.2%).
<br /> Vapor Pressure: 0.5 MM HG @ 20 C. Eyes: FLUSH EYES WITH WATER FOR 15 MIN- C)CERCLA REPORTABLE QUANTITY:2.5 GALLON
<br /> Vapor Density: <4.6 UTES, HOLDING EYELIDS OPEN. IF IRRITATION D) 49 CFR 172.101, APPENDIX A: HAZARDOUS
<br /> Solubility: EMULSIFIES DEVELOPS OR PERSISTS, CONSULT A PHYSI- SUBSTANCE
<br /> Volatiles: APPROXIMATE 25% CIAN. E)49 CFR 172.101,APPENDIX B:MARINE POLLU-
<br /> Evaporation: 0.03 Notes to Physician: NO SPECIFIC ANTIDOTE, TANT
<br /> Melting Point: NOT APPLICABLE GIVE SUPPORTIVE CARE.TREATMENT BASED ON X.SHIPPING INFORMATION
<br /> Appearance: CLEAR, DEEP ORANGE LIQUID, JUDGEMENT OF THE PHYSICIAN IN RESPONSE
<br /> � AROMATIC ODOR TO REACTIONS OF THE PATIENT. THIS PROD- Shipping name: RQ, ENVIRONMENTALLY HAZ-
<br /> UCT CONTAINS AN AROMATIC HYDROCARBON ARDOUS SUBSTANCES, LIQUID,N.O.S.,POLLUTANT III.INGREDIENTS AND CAN BE EXTREMELY HARMFUL IF SWAL- ,ERG , 9, UN3082, PG III, MARINE POLLUTANT
<br /> LOWED. IF THIS HAPPENS AND THE PATIENT "ERG#171"
<br /> IS CONSCIOUS, IMMEDIATELY ADMINISTER AC- Hazard Class: CLASS 9
<br /> Material Number Percent TLV Hazard TIVATED CHARCOAL (6-8 HEAPING TEASPOON- Identification No: UN3082
<br /> ` TRIFLURALIN 01582-09-8 43.00 NOT SKIN a FULS)WITH WATER.DO NOT GIVE ANYTHING BY Labels Required: CLASS 9
<br /> (ALPHA, ESTAB- EYE IR- MOUTH TO AN UNCONSCIOUS PERSON.GASTRIC Placarding: UN3082
<br /> ALPHA LISHED RITANT,KINLAVAGE WITH A CUFFED ENDOTRACHEAL TUBE Freight Class: COMPOUND,WEED KILLING,LIQ-
<br /> ALPHA-
<br /> sENSI- TO PREVENT ASPIRATION SHOULD BE COM- UID, (HERBICIDES), N.O.I. (NMFC ITEM 50320,
<br /> 2,6-DINTIRO- TIZER PLETED WITHIN 15 MINUTES. IN THE ABSENCE CLASS 60)
<br /> N,N- OF DEPRESSION, CONVULSIONS, OR IMPAIRED
<br /> DIPROPYL-P- GAG REFLEX,VOMITING CAN BE INDUCED WITH
<br /> TOLUIOWE) Chemical Name Equivalent R.0.
<br /> AROMATIC 54742-94-5 42.00 50 SKIN 1 A BLUNT INSTRUMENT OR FINGER. MAKE CER- :
<br /> HYDROCAR- MG/M3 &EYE TAIN VOMITUS IS NOT INHALED BY RAISING HIPS TRIFLURALIN-CAS#1582-09-8 10 LBS/4.54 KG
<br /> BON IRRITANT HIGHER THAN HEAD. IF PATIENT IS UNCON-
<br /> INERT IN- 5.00 NOW NOW NAPHTHALENE-CAS#0091-20-3 100 LB/45.4 KG
<br /> e� GREDIENTS HAZAR- HAZAR- SCIOUS,DO NOT INDUCE VOMITING. Xt.GENERAL PRODUCT INFORMATION
<br /> DOUS DOUS
<br /> IV.FIRE AND EXPLOSION HAZARD V1.REACTIVITY National Fire Protection Association Rating:
<br /> Stability: Stable (Rating level:4-Extreme,3-High,2-Moderate,1-Slight,
<br /> Flash Point: >200 DEGREES F. 0-Minimum)
<br /> Conditions to Avoid: AVOID EXCESSIVE HEAT
<br /> Autoignition Temp: >800 DEGREES F. Health: 2
<br /> ` AND SOURCES OF IGNITION.
<br /> Flammable Limit: 1.890-11.7% i Fire: 2
<br /> Extinguishing Media: DRY CHEMICAL, CARBON Polymerization: Will Not Occur Reactivity: 0
<br /> Conditions to Avoid: NONE CURRENTLY KNOWN.
<br /> DIOXIDE,WATER AND FOAM. S.A.R.A.Title III Hazard Classification: (Yes/No)
<br /> Special Fire Fight Proc: WEAR SELF-CONTAINED Incompatibility material: AVOID CONTAMINA- immediate(Acute)Health: Y
<br /> BREATHING APPARATUS WITH FULL FACE PIECE TION WITH STRONG OXIDIZING AND REDUCING Delayed(Chronic)Health: Y
<br /> ,,. OPERATED IN PRESSURE DEMAND OR OTHER AGENTS OR STRONG ALKALI. Sudden Release of pressure: N
<br /> POSITIVE PRESSURE MODE AND FULL FIRE Hazardous Combustion: FLUORINE COMPOUNDS Fire: Y
<br /> FIGHTING PROTECTIVE CLOTHING. AND OXIDES OF NITROGEN.INCOMPLETE COM- ( Reactive: N
<br /> Fire and Expl Hazard: PRODUCT CLASSIFIED AS BUSTION MAY LEAD TO CARBON MONOXIDE.
<br /> A CLASS IIIB COMBUSTIBLE LIQUID ACCORDINGMail inquiries to: 225 Schilling Blvd., Suite 300 Col-
<br /> TO NFPA CODE 30. CLOSED CONTAINERS MAY ; VII.SPILL OR LEAK PROCEDURES lierville,TN 38017
<br /> Helena Chemical Company believes that the data con-
<br /> RUPTURE DUE TO PRESSURE BUILD-UP WHEN Spill or Leak Proc: ROPE OFF CONTAMINATED
<br /> SUBJECTED TO EXCESSIVE HEAT OR FIRE. AREA & CONTAIN THE SPILL. ABSORB THE as herein factual. This data is not
<br /> MATERIAL WITH CLAY OR SAWDUST AND PUT as a warranty or representation of legal responsibility.
<br /> to be taken
<br /> V.HEALTH HAZARD It is offered solely for your consideration,investigation
<br /> INTO SUITABLE CONTAINERS FOR DISPOSAL. and verification. VID 8.7.03
<br /> Carcinogen Information: NONE CURRENTLY DO NOT CONTAMINATE WATER WITH WASTE OR
<br /> KNOWN CLEANUP MATERIAL. THIS MATERIAL IS TOXIC
<br /> ACUTE EFFECTS OF OVER EXPOSURE TO FISH.
<br /> Swallowing:TRIFLURALIN IS CONSIDERED ONLY Waste Disposal Method: THIS MATERIAL MUST
<br /> SLIGHTLY TOXIC;HOWEVER,THE SOLVENT MAY BE DISPOSED OF ACCORDING TO FEDERAL,
<br /> CAUSE POISONING IF INGESTED. ORAL LD50 STATE,OR LOCAL PROCEDURES UNDER THE RE-
<br /> (RATS)IS GREATER THAN 10,000 MG/KG. SOURCE CONSERVATION AND RECOVERY ACT.
<br /> Skin Absorption: HARMFUL IF ABSORBED
<br /> THROUGH SKIN.AVOID CONTACT WITH SKIN OR VIII.SPECIAL PROTECTION INFORMATION
<br /> CLOTHING.
<br /> Inhalation: HIGH VAPOR/AEROSOL CONCENTRA- Respiration: IF WORK AREA IS NOT WELL VEN-
<br /> TIONS ARE IRRITATING TO THE RESPIRATORY TILATED.USE A NIOSH RESPIRATOR APPROVED
<br /> TRACT. FOR ORGANIC SOLVENT VAPORS.
<br /> Skin contact: CAUSES SLIGHT TO MODERATE IR- Ventilation: MAINTAIN ODOR FREE ATMO-
<br /> RITATION.REPEATED CONTACT CAN SENSITIZE SPHERE. USE MECHANICAL DEVICES IF VENTI-
<br /> THE SKIN TO THIS MATERIAL. LATION IS NOT ADEQUATE.
<br /> Eye Contact: CAUSES IRRITATION WITH POSSI- Gloves: IMPERVIOUS GLOVES.
<br /> BLE TISSUE AND CORNEAL OPACIFICATION. Eyes: CHEMICAL WORKERS GOGGLES.
<br /> i Chronic Effects: SKIN IRRITATION AND RASH: Other: USE COVERALLS, IMPERVIOUS APRON 1
<br /> NAUSEA, VOMITING, CRAMPING, & DIARRHEA: AND FOOTWEAR.A SAFETY SHOWER AND EYE
<br /> EYE IRRITATION;DIZZINESS,HEADACHE, FEVER WASH SHOULD BE PROVIDED IN WORK AREA.
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