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<br /> MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
<br /> offer empty container for recycling or reconditioning,or TWA Time Weighted Average
<br /> ass 9. PHYSICAL AND CHEMICAL PROPERTIES puncture and dispose of in a sanitary landfill or by in- USEPA U.S.Environmental Protection Agency
<br /> cineration,or,if allowed by State and local authorities, This Material Safety Data Sheet (MSDS) serves dif-
<br /> NOTE:Physical data are typical values,but may vary !
<br /> from sample to sample. A typical value should not be by burning. If burned,stay out of smoke, ferent purposes than and DOES NOT REPLACE OR
<br /> construed as a guaranteed analysis or as a specifica- 14. TRANSPORTATION INFORMATION MODIFY THE EPA-ACCEPTED PRODUCT LABEL-
<br /> bon. ING(attached to and accompanying the product con-
<br /> Physical Appearance: Reddish brown to dark brown .l NOTE: Information is for surface transportation of tainer). This MSDS provides important health,safety
<br /> liquid. package sizes generally offered and does not address and environmental information for employers,employ-
<br /> Odor: Characteristic organic amine and phenolic. regulatory variations due to changes in package size, ees,emergency responders and others handling large
<br /> PH:Approximately 7 to 9mode of shipment or other conditions. quantities of the product in activities generally other
<br /> Specific Gravity: Approximately 1.155 @ 20°C Packages containing less than 26.3 gallons of this than product use,while the labeling provides that in-
<br /> Water Solubility: Soluble. product are generally not regulated. For packages formation specifically for product use in the ordinary
<br /> Isis Melting Point Range: Not Available. containing 26.3 gallons or higher: course.
<br /> DOT Proper Shipping Name: ENVIRONMENTALLY Use, storage and disposal of pesticide products are
<br /> Boiling Point Range: Not Available. Expected to be
<br /> similar to water: > 100°C HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4-D regulated by the EPA underthe authority of the Federal
<br /> Vapor Pressure: G1 x 10-' mm Hg @ 26'C(data SALTS),RQ(2,4-D SALTS) Insecticide, Fungicide, and Rodenticide Act(FIFRA)
<br /> on 2,4-D dimethylamine salt) DOT Hazard Class f I.D.No.: 9/UN3082 through the product labeling, and all necessary and
<br /> DOT Label: Class 9 appropriate precautionary,use,storage,and disposal
<br /> Miss Molecular Weight: 266.1 (data on 2,4-D dimethy- U.S. Surface Freight Classification: Weed killing information is set forth on that labeling. It is a violation
<br /> lamine salt) compound,N.O.I.B.N. of federal law to use a pesticide product in any manner
<br /> 10. STABILITY AND REACTIVITY not prescribed on the EPA-accepted label.
<br /> 15. REGULATORY INFORMATION Although the information and recommendations set
<br /> Chemical Stability: This material is stable under nor-
<br /> mal handling and storage conditions described in Sec- Federal Regulations: forth herein(hereinafter"Information") are presented
<br /> tion 7. TSCA Inventory:This product is excepted from TSCA in good faith and believed to be correct as of the
<br /> Conditions To Be Avoided None known because it is solely for FIFRA regulated use. date hereof, Nufarm, Inc. makes no representations
<br /> Incompatibility With Other Materials:known
<br /> Stroxidiz- SARA Hazard Notification: as to the completeness or accuracy thereof. Informa-
<br /> Hazard Categories Under Criteria of SARA Title III tion is supplied upon the condition that the persons
<br /> ing agents: bases,acids. Rules(40 CFR Part 370): receiving same will make their own determination as
<br /> Hazardous Decomposition Products: i to its suitability for their purposes prior to use. In no
<br /> aee Decomposition Type: Thermal 'i event will Nufarm, Inc. be responsible for damages
<br /> Decomposition Products: Hydrogen chloride,oxides Rel....f Aeute Chrome of any nature whatsoever resulting from the use or of
<br /> of carbon,nitrogen and sulfur. Fire: Reactive: Pressure: Heakh: Health:
<br /> 9 I reliance upon Information. NO REPRESENTATIONS
<br /> Hazardous Polymerization: Does not occur. No No No Yes Yes OR WARRANTIES,EITHER EXPRESS OR IMPLIED,
<br /> ..-- ...... OF MERCHANTABILITY, FITNESS FOR A PARTIC-
<br /> a.
<br /> 11. ACETIC ACID, (2,4-DICHLOROPHENOXY)-, CAS TOXICOOLOGICAL INFORMATION Section 313 Toxic ChemicULAR PURPOSE OR OF ANY OTHER NATURE ARE
<br /> �. LO
<br /> Toxicological Data: MADE HEREUNDER WITH RESPECT TO INFORMA-
<br /> Except as noted, data from laboratory studies con- NO.9475-7(38.9%equivalent by weight in product) TION ORTHE PRODUCTTO WHICH INFORMATION
<br /> ducted on this product are summarized below. Reportable Quantity(RQ)under U.S.CERCLA: REFERS.
<br /> Eye Irritation: Severely irritating(Rabbit). WEEDAR®is a registered trademark of Nufarm,Inc.
<br /> Skin Irritation: Minimally irritating(Rabbit). Ingredient RQ i VID 5.14.03
<br /> ses Dermal: Slightly toxic. (Rabbit LD50 1544 mg/kg).
<br /> Inhalation: Slightly toxic.(Rat 4-hr LC50: >3.5 mg/L) ACETIC
<br /> TIICrtLoaoPHENoxv)- 100lbs
<br /> gallons ofthisproduct,26.3
<br /> (Data on similar product)
<br /> Oral: Slightly toxic. (Rat LD50 1161 mg/kg). Selected State Regulations:
<br /> This product contains substances that are considered This product contains the following components that i
<br /> r
<br /> to be probable or suspected human carcinogens as are regulated under California Proposition 65:
<br /> follows: i
<br /> Ingredient
<br /> Level(ug/day)nt Cancer Reproductive �
<br /> Name List List California Nufarm
<br /> Regulatory Agency Not Not Not Not Not
<br /> tam Listing As Carcinogen
<br /> Applicable Applt Applicable applicable AppIL
<br /> Ingrodients cable cable
<br /> Name OSHA IARC NTP ACGIH
<br /> 16. OTHER INFORMATION
<br /> Chbropnenoxy No 2B No No
<br /> herbiddes I i National Fire Protection Association(NFPO)Haz-
<br /> a. (Also see Section 3.) and Ratings:
<br /> 12. ECOLOGICAL INFORMATION
<br /> Aquatic TOxICi I Ratings for This Product Key to Ratings
<br /> Data on 2,4-D dimethylamine salt: 2 Health Ha rd 0 Minimal
<br /> a� 1 Rammatiffity, 1
<br /> Slight
<br /> 96-hr LC50 Blue di 524 m /I 0 Instability 2 Moderate i
<br /> 96-hr LC50 Rainbow Trout: 250 mg/I 3 Serious
<br /> 48-hr ECso Daphnia: 184 mg/I 4 severe
<br /> Avian Toxicity: Abbreviations and Acronyms Not Defined Else-
<br /> Data on 2,4-D dimethylamine salt: ( where:
<br /> Bobwhite Quail Oral LD50: 500 mg/kg ACGIH American Conference of Governmental Indus-
<br /> Mallard Duck 8-day Dietary LCso: >5620 ppm trial Hygienists
<br /> Environmental Fate: ANSI American National Standards Institute
<br /> In laboratory and field studies,2,4-D DMA salt rapidly CERCLA Comprehensive Environmental Response,
<br /> dissociated to parent acid in the environment. The Compensation and Liability Act
<br /> typical half-life of the resultant 2,4-0 acid ranged from DOT Department of Transportation
<br /> a few days to a few weeks. FIFRA Federal Insecticide,Fungicide and Rodenticide
<br /> Act
<br /> 13. DISPOSAL CONSIDERATIONS i IARC International Agency for Research on Cancer
<br /> Waste Disposal Method: I MSHA Mine Safety and Health Administration
<br /> Pesticide wastes are acutely hazardous. Improper dis- NIOSH National Institute for Occupational Safety and
<br /> ass posal of excess pesticide is a violation of Federal Law Health
<br /> and may contaminate ground water. If these wastes NTP National Toxicology Program
<br /> cannot be disposed of by use according to label instruc- ! OSHA Occupational Safety and Health Administration
<br /> tions, contact your State Pesticide or Environmental PEL Permissible Exposure Limit
<br /> Control Agency,or the Hazardous Waste representa- SARA Superfund Amendments and Reauthorization
<br /> tive at the nearest EPA Regional Office for guidance. Act of 1986
<br /> Container Handling and Disposal: STEL Short Term Exposure Limit
<br /> Do not reuse empty container. Triple rinse(or equiv- TLV Threshold Limit Value
<br /> alent)adding rinsate to application equipment. Then TSCA Toxic Substances Control Act
<br /> Database and format copyright Oc by C&P Press. All rights reserved. Powered by C&P Press.
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