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C A M B R I A Ms. Lori Duncan <br /> September 9,2005 <br /> Another method to apply hydrogen peroxide to the subsurface would be to install temporary, <br /> direct-push probes to the desired depth intervals instead of using permanent groundwater <br /> monitoring wells. The hydrogen peroxide can be injected into the probes using a pump to <br /> provide maximum infiltration of the solution into the subsurface. This method can be used to <br /> remediate unsaturated soils. If this method is used, confirmation borings would be required. <br /> Feasibility and Cost-Effectiveness: Implementing hydrogen peroxide injection at the site using <br /> the siphon method would cost an estimated$35,000 to$40,000 for the first year. This estimate is C'L(� <br /> based upon installing three additional wells and/or direct-push probes to be used as injection n <br /> points in areas of remaining source material. These proposed wells and existing wells VEW-2 1` <br /> and MW-3 would be injected with hydrogen peroxide on a monthly basis for 1 year. One well <br /> © volume of 7.5% hydrogen peroxide solution would be injected per well per month. Based on <br /> monitoring data results, follow-up injections or additional injection points could be required to <br /> meet the approved groundwater clean-up goals. To verify soil clean-up,confirmation soil borings <br /> would be required. The cost of four confirmation soil borings is estimated at$10,000. <br /> Hydrogen peroxide injection may provide hydrocarbon mass reduction at a relatively low cost. <br /> The addition of a liquid solution of hydrogen peroxide to soil may potentially cause leaching of <br /> hydrocarbons in soils to groundwater. Finally, the effectiveness of hydrogen peroxide injection <br /> has been demonstrated in bench-scale studies at other sites, but the reliability and costs remain <br /> uncertain when compared to other technologies. Additionally, hydrogen peroxide injections <br /> alone would not address migration of the groundwater plume beneath the site. <br /> Recommendation: With the uncertainties regarding effectiveness, potential hydrocarbon leaching <br /> to groundwater, total costs, and the lack of hydraulic control, the potential drawbacks do not <br /> justify the estimated lower cost. We do not recommend this remedial alternative. <br /> SVE with AS <br /> SVE is a common remediation technology applied to address gasoline fuel impacts to unsaturated <br /> soil at UST sites. SVE is most effective in moderate to high permeability soils. SVE involves <br /> applying a vacuum to wells to extract hydrocarbon-bearing vapors from the vadose zone and <br /> capillary fringe area. Extracted hydrocarbons are typically treated by granular activated carbon <br /> (GAC), catalytic or thermal oxidizers, or internal combustion engines. Additionally, SVE can <br /> improve or protect groundwater quality by removing source area hydrocarbons, by encouraging <br /> hydrocarbon diffusion from groundwater, and by delivering oxygen to the subsurface. Increased <br /> oxygen concentrations can stimulate naturally occurring hydrocarbon biodegradation in soil and <br /> groundwater. <br /> SVE system components would include appropriately constructed SVE wells, vapor conveyance <br /> piping, a vapor and liquid separator, a vapor extraction device, and a vapor treatment device. The <br /> vapor extraction device (blower) would be sized based on the radius of influence and applied <br /> 14 <br />