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MIS
<br /> No. 317 4/86 TOLUENE
<br /> SEMON 6. HEALTH HAZ.ARID IN'ORNIATION IT.,V
<br /> ►olucm is not consroereo a cammogen 0'y erre r I '•,►r Kt„or WnA.. +•^777 tn; apor.,0. toluene may cause ;
<br /> irritation of the eyes,nose, upper respiratory tract,and skir Exposure to 200 ppm for 8 hours causes mild fatigue,
<br /> weakness, confusion, lacrimation(tearing) and paresthesia(a sensation of prickling,tingling,or creeping on the skin that
<br /> has no objective cause). Exposure to higher concentrations may cause headache,nausea,dizziness,dilated pupils,and
<br /> euphoria,and,in severe cases,may cause unconsciousness and death. The li3uid is irritating to the eyes and skin, Contact
<br /> with the eves may cause transient corneal damage,conjunctival irritation,and bums if not promptly removed. Repeated
<br /> andlor prolonged contact with the skin may cause drying and cracking. It may be absorbed through the skin in toxic
<br /> amounts. Ingestion causes irritation of the gastrointestinal tract and may cause effects resembling''t•those from inhalation of
<br /> the vapor. Chronic overexposure to toluene may cause reversible kidney and liver injury. FIRS AID: E)T Q2L,7L T:
<br /> Immediately flush eyes,including under eyelids,with running water for at least 15 minutes. Get medical attention if irritation
<br /> persists., SKIN CONTACT: Immediately flush skin(for at least 15 minutes)while removing contaminated shoes and
<br /> clothing. Wash exposed area with soap and water. Get medical attention if irritation persists or if a large area has been
<br /> exposed." IN A .ATION: Remove victim to fresh air. Restore and/or support breathing as required.Keep victim warm and
<br /> quiet.Get medical help.` INGESTION: Give victim 1 to 2 glasses of water or milk.Contact a poison control center. Do not
<br /> induce vomiting unless directed to do so.Transport victim to a medical facility.Never give anything by mouth to a person
<br /> who is unconscious or convulsing. ° GET MEDICAL ASSISTANCE.In plant,paramedic,community. Get medical help
<br /> for further treatment,observation, and support after first aid,if indicated.
<br /> SECTION 7. SPILL. LEAK, AND DISPOSAL PROCEDURES
<br /> SP . it LAK: Notify safety personnel of large spills or leaks. Remove all sources of heat and ignition. Provide maximum
<br /> explosion-proof ventilation. limit access to spill a=to necessary personnel only. Remove leaking containers to safe
<br /> place if feasible. Cleanup personnel need protection against contact with liquid and inhalation of vapor(see sect. 8),
<br /> WASTE DTSPOSA Absorb small spills with paper towel or vermiculite.Contain large spills and collect if feasible,or
<br /> absorb with vermiculite or sand. Place waste solvent or absorbent into closed containers for disposal using nonsparking
<br /> tools. Liquid can be flushed with water to an open holding area for handling. Do not flush to sewer,watershed,or waterway.
<br /> COMMENTS: Place in suitable container for disposal by a licensed contractor or burn in an approved incinerator.Consider
<br /> reclaiming by distillation.Contaminated absorbent can be buried in a sanitary landfill. Follow all Federal,state,and local
<br /> regulations. TLm%: I00-10 ppm Toluene is designated as a hazardous waste by the EPA. The EPA(RCRA)HW No.is
<br /> U220(40 CFR 261). The nportable quantity(RQ)is 1000 lbs1454 kg(40 CFR 117).
<br /> SECTION S. SPECIAL PROTECTION INFORMATION
<br /> Provide general and local exhaust ventilation to meet TLV requirements.Ventilation fans and other electneal service must be
<br /> nonsparking and have an explosion-proof design. Exhaust hoods should have a face velocity of at least 100 lfm(linear feet
<br /> per minute)and be designed to capture heavy vapor. For emergency or nonroutine exposures where the TLV may be exceeded,
<br /> use an organic chemical cartridge respirator if concentration is less than 200 ppm and an approved canister gas mask or self-
<br /> contained breathing apparatus with full facepiece if concentration is greater than 200 ppm.
<br /> Safety glasses or splash goggles should be wom in all work areas. Neoprene gloves,apron,face shield,boots,and other
<br /> appropriate protective clothing and equipment should be available and worn s necessary to prevent skin and eye contact
<br /> Remove contaminated clothing immediately and do not wear it unt'it has been properly laundered.
<br /> Eyewash stations and safety showers should be readily available in use and handling areas.
<br /> Contact lenses pose a special hazard;soft lenses may absorb irritants and all lenses concentrate them
<br /> SECTION 9. SPECIAL PRECAUTIONS AND COMMENTS
<br /> ST�ORaCyF SEGREGATE h': Store in a cool,dry,weII-ventilated arca away from oxidizing agents,heat,sparks,or open flame.
<br /> Storage areas must meet OSHA requirements for class IB flammable liquids.Use metal safety cans for handling small amounts.
<br /> Protect containers from physical damage. Use only with adequate ventilation.Avoid contact with eyes,skin,or clothing.Do
<br /> not inhale or ingest. Use caution when handling this compound because it can be absorbed through intact skin in toxic
<br /> amounts. M:CI L t•ANDI_TN /SR AGE.: Ground and bond metal containers and equipment to prevent static spans when
<br /> making transfers. Ds not smoke in use or storage areas.Use nonsparking tools. ENGTNEERTNG CONTROLS: Preplacement
<br /> and periodic medical exams emphasizing the liver,kidneys,nervous system,lungs,hears,and blood should be provided.
<br /> Workers exposed to concentrations greater than the action level(50 ppm)should be examined at least once a year.Use of
<br /> alcohol can aggravate the toxic effects of toluene.
<br /> COMMEMEN7 : Emptied containers contain product residues. Handle accordingly!
<br /> Toluene is design=d as a hazardous substance by the EPA(40 CFR 116). 66T Classification:Flammable liquid. UN1294.
<br /> Data Sourcc(s)Code: 7-9, 12, 16,20,21,24,26,34,81,82. CR
<br /> rudgements as to the suttee'ihty of rsforru:ion heron for prrehasees purposes Approvals �•rr:s G toGea, frry(n,
<br /> arta necesw0v nur:hasees respombirnr 7hertfort,although rtwonabic tars
<br /> has boon ukea,o Inc preps�on of au:fi u:fomsion,Gemurn Publrs'unr Corp. Indust. Hy�rene/Safety' /
<br /> extends no wx.Tru�uea,r,.6=no reprseouuoas and=urw no rtspoasrbirtty as e /B Lo
<br /> to the acaxacy orruttabiLly of such inforrauoa for epphexuon to puchasefs
<br /> mteodedpurpoaesorforC45"quencaofit:we. I Medical Rc.iem
<br /> C 'rUtN G 1M 04msua Nbltthrnr Corpoream
<br /> +.:>casmvcut u,e v rgrcductn:u7:6wt tie pre,airYs pemvmm a Fdr>Drea Copyright CD April 1, 1986
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