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NO.- ?ffa <br /> SECTION VI. HEALTH HAZARD INFORMATION '1V 5 ppm.Ceiling Level (as HCI) <br /> queous HCl and its vapors are strong i ritants of the eyes, mucous memaranes,• and skin. <br /> Severity of eye in ury from splashes from irritation to severe burns ) depends qn <br /> quantity, cone. an duration of contact. Excessive acute exposure to C1 va ors mists <br /> promptly irritates the upper respiratory tract and can result in coughing, purning of <br /> the throat, choking sensation and, if inhaled deeply, pulmonary edema. Prolonged or <br /> repeated low level exposure may cause teeth erosion. Skin exposure can cause burns; <br /> repeated or prolonged exposure to .dilute soln, may cause dermatitis. Ingestion can <br /> cause severe burns and possible laryngeal spasm. FIRST AID: <br /> Eye Contact: Contact physician! Immediately flush with running water min, <br /> xnc v ng under eyelids. <br /> Skin Contact: Flush affected area well with water. Remove grossly contaminated <br /> c of ng under safety shower. Get medical help if large skin area contacted or - <br /> if irritation persists. <br /> Inhalati,)n: Remove to fresh air. Restore and/or support breathing as needed. Use 0 <br /> 7;Fierapy`for coughing, difficult breathing. Get medical help. Keep warm and at reit. <br /> esest�ion�: If victim is conscious, give 2-3 glasses of water, then milk of magnesia or <br /> -.3mewater. Contact physician! Do not induce vomitinttl <br /> SECTION VII. SPILL, LEAK, AND DISPOSAL PROCEDURES <br /> Report large spills to safety personnel. Evacuation may be needed; keep upwind. Remove <br /> sources of ignition if )i is a hazard. Provide optimum ventilation. Those involved <br /> in clean-up of large spi9ls must use full protective clothing, boots, and self-contained <br /> breathing apparatus. <br /> mall spills and residues can be covered with excess of a mixture of soda ash and slaked <br /> line to neutralize, and the slurry picNed up for landfill burial or flushed with mush <br /> water. <br /> ontain large spills. Collect or flush with water to holding area for neutralization. <br /> Do not flush directly to sewer or surface waters. <br /> DISPOSAL: Dispose of acid via licensed contractor or neutralize with limestone, soda <br /> asn or slaked lime. F1lushir, to sewer depends on allowable neutral salt concentrations �. <br /> aciedfcouneutra�ize aQka .ineewaste�,State and Loca u a4n 3°sna006rleSe(4�fCi�sttei7 <br /> ww I SECTION VIIi. SPECIAL PROTECTION INFORMATION <br /> Provide adequate exhaust ventilation to meet TLV requirements. Face velocity of hoods <br /> should exceed 100 lfm. Use approved respirator or self-contained breathing apparatus <br /> for emergency or non-routine conditions with full facepiece above 50 ppm. <br /> Those handling hydrochloric acid should use protective clothing and equipment to prevent <br /> body contact with the liquid. Use rubber gloves or gauntlets, apron, boots, long <br /> sleeved shirt, body suit, etc. Use chemical safety goggles and/or face shield for eye <br /> protection _,ainst splashing of acid, <br /> An eyewash station, washing facilities, a^.d safety shower must be readily available to <br /> areas of use and handling. <br /> SECTION IX, SPECIAL PRECAUTIONS AND COMMENTS <br /> Store closed containers out of direct sunlight, in a clean, cool, open or well-ventilated <br /> area as:av from oxidizing agents, away from alkaline materia3 and sources of heat. Area <br /> should have acid resistant floor and approved drainage. Protect containers from physical <br /> damage. Use nonsparking tools in areas around tanks and pipes where hydrogen might be <br /> generated. <br /> Use with good ventilation, Avoid inhalation of HCI vapors. Odor of HC1 gives adequate <br /> warning for a prompt voluntary withdrawal from excessive exposure. Do not get in eyes <br /> or on skin or clothing. Wash thoroughly after handling. <br /> Provide emergency neutralization materials and equipment near storage and use areas. <br /> DOT Classification: CORROSIVE KATERIAL I.Q. No. UN1789 Label: CORROSIVE <br /> I`tO Class 8 <br /> DATA SOURCE(S)CODE: 1-12,14-16,27,31,34,37.38,47-49 <br /> A,Cg s u a ev w++alr a��a^vim�•^ a CU WS WPCw ••wwu.. APPROVALS MIS,CRD <br /> 1.iLR`Y4111 IM Ob• IJ'W,1'^�411>•HM{i'.nIIi ON^IVa^•W:^K�•1.On 1N <br /> r,enrw.y;y Gwr^vuo.wgCaov>»a+onorosro�u•wdn m/rsrolwwre►.rvw <br /> INDUST.HYGIENE%SAFETY <br /> asw•w ro nureo+.r�a a mo Ict�xr d w.uae.o wen rna•vm^pr vpca•a.c av L (,^•+-Pk= moo, <br /> ev:,� V+ a.m..o>•i r�+,.e..e.e.+ai•1w MEDICAL REVIEW <br /> 15 June 1984 <br /> GENT UM PUBLISHING <br /> 1 . <br /> 4 <br /> .espd� <br />