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N <br /> CLEARWA`I'ER <br /> c F 'LP 13P <br /> highly impacted zones. Additional details about chemical oxidants and injection are supplied in <br /> j; Attachment 2. <br /> ISCO was not considered in the 2002 CAP as an option because of regulatory policies of the <br /> Central Valley Regional Water Quality Control Board (CVRWQCB), which limited subsurface <br /> chemical injection at that time. A permit will be required for underground injection of chemical <br /> oxidants into the saturated zone. Clearwater and the Responsible Party (Floyd Barnes) would <br /> apply to become an "enrollee" under General Permit # R5-2008-0149, issued by the <br /> CVRWQCB. As such, a copy of this report is being sent to the CVRWQCB for their <br /> information. The terms of this general permit and the notice-of-intent-to-comply information are <br /> included in Attachment 3. <br /> To gain a more effective radius of influence, a temporary dewatering system will be used both to <br /> create a hydraulic control and to dewater the saturated soil interval within the injection zones. <br /> Using groundwater extraction for hydraulic control, a system of temporary extraction points will <br /> be installed and connected to a liquid ring pump to dewater upgradient and downgradient of the <br /> source area. The details and location of the temporary dewatering system and injection points, <br /> will be the focus of a future remediation action plan (RAP), which is recommended to be created <br /> after approval of this CAP by S7CPHS-EHD. <br /> Based on the Site Conceptual Model, across the site, the treatment zone is generally located <br /> between 20 and 25 feet below ground surface (bgs), with several locations reporting olfactory <br /> detections to 34 feet bgs from the 1997 and 2000 soil investigation and well installation events, <br /> respectively (see figures in Attachment 4). Table 3 provides well construction data for all wells <br /> at the site. The dewatering system would be placed both upgradient and downgradient of the <br /> injection points, at a point within the effective hydraulic radius to maximize extraction of <br /> groundwater impacted with hydrocarbons desorbed via ISCO activity. In reference to the Site <br /> Conceptual Model (SCM) of 2009, there are likely to be two major zones at the site of sorbed- <br /> phase impacts (although the lack of data points between these two areas may mean that they are <br /> one large area). Area A includes the area around the former underground storage tank (UST), <br /> i and Area B includes the area between wells IW-6 and IW-12, with AS-1 being at the western <br /> jedge of Area B . These areas may be horizontally contiguous, but data gaps between them <br /> preclude this conclusion. Chemical oxidation injection points would need to be located in both <br /> zones, with a dewatering system across both areas. <br /> The need for soil samples for Bench Testing and the need for data between MW-4 and MW4 <br /> dictate a soil sampling event using direct push technology (DPE) equipment in this middle area. <br /> OVERVIEW OF ISCO TECHNOLOGY <br /> 1r4-Situ Chemical Oxidation (ISCO) relies on the capacity of oxidants to chemically destroy <br /> hydrocarbon bonds and release hydrocarbons that are electrostatically bound to colloidal surfaces <br /> of"clay and silt. Chemical oxidants work by producing free radicals, such as the hydroxyl radical, <br /> which oxidize hydrocarbons by breaking the chemical bonds of the target compounds. <br /> Floyd Flames 4 Updated CAP <br /> ZB178 Update to CAP March 2010 <br />