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ORC will stop releasing when dry and begin to release again when rehydrated; however, <br /> it is stable at 2-3% moisture, which facilitates storage and handling. The release rate of <br /> oxygen, in systems evaluated thus far, starts out as pseudo-first order as in: <br /> - d[Mg02]/dt = d(%02)Idt = k M9 0 <br /> I <br /> ( 2] <br /> The amount of oxygen released is therefore given by: <br /> 102JA021ta = 1-IM9021AM90211 = 1-e' <br /> where the subscript "t" refers to the amount of oxygen produced by time t which equates <br /> f to the fraction of M902 reacted. After several hours to several days, the release kinetics <br /> change to a pseudo-zeroth order expression where the release is simply a linear function <br /> R of time. <br /> E <br /> The by-products of the reaction as presented in the equation are oxygen and a magnesium <br /> hydroxide slung which is essentially Milk of Magnesia. The oxygen is consumed and the <br /> insoluble magnesium hydroxide remains. When formulated as ORC-concrete, the spent <br /> material can be easily removed before recharging with fresh ORC. <br /> The issue of whether or not any significant chemical oxidation occurs with ORC merits <br /> review. Although there is a widely held belief that magnesium peroxide first degrades to <br /> hydrogen peroxide, which then releases oxygen upon decomposition, a detailed <br /> examination of the thermodynamics involved shows this is false; the full technical detail <br /> is submitted as Exhibit 3. Essentially, the driving force for the release of oxygen is the <br /> reaction which forms magnesium hydroxide which releases the oxygen directly. Therefore, <br /> ORC is a source of slowly released molecular oxygen which finds its way into biological <br /> oxidation processes and does not have a significant ability to chemically oxidize <br /> compounds or remediating organisms by powerful free-radical mechanisms as is the case <br /> with hydrogen peroxide and peroxide hydrates. <br /> 3. Proof of Effic icy Product/Method <br /> The first field evaluations of oxygen barriers were made by the University of Waterloo and <br /> the results entered the peer-reviewed literature (Bianchi-Mosquera et al. 1994. Enhanced <br /> degradation of dissolved benzene and toluene using a solid oxygen releasing compound. <br /> GWMR, Winter, pp.120-128). This is provided as Exhibit 4. The study clearly <br /> demonstrated the effectiveness of ORC, particularly with respect to the fact that the <br /> results in all cases were achieved with sub-optimal applications of product. In future <br /> applications, the amount of ORC in the barrier could be increased considerably and/or be <br /> made with a higher percentage of active oxygen. Regenesis clearly recognizes it is in a <br /> engineering phase, that has just followed a period in which the validity of the basic <br /> • concept has been proven. Oxygen can be delivered to the subsurface in a passive, low <br /> cost time release manner, which can be effective in the remediation of modest levels of <br />