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Section 6. Accidental release measures <br /> Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains <br /> and sewers. Inform the relevant authorities if the product has caused environmental <br /> pollution(sewers,waterways,soil or air). <br /> Methods and materials for containment and cleaning up <br /> Small spill Stop leak if without risk. Move containers from spill area. Dilute wth water and mop up <br /> if water-soluble. Alternatively,or if water-insoluble,absorb with an inert dry material and <br /> place in an appropriate waste disposal container. Dispose of via a licensed waste <br /> disposal contractor. <br /> Large spill Stop leak if without risk. Move containers from spill area. Approach release from <br /> upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash <br /> spillages into an effluent treatment plant or proceed as follows. Contain and collect <br /> spillage wth noncombustible,absorbent material e.g.sand,earth,vermiculite or <br /> diatomaceous earth and place in container for disposal according to local regulations <br /> (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated <br /> absorbent material may pose the same hazard as the spilled product. Note:see <br /> Section 1 for emergency contact information and Section 13 for waste disposal. <br /> Section 7. Handling and storage <br /> Precautions for safe handling <br /> Protective measures Put on appropriate personal protective equipment(see Section 8). Avoid exposure- <br /> obtain special instructions before use. Do not handle until all safety precautions have <br /> been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. <br /> Avoid breathing vapor or mist. If during normal use the material presents a respiratory <br /> hazard,use only with adequate ventilation or wear appropriate respirator. Keep in the <br /> original container or an approved alternative made from a compatible material, kept <br /> tightly closed when not in use. Empty containers retain product residue and can be <br /> hazardous. Do not reuse container. <br /> Advice on general Eating,drinking and smoking should be prohibited in areas where this material is <br /> occupational hygiene handled,stored and processed. Workers should wash hands and face before eating, <br /> drinking and smoking. Remove contaminated clothing and protective equipment before <br /> entering eating areas. See also Section 8 for additional information on hygiene <br /> measures. <br /> Conditions for safe storage, Store in accordance with local regulations. Store in original container protected from <br /> including any direct sunlight in a dry,cool and well-ventilated area,away from incompatible materials <br /> incompatibilities (see Section 10)and food and drink. Store locked up. Keep container tightly closed <br /> and sealed until ready for use. Containers that have been opened must be carefully <br /> resealed and kept upright to prevent leakage. Do not store in unlabeled containers. <br /> Use appropriate containment to avoid environmental contamination. See Section 10 for <br /> incompatible materials before handling or use. <br /> Section 8. Exposure controls/personal protection <br /> Control parameters <br /> Occupational exposure limits(OSHA United States) <br /> Ingredient name Exposure limits <br /> Titanium Dioxide ACGIH TLV(United Slates, 3/2016). <br /> TWA: 10 mg/m3 8 hours. <br /> OSHA PEL(United Slates,6/2016). <br /> TWA: 15 mg/m3 8 hours. Forth:Total dust <br /> Zinc Oxide NIOSH REL(United Stales, 10/2016). <br /> CEIL 15 mg/m3 Form: Dust <br /> TWA: 5 mg/m310 hours. Forth: Dust and <br /> fumes <br /> STEL: 10 mg/m3 15 minutes. Forth: Fume <br /> OSHA PEL(United Slates,6/2016). <br /> Date ofissuaftte 0frsvh4w :16'19/2017 Dateorpeviousissue :917/2017 Version :4.01 4111 <br />