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Joe Lentini 4- 5 November 2010 <br /> Former Pipelines, Tracy <br /> pipelines in the vicinity of Trench 3 has been delineated. However, the groundwater <br /> data obtained from B-77 and B-78 in October 2008 show that the lateral extent of <br /> the pipeline release in the Trench 3 area has not been delineated. Figure 3b in the <br /> Work Plan shows that TPHc has been detected at 570 Ng/L about 250 feet east of <br /> Trench 3 at a depth of 146 feet bgs. This pollution could have migrated with the flow <br /> of deep zone groundwater because no contaminants of concern were detected <br /> above 100 feet bgs in borings B-77 and B-78. The flow direction of groundwater in <br /> aquifers underlying the shallow zone has not been determined. Additional <br /> investigation and monitoring wells are needed in this area to delineate the lateral <br /> extent of COCs below the shallow zone. <br /> 3. Based on the analytical results which show that elevated concentrations of TPH are <br /> present in the shallow zone in MW-2, we concur that the lateral and vertical extent <br /> of petroleum hydrocarbons has not been delineated in the Trench 2 area. Additional <br /> investigation and monitoring wells are needed in this area to delineate the extent of <br /> CDCs in the shallow zone to the west of Trench 2. <br /> 4. The additional investigation to delineate the lateral extents in the Trench 2 and 3 <br /> areas should include the depth discrete groundwater sampling proposed in the <br /> 6 November 2009 Risk Assessment Scope of Work, Former Shell Central Valley <br /> Crude Oil Pipeline, Hansen Road Near Schulte Road, Cordes Ranch (RA Work <br /> Plan) for the MW-1 through MWA 1 well installation phase of the investigation. <br /> Groundwater sampling prior to well installation would more accurately characterize <br /> the vertical extent of pollutants and finalize the total depths of future monitoring <br /> wells in at Trenches 2 and 3. <br /> 5. The Investigation Report does not provide any indication that the vadose zone soil <br /> sampling for the analysis of physical properties, as described in the RA Work Plan <br /> was conducted. Shell proposed to analyze the physical properties to support a <br /> proposed assessment of soil vapor intrusion pathways. The soil vapor sampling was <br /> conducted on April 2007 in areas containing the highest levels of TPH in soil and <br /> groundwater in Trenches 2, 3, and 4. The results of soil sampling and the <br /> performance of a Johnson and Ettinger (J&E) Model evaluation were summarized in <br /> Shell's August 2007 Site Investigation Report. The J&E Model results indicated that <br /> a detection of benzene in boring B-72 at 30 feet bgs at a concentration of <br /> 390,000 micrograms per cubic meter (Ng/m3) posed an incremental cancer risk that <br /> exceeded the de minimis standard of one-in-a-million. Based on these results, Shell <br /> stated that permanent soil vapor probes would be installed near the highest levels of <br /> soil and groundwater pollution to facilitate additional soil vapor sampling. <br /> 6. The soil vapor contaminant concentrations and indoor air intrusion modeling results <br /> indicate that cleanup will be necessary to prevent further groundwater degradation <br /> and protect human health. Cleanup levels to protect groundwater quality from soil <br /> vapors may be evaluated using modeling software, such as VLEACH, which is <br /> available on the internet at http://wvvw.epa.gov/ada/csmos/models/vleach html. <br /> Contaminant concentrations remaining after cleanup to protect groundwater can be <br /> re-modeled using J&E Model. The Department of Toxic Substances Control's latest <br /> version of the model and guidance for using it are available on the internet at <br /> hftp://www.dtsc.ca..clov/assessin.grisk/humanrisk2.cfm. <br />