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1 <br /> flow purging has the advantage of minimizing mixing between tion-reduction potential,temperature and turbidity should be <br /> the overlying stagnant casing water and water within the used to determine when formation water is accessed during <br /> screened interval. purging. In general,the order of stabilization is pH,tempera- <br /> ture,and specific conductance,followed by oxidation- <br /> A. Low-Flow Purging and Sampling reduction potential, dissolved oxygen and turbidity. Tempera- <br /> ture and pH,while commonly used as purging indicators, are <br /> Low-flow refers to the velocity with which water actually quite insensitive in distinguishing between formation <br /> enters the pump intake and that is imparted to the formation water and stagnant casing water; nevertheless,these are <br /> pore water in the immediate vicinity of the well screen. It important parameters for data interpretation purposes and <br /> does not necessarily refer to the flow rate of water discharged should also be measured. Performance criteria for determi- <br /> j at the surface which can be affected by flow regulators or nation of stabilization should be based on water-level draw- <br /> restrictions. Water level drawdown provides the best indica- down, pumping rate and equipment specifications for measur- <br /> tion of the stress imparted by a given flow-rate for a given ing indicator parameters. Instruments are available which <br /> hydrological situation. The objective is to pump in a manner utilize in-line flow cells to continuously measure the above <br /> that minimizes stress(drawdown)to the system to the extent parameters. <br /> practical taking into account established site sampling <br /> objectives. Typically,flow rates on the order of 0.1 -0.5 L/min It is important to establish specific well stabilization <br /> ' are used, however this is dependent on site-specific criteria and then consistently follow the same methods <br /> hydrogeology. Some extremely coarse-textured formations thereafter, particularly with respect to drawdown,flow rate <br /> have been successfully sampled in this manner at flow rates and sampling device. Generally,the time or purge volume <br /> to 1 Vmin. The effectiveness of using low-flow purging is required for parameter stabilization is independent of well <br /> intimately linked with proper screen location, screen length, depth or well volumes. Dependent variables are well diam- <br /> and well construction and development techniques. The eter,sampling device, hydrogeochemistry, pump flow rate, <br /> reestablishment of natural flow paths in both the vertical and and whether the devices are used in a portable or dedicated <br /> horizontal directions is important for correct interpretation of manner. If the sampling device is already in place(i.e., <br /> the data. For high resolution sampling needs,screens less dedicated sampling systems),then the time and purge <br /> than 1 m should be used. Most of the need for purging has volume needed for stabilization is much shorter. Other <br /> been found to be due to passing the sampling device through advantages of dedicated equipment include less purge water <br /> the overlying casing water which causes mixing of these for waste disposal,much less decontamination of equipment, <br /> stagnant waters and the dynamic waters within the screened less time spent in preparation of sampling as well as time in <br /> interval. Additionally,there is disturbance to suspended the field,and more consistency in the sampling approach <br /> sediment collected in the bottom of the casing and the which probably will translate into less variability in sampling <br /> displacement of water out into the formation immediately results. The use of dedicated equipment is strongly recom- <br /> adjacent to the well screen. These disturbances and impacts mended at wells which will undergo routine sampling over <br /> can be avoided using dedicated sampling equipment,which time. <br /> precludes the need to insert the sampling device prior to <br /> ' purging and sampling. If parameter stabilization criteria are too stringent, <br /> then minor oscillations in indicator parameters may cause <br /> isolation of the screened interval water from the purging operations to become unnecessarily protracted. It <br /> overlying stagnant casing water may be accomplished using should also be noted that turbidity is a very conservative <br /> low-flow minimal drawdown techniques. If the pump intake is parameter in terms of stabilization. Turbidity is always the <br /> located within the screened interval, most of the water last parameter to stabilize. Excessive purge times are <br /> pumped will be drawn in directly from the formation with little invariably related to the establishment of too stringent turbidity <br /> mixing of casing water or disturbance to the sampling zone. stabilization criteria. It should be noted that natural turbidity <br /> However,if the wells are not constructed and developed levels in ground water may exceed 10 nephelometric turbidity <br /> properly,zones other than those intended may be sampled. units(NTU). <br /> At some sites where geologic heterogeneities are sufficiently <br /> different within the screened interval, higher conductivity C.Advantages and Disadvantages of Low-Flow <br /> zones may be preferentially sampled.This is another reason (Minimum Drawdown)Purging <br /> to use shorter screened intervals, especially where high <br /> spatial resolution is a sampling objective. In general,the advantages of low-flow purging <br /> include: <br /> B. Water Quality Indicator Parameters • samples which are representative of the mobile load of <br /> contaminants present(dissolved and colloid-associ- <br /> It is recommended that water quality indicator ated); <br /> parameters be used to determine purging needs prior to - minimal disturbance of the sampling point thereby <br /> sample collection in each well. Stabilization of parameters minimizing sampling artifacts; <br /> such as pH,specific conductance, dissolved oxygen,oxide- - less operator variability, greater operator control; <br /> 5 <br />