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_ <br /> x " <br /> i <br /> No.317 <br /> Materia! Safety Data Sheet TOLUEN <br /> 1 Corporation (Revision D) <br /> Genium P1lblishing <br /> 1145 Catalyn Street Issued:August 1979 <br /> Schenectady,NY 12303-1836 USA ttEraust PuauSNHC CORP. Revised: A til 1986 <br /> (518)377-8855 20 <br /> SECTION 1. MATEKIAL IpENTIFICATION HMIS 3 <br /> ..e,Fzlnt,t+9T TOLUENE H:2 2 0 <br /> G Mcthyl Benzene,?Acthyl Benzol,PhenybnF:3 - <br /> ethanc,Toluol, F: 6 <br /> C7Hg,CAS t 0168-68.3 <br /> PPE* R I <br /> Pp including: 'See SCOL 8 I 3 <br /> �4,, ..rrraxarcUPPL1FR_: Available from m3nY su Hers, <br /> Allied Co PO Boz 2064R,Morristown,NJ 07960;Telephone:(201)455-440D S 2 <br /> sp., h 4 <br /> Ashland Chen cic Co.,Industrial Clumicals R Solvents Dir.,YO Bax 221 , <br /> Culutnbus,OH;,clephone:(614)889.3844 <br /> w :HAZARD-DATA ` <br /> SECTION 2.1NURT+DTT:i�1s AND HAZA_RDS' ca 100 J 8-hr Tl V:loo ppzaar <br /> 375 mglm3•(Skin)•• <br /> - Toluene C133 -- - - <br /> Man,lahal c;i TCl w <br /> 100 ppm:Psychotropic••' <br /> Rat,oral,LD50:5000 m6/1'9 <br /> • Current(1985-86)ACC,IH Tl.V.The OSHA PEL is 2D0 PPm wit!'an Rat,Inhalation,LCLO' <br /> acceptable eeiliag caaccntrttion a.300 ppm and an acceptable <br /> 40W pprn/4 hrs. <br /> maximum peak of 500 PP-'10 minutes. u h intact Rabbit,Skin,LD50:14 gra$ <br /> •• Skin designation indicates thattolusrncexn be absorbed t}tro g -------------------- <br /> Skin <br /> -_E_c__3�ppm <br /> ti skin and contribute w overall expo Human, Y <br /> ••* Affects the mind. <br /> SECTION 3. PHYSICAL DATA kvaporation Rau(BuAc.1) .2.24 <br /> Specific Gravity(H2O 5 1)...0.666 <br /> Boiling Point...'_31'F(11I'Q 93'C) <br /> Vapor Pressure C 20'C,mrn HS"'22 Melting Point...-I39'F(- <br /> water Solubility'@ 20"C,wt.%...0.05 percent Volatile by Volume.••t a 100 <br /> Vapor Density(Air'=l)••.3.14 Molecular weight—92.15 <br /> st <br /> divid <br /> Clear,colorless liquid fa tic ho curstrap rapidly upon erratic xdposure to tolusoe,he Odor is dodor islnott a g000dmwaarnwarning in <br /> the range of l0 to 15 pPrn. Because olfactory g <br /> property. LOUVER -UPPER <br /> SECTION 4. FIRE AND EXPLOSI(}N DATA Flammabil.ty Limits In Air <br /> Flash Point and Method Autoignition Temp. 1.27 7.1 <br /> 40'F(4'C) CC 696'F f480'Cl <br /> 96 by Voluroe <br /> Carbon dioxide,dry chemical,alcohol foarr> Do not use a solid stream cf water because c s am <br /> t containers that arc exposed to situ and to disperse vapors. <br /> will scatter and spread the fire. Usc water spray to cool A class <br /> � , r : This OSHA class IB flatnmablc liquid is a dangerous fisc hazard.It is a moderate rue <br /> hazard when exposed to oxidize.heat,sparks,or open fla.•nc, Vapors are heavier than air and may'travel a considerable <br /> pparatus with full facep'sece <br /> distance to an ignition- <br /> and fiuh back. <br /> ,n : Fire fighters should wear self-contained breathing a <br /> operated n a r-354ivc-pressure mode when fighting fists it'vOlving <br /> toluene. <br /> SECTION S• REACT-WITY DATA <br /> t : ielucne is sWbic in closed canlaincrs at room temp stature under with <br /> strong <br /> Oxidizing <br /> and <br /> s '- <br /> haadhng cendi'iL$sts. It docs not undergo hazardous polymerizaton. This material is incompatible with strong g <br /> ls <br /> presence of sulfuric acid,will product nitrated <br /> at cots,diniuuecn tcraoxidc,silver perchlorate,tetranitromethane,and uranium hexalluoride. Conta^t with thnit maria <br /> - ---- -- r.:.ty czusc-fir_or_cxploston. Nitric acid and toluene,csp_cia11}'in the p - <br /> compounds shat arc dzhgcmusly CxPrfaces,and all sOurecs of heat and asrvc• <br /> n V Avoid exposure to sparks,open flame,hat su s'siton or burning produces carbon dioxide andlortne <br /> Kill attack sonic forms of plastics,rubber,and coatings. Thermal de:.ampo <br /> carbon monoxides <br />