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Mr. Michael Desso - 3 - • 22 February 2005 <br /> Nestle USA, Inc. <br /> believes only arsenic and antimony may be mobilized by the push-pull tests. Nestl6 needs to fully <br /> assess this potential impact before Regional Board staff can agree that in situ carbohydrate- <br /> enhanced bioremediation can be implemented to treat the entire 25,000 ftZ Industrial Avenue <br /> hotspot or any other Nest16 hotspots. Nestle should assess baseline concentrations of metals and <br /> monitor for a full suite of metals during push-pull tests and the longer-term pilot test recommended <br /> in General Comment 1. <br /> 10. Monitoring data collected during the 1999/2000 permanganate pilot test shows the horizontal <br /> groundwater gradient in the Upper Aquifer beneath the Industrial Avenue property is very small <br /> when the extraction wells are not operating. The permanganate did not appear to move in the six <br /> months following injection and pumping had to be implemented to mix the permanganate <br /> throughout the target treatment area. Furthermore, the permanganate should have been completely <br /> utilized in 4 to 6 months, but it persisted for more than 12 months. Please confirm that the <br /> problems encountered (or lessons teamed) during this pilot study were reviewed and considered in <br /> preparation of the Draft Work Plan. <br /> Specific Comments <br /> 1. Page 5, Subtask 3a: Briefly explain how the tracer will be added to the well and mixed to provide a <br /> uniform concentration throughout the test interval. <br /> 2. Page 6, Subtask 3b: This section indicates the injection solution will contain 1%carbohydrate. <br /> This percentage appears to be low, so explain how this amount was determined to be optimal for the <br /> push-pull test. Also,please explain how the molasses will be mixed with the treated groundwater <br /> effluent and bromide tracer prior to injection. <br /> 3. Table 1: Some of the proposed analyte reporting limits in this table are too high. For example, the <br /> proposed reporting limits (RLs) for cVOCs are 1 to 2 orders of magnitude higher than the RLs that <br /> Nestle' achieves under the existing long-term groundwater-monitoring program. Revise the RL for <br /> cVOCs to 0.5 gg/L and the RL for sulfate to 1 mg/L. Also, add a full suite of metals to this table <br /> with RLs equal to or less than the lowest applicable water quality objectives or the lowest RLs that <br /> can be achieved with EPA analytical methods. <br /> Chloroform is a Nestle' CoC that is commonly detected in M-1 A, so please add it to the VOCs that <br /> will be tested/reported. <br /> If you have any questions, please contact me at(916) 464-4733 (mpierce(a,waterboards.ca.aov). <br /> Marcus L. Pierce, C.Hg. <br /> Engineering Geologist <br />