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Nestle USA, Inc.—Ripon, CA January 28, 2011 <br /> 2011 Revised Feasibility Study <br /> Groundwater extraction and treatment activities at the Site and at 519 South <br /> Stockton Avenue have resulted in the discharge of approximately 1.4 billion <br /> gallons of water between 2000 and 2009. These activities removed an estimated <br /> 1,286 pounds of CDCs between 2000 and 2009, equivalent to 0.87 pounds of <br /> COCs per every million gallons of groundwater pumped. Figure 4 and Figure 5 <br /> summarize the historical mass removal rates at the Stockton Avenue and <br /> Industrial Avenue treatment systems. <br /> The detection of COCs in groundwater samples collected from two private <br /> (domestic) water wells south of the River in 2005 has been addressed with <br /> additional characterization, well replacement and wellhead treatment. <br /> Immediately following this discovery, bottled water was provided to the residents <br /> of the impacted domestic wells. Soon after, wellhead treatment systems were <br /> installed at each affected well. As of the date of this Revised FS Report, one <br /> water replacement well has been installed at one residence and another well is <br /> targeted for installation in November 2009. <br /> 3.4.3 Source Area Remediation <br /> Even though multiple SVE and groundwater extraction and treatment systems <br /> have operated since 1989, potential residual source areas with elevated COCs <br /> may continue to impact groundwater beneath the Site. Pilot tests of multiple <br /> technologies were conducted to assess additional mass removal from the source <br /> areas northeast of the Site (near the extraction wells EI-1 and EW-1, and <br /> monitoring wells M-1A and M-113). These included injection of microbes and <br /> nutrients in 1989"', potassium permanganate in 2000"" and a carbohydrate <br /> substrate (molasses) in 2005X"' <br /> Very little information is available about the 1989 pilot test of injected microbes <br /> and nutrients, although the 1994 FS indicated in-situ bioremediation may be <br /> effective. <br /> In August 1999, potassium permanganate was injected in four locations at three <br /> depth intervals in the Upper Aquifer. Since no hydraulic mixing was observed <br /> initially, pumping from three extraction wells in various configurations was <br /> introduced to enhance mixing. This allowed permanganate to reach impacted <br /> groundwater approximately 20 feet from the injection points. Though TCE <br /> oxidation was observed in all seven monitoring wells, and cis-1,2- <br /> dichlooroethene (cis-1,2-DCE) oxidation occurred in six of the wells monitored, <br /> concentration rebound occurred in most wells within 28 weeks"" A detailed <br /> assessment of this potassium permanganate injection study is included in <br /> Attachment A.1. <br /> The most recent in-situ biodegradation test, performed in 2005, indicated half- <br /> lives associated with carbohydrate utilization at approximately 20 days". The <br /> test showed the transformation of TCE to cis-1,2-DCE, although complete <br /> breakdown of TCE to ethene was not observed during the 30-day test. Results <br /> also showed increases in selenium and arsenic in groundwater above <br /> background levels, with concentrations returning to background levels after 30 to <br /> 7 <br />