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MONITORING AND REPOR4 PROGRAM NO.R5-2003-0802 ` -2- <br /> SOUTH <br /> 2-SOUTH SHORE PARCELS,L&M OPERABLE UNIT <br /> CONOCOPHILLIPS PETROLEUM COMPANY; CHEVRON,U.S.A.; <br /> TEXACO REFINING AND MARKETING,INC.;TOSCO CORPORATION; <br /> L&M PETROLEUM COMPANY,INC.;AND MR.BILLY MCKINNON <br /> STOCKTON, SAN JOAQUIN COUNTY <br /> GROUNDWATER MONITORING <br /> As shown on Figure 1, there are 17 monitoring wells associated with the three OUs. Three of the <br /> monitoring wells are either missing or damaged. Six of the 17 wells are associated with the area <br /> owned/operated by the Discharger. The groundwater monitoring program for these six wells and <br /> any wells installed subsequent to the issuance of this MRP, shall follow the schedule below. <br /> Monitoring wells with free phase petroleum product or visible sheen shall be monitored for <br /> product thickness and depth to water only. Sample collection and analysis shall follow standard <br /> EPA protocol. <br /> EPA Analytical Max.Detection Sampling <br /> Constituents Method Limit ' Frequency' <br /> (FtB�) Fre uenc <br /> Depth to Groundwater --- --- Quarterly <br /> Volatile Organic Compounds 8021B or 8260B 0.5 Quarterly <br /> Semivolatile Organic Compounds 8270 various' Quarterly <br /> Total Petroleum Hydrocarbons as Gasoline 8015M 50 Quarterly <br /> Total Petroleum Hydrocarbons as Diesel(Extractable) 8015M4 50 Quarterly <br /> Total Petroleum Hydrocarbons as Motor Oil(Extractable) 8015W 50 Quarterly <br /> Benzene 8020 or 8260B 0.5 Quarterly <br /> Toluene 8020 or 8260B 0.5 Quarterly <br /> Ethylbenzene 8020 or 8260B 0.5 Quarterly <br /> Xylene 8020 or 8260B 0.5 Quarterly <br /> MTBE6 Dissolved Metals 6000/7000 various' Quarterly <br /> 8260B 0.5 Quarterly <br /> TBA6 8260B 5 Quarterly <br /> 6 8260B 0.5 Quarterly <br /> D�E6 8260B 0.5 Quarterly <br /> 6 8260B 0.5 Quarterly <br /> Ethanol 8260B 50 Quarterly <br /> Methanol6 8260B 100 Quarterly <br /> For nondetectable results. <br /> Groundwater level measurements for all South Shore Parcel monitoring wells shall be collected within an eight- <br /> hour period. Groundwater sampling activities for all wells requiring sampling shall be collected within five days. <br /> If the OUs are collecting water levels and performing sampling separately,the activities must be coordinated to <br /> meet these requirements. <br /> ' Maximum detection limits must meet or be lower than the applicable water quality objective,unless this is not <br /> achievable by an EPA or State approved laboratory method. See Table 2 for a list of applicable water quality <br /> objectives. <br /> ° Without silica gel cleanup. <br /> 5 Dissolved metals to be analyzed include antimony,arsenic,beryllium, cadmi <br /> um,chromium,copper,mercury, <br /> nickel,lead, selenium,silver,thallium,and zinc. <br /> 6 Fuel oxygenates,including methyl tertiary butyl ether(MTBE),methanol,ethanol,tertiary butyl alcohol(TBA), <br /> tertiary amyl methyl ether(TAME),di-isopropyl ether(DIPE),and ethyl tertiary butyl ether(ETBE),shall be <br /> analyzed in all monitoring wells during first and third quarter monitoring events. If results are nondetectable for <br /> fuel oxygenates in all wells during both monitoring events,no finther monitoring for oxygenates is required. If a <br /> fuel oxygenate is detected in either monitoring event,it shall be added to the quarterly monitoring program for <br /> the well in which it was detected. <br />