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Stantec <br /> L & M OPERABLE UNIT- THIRD QUARTER 2011 SITE STATUS, REMEDIAL SUMMARY, <br /> AND GROUNDWATER MONITORING REPORT <br /> Groundwater Monitoring and Sampling <br /> October 28, 2011 <br /> 2.6.2.1 Quality Assurance/Quality Control Samples <br /> Duplicate sample QCDUP-6 was collected from L&M OU D-Zone well MW-69 during 3Q11 <br /> sampling event. A comparison of the samples is shown below. <br /> Analyte Sample # Sample # % Difference <br /> MW-69 QCDUP-6 <br /> TPHg (mg/L) <0.05 <0.05 0% <br /> TPHd (mg/L) 0.38 0.22 +/- 53.3% <br /> TPHo (mg/L) 0.092 <0.05 NA <br /> Benzene (mg/L) <0.0005 <0.0005 0% <br /> MtBE (mg/L) <0.0005 <0.0005 0% <br /> TBA (mg/L) <0.005 <0.005 0% <br /> 2.6.2.2 General Laboratory Notes <br /> The laboratory validation issues are consistent with the D-Zone quality assurance and quality <br /> control. Each set of issues corresponds directly with the denoted report. All laboratory reports <br /> are included in Appendix D. <br /> Validation issues with report number 78189: <br /> The MRL for chloromethane in well MW-70 was raised due to the presence of an interfering <br /> compound. <br /> Validation issues with report number 78203: <br /> The MRL for 1,1,2-trichloroethane was raised in samples collected from well MW-55 due to the <br /> presence of an interfering compound. <br /> Groundwater samples collected from well MW-55 were analyzed by EPA Method 8260B using <br /> bottles that contained headspace bubbles greater than 1/4 inch in diameter. <br /> 2.7 THIRD QUARTER 2011 SEPARATE PHASE HYDROCARBONS AND <br /> HYDROCARBON CONCENTRATION TRENDS <br /> 2.7.1 Shallow Zone <br /> The following sections summarize trends for detected petroleum hydrocarbons, fuel oxygenates, <br /> and observed SPH for shallow (A-Zone) groundwater beneath the Site. <br /> 2.7.1.1 Separate Phase Hydrocarbons <br /> Measurable SPH or SPH-sheen has historically been observed in shallow A-Zone wells MW-10, <br /> 2AMW-13, 2AMW-14, MW-19, and DPE-1 through DPE-13. Due to the quantity and viscous <br /> Iffidewater7W Stockton(P2A)\QMRs\2011\3Q11\3011 QSSR QRSR QMR Stockton_FINAL.doc 2.18 <br />