Laserfiche WebLink
amec <br /> selected, the regulatory permitting process for implementation could be streamlined by <br /> performing the remediation in accordance with General Order for In Situ Groundwater <br /> Remediation at Sites with Volatile Organic Compounds (Order No. R5-2008-0149 [General <br /> Order]). The RWQCB also requested bench scale testing to verify the effectiveness of the <br /> proposed in situ remediation methods and to identify geochemical changes likely to occur in <br /> groundwater as a result of the in situ remediation. <br /> This Interim RAP is intended to fulfill the RWQCB request. UniFirst proposes using in situ <br /> injection of hydrogen release compound (HRC)to stimulate the naturally occurring reductive <br /> dechlorination of the CVOCs in groundwater. UniFirst proposes first to conduct a pilot test to <br /> evaluate the effectiveness of this method for this site. The pilot test will be conducted in the <br /> area where CVOC concentrations in groundwater are the highest(in the vicinity of monitoring <br /> well cluster MW-5). The test will allow the collection of performance data that could be used <br /> for subsequent application to other locations, if it is shown to be necessary. This Interim RAP <br /> was prepared using the General Order as guidance. A Notice of Intent to conduct the pilot test <br /> is presented in Appendix B. <br /> 7.1 BENCH SCALE TEST <br /> UniFirst proposes to not conduct bench scale testing of HRC injections prior to performing the <br /> pilot test. HRC has been utilized for remediation at numerous sites with PCE in groundwater. <br /> Information on the performance of HRC at sites similar to UniFirst is readily available <br /> (Koenigsberg, 1999; Koenigsberg, 2004). HRC is manufactured by Regenesis, Inc., of San <br /> Clemente, California. Material Safety Data Sheets for these materials are provided in <br /> Appendix C. HRC contains glycerol tripolylactate, glycerol, and lactic acid. Upon contact with <br /> water, FIRC releases lactic acid that acts as a hydrogen source for microbes that degrade <br /> CVOCs. The availability of an abundant hydrogen source significantly increases the rate at <br /> which the microbes degrade the CVOCs in groundwater. <br /> A typical case study involving a dry cleaner located in Texas with groundwater affected by <br /> PCE and clayey soil conditions, similar to conditions at the Stockton site, is presented in <br /> Appendix D. The results of this and other studies indicate HRC should be effective in reducing <br /> the concentration of CVOCs in groundwater at the UniFirst site. These case studies indicate <br /> the likely geochemical changes in the aquifer resulting from enhanced reducing conditions due <br /> to HRC are well understood. The changes are likely to include reductions in dissolved oxygen, <br /> nitrate, and sulfate and increases in dissolved iron. However, these changes are ephemeral <br /> and aquifer geochemical conditions at other sites have been shown to gradually revert to their <br /> previous condition as the supply of FIRC in the aquifer is exhausted (about 1 to 2 years). <br /> AMEC_ Geomatrix, Inc. <br /> 1A13000s\13290Wrchive\13290-49.DOG 10 <br />