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STANDARD OPERATING PROCEDURE- <br /> Lq.r GROUNDWATER SAMPLING <br /> Gettler-Ryan Inc. field personnel adhere to the following procedures for the collection and handling of <br /> groundwater samples prior to analysis by the analytical laboratory. Prior to sample collection, the type <br /> of analysis to be performed is determined. Loss prevention of volatile compounds is controlled and <br /> sample preservation for subsequent analysis is maintained. <br /> Prior to sampling the presence or absence of free-phase hydrocarbons is determined using an interface <br /> probe. Product thickness,if present, is measured to the nearest 0.01 foot and is noted in the field notes. <br /> In addition, static water level measurements are collected with the interface probe and are also recorded <br /> in the field notes. <br /> After water levels are collected and prior to sampling, each well is purged a minimum of three well <br /> casing volumes of water using pre-cleaned pumps (stack, suction, Grundfos), or polyvinyl chloride <br /> bailers. Temperature,pH and electrical conductivity are measured a minimum of three times during the <br /> purging. Purging continues until these parameters stabilize. <br /> Groundwater samples are collected using Chevron-designated disposable bailers. The water samples are <br /> transferred from the bailer into appropriate containers. Pre-preserved containers, supplied by analytical <br /> laboratories, are used when possible. When pre-preserved containers are not available, the laboratory <br /> is instructed to preserve the sample as appropriate. Duplicate samples are collected for the laboratory <br /> to use in maintaining quality assurance/quahty control standards. The samples are labeled to include the <br /> job number, sample identification, collection date and time, analysis, preservation (if any), and the <br /> sample collector's initials. The water samples are placed in a cooler, maintained at 40C for transport to <br /> the laboratory. Once collected in the field, all samples are maintained under chain of custody until <br /> delivered to the laboratory. <br /> The chain of custody document includes the job number, type of preservation,if any, analysis requested, <br /> sample identification, date and time collected, and the sample collector's name. The chain of custody <br /> is signed and dated (including time of transfer)by each person who receives or surrenders the samples, <br /> beginning with-the field personnel and ending with the laboratory personnel. <br /> A laboratory supplied trip blank accompanies each sampling set. For sampling sets greater than 20 <br /> samples,5%trip blanks are included. The trip blank is analyzed for some or all of the same compounds <br /> as the groundwater samples. <br /> As requested by Chevron Products Company, the purge water and decontamination water generated <br /> during sampling activities is transported by PNM to McKittrick Waste Management located in <br /> McKittrick, California. <br /> N.Califomialformskhevron-SOP.I OM <br />