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i <br /> r <br /> - ULTRAMAR FIELD PROCEDURES _ <br /> f { <br /> The following section describes procedures used by Ultramar field personnel In the performance of ground water <br /> sampling. <br /> r <br /> a Ground Water Level and Total Depth Determination <br /> I <br /> I A water level indicator is lowered down the well and a measurement of the depth to water from an established <br /> reference point on the casing is taken. The indicator probe is used to sound the bottom of the well andla <br /> measurement of the total depth of the well is taken. Both the water level and total depth measurements are taken <br /> # to the nearest 0.01-foot. <br /> f � <br /> Visual Analysis of Ground Water <br /> Prior tou in and ' <br /> P rg g sampling p g ground water monitoring wells, a water sample is collected from each well for. <br /> subjective analysis. The visual analysis involves gently lowering a clean, disposable, polyethylene bailer to <br /> approximately one-half the bailer length past the water table interface. The bailer is then retrieved, and the sample <br /> contained within the bailer is examined-for floating product or the appearance of a petroleum product sheen. .:If <br /> measurable free product is noted in the bailer, a water/product interface probe is used to determine the thickness <br /> of the free product to the nearest 0.01-foot. The thickness of free product is determined by subtracting the depth <br /> to product from the depth to water. <br /> Monitoring Well Purging and Samoling } <br /> i . <br /> Monitoring wells are purged by removing approximately four casing volumes of water from the well using a clean <br /> disposable bailer or electrical submersible purge pump. Purge volumes are calculated prior to purging. During <br /> 4 purging the temperature, pH, and electric conductivity are monitored. The well is sufficiently purged when:-the four <br /> casing volumes have been removed; the temperature, pH, and conductivity have stabilized to within 10% of the <br /> r initial readings; and the ground water being removed is relatively free of suspended solids. After purging, ground <br /> water levels are allowed to stabilize to within 80%of the initial water level reading. A water sample is then collected , <br /> from each well with a clean, disposable polyethylene bailer. If the well is bailed dry prior to removing the minimum <br /> volume of water, the ground water is allowed to recharge. If the well has recharged to within 80% of the initial <br /> i reading within two hours, the well will continue to be purged until the minimum volume of water has been removed. <br /> If the well has not recharged to at least 80% of the initial reading within two hours, the well is considered to contain <br /> I formational water and a ground water sample is collected. Ground water removed from the well is stored in 55- '• <br /> gallon drums at the site and labeled pending disposal. <br /> In wells where free product is detected, the wells will be bailed to remove the free product. An estimate of the i <br /> volume of product and water will be recorded. If the free product thickness is reduced to the point where a <br /> measurable thickness is no longer present in the well, a ground water sample will be collected. If free product <br /> persists throughout bailing, a final free product thickness measurement will be taken and a ground water sample <br /> will not be collected. <br /> Samples are stored in 40-milliliter vials so that air passage through the sample is minimized (to prevent volatilizing <br /> the sample). The vial is tilted and flied slow until an upward convex meniscus <br /> forms over the mouth of the vial. <br /> IY Pw <br /> The Teflon side of the septum (in cap)is then placed against the meniscus, and the cap is screwed on tightly. The <br /> sample is then inverted and the bottle is tapped lightly to check for air bubbles. If an air bubble is present in the k <br /> vial, the cap is removed and more sample is transferred from the bailer. The vial is then resealed and rechecked ) <br /> for air bubbles. The sample is then appropriately labeled and stored on ice from the time of collection through the <br /> time of delivery to the laboratory. A Chain-of-Custody form is completed to ensure sample integrity. Ground water <br /> samples are transported to a state-certified laboratory and analyzed within the EPA-specified holding times for the <br /> requested analyses. <br /> l <br /> Utb mar Field PioceGureaKWR-94 <br /> I <br /> e <br /> } <br />