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STANDARD OPERATING PROCEDURE- <br /> GROUNDWATER SAMPLING <br /> ' Gettler- <br /> Ryan Inc field personnel adhere to the following procedures for the collection and handling of <br /> groundwater samples prior to analysis by the analytical laboratory. Pnor to sample collection,the type <br /> of analysis to be performed is determined Loss prevention of volatile compounds is controlled and <br /> sample preservation for subsequent analysis is maintained <br /> Prior to sampling, the presence or absence of free-phase hydrocarbons is determined using an interface <br /> probe Product thickness,if present, is measured to the nearest 0 01 foot and is noted in the field notes. <br /> In addition, static water level measurements are collected with the interface probe and are also recorded <br /> in the field notes <br /> ' After water levels are collected and prior to sampling, temperature, pH and electrical conductivity are <br /> measured If purging is to occur,each well is purged a minimum of three well casing volumes of water <br /> using pre-cleaned pumps (stack, suction, Grundfos), or polyvinyl chloride bailers The measurements <br /> ' are taken a nummum of three times during the purging Purging continues until these parameters <br /> stabilize <br /> Groundwater samples are collected using disposable bailers The water samples are transferred from the <br /> bailer into appropriate containers Pre-preserved containers, supplied by analytical laboratories, are used <br /> when possible. When pre-preserved containers are not available, the laboratory is instructed to preserve <br /> i the sample as appropriate Duplicate samples are collected for the laboratory to use in maintaining <br /> quality assurance/quality control standards. The samples are labeled to include the job number, sample <br /> identification,collection date and time, analysis,preservation(if any), and the sample collector's initials <br /> The water samples are placed in a cooler, maintained at 4oC for transport to the laboratory. Once <br /> collected in the field, all samples are maintained under chain of custody until delivered to the laboratory. <br /> ' The chain of custody document includes the job number,type of preservation,if any,analysis requested, <br /> sample identification, date and time collected, and the sample collector's name. The chain of custody is <br /> signed and dated (including time of transfer) by each person who receives or surrenders the samples, <br /> beginning with the field personnel and ending with the laboratory personnel <br /> ' A laboratory supplied trip blank accomparues each sampling set. For sampling sets greater than 20 <br /> samples, 5%trip blanks are included. The trip blank is analyzed for some or all of the same compounds <br /> as the groundwater samples <br /> ' As requested by Tosco Marketing Company,the purge water and de <br /> contaminaaon water generated during <br /> sampling activities is transported to Tosco- San Francisco Area Refinery,located in Rodeo, California <br /> ' hlfarnehoa�icetsop frs�SIOD <br />