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<br /> .r Ethylbenzylaniline 3728
<br /> d arts. renders it entirely unit
<br /> ge The most commonly used pressed almond oil or olive oil. Also sol in dil acids. pK. Caution: Irritating to eyes,skin,mucous membranes,and.
<br />.n nbination,are the follow- 2.5• in high concns, narcotic.
<br /> Id+ 71, amyl alcohol, gasoline, ° THERAP CAT: Topical anesthetic. USE: For conversion to styrene monomer;as resin solvent.
<br /> THERAP CAT(VET): Local (usually surface)anesthetic.
<br /> ne!t'�stor oil.acetone,nicotine, 3724. Ethylbenzhydramine. 2-(Diphenylmethoxy)-+Y,N-
<br /> iodide, pyridine bases, sulfuric 3720. N-Ethylamphetamine. N-Ethyl-a-methylbenzene- diethylethanamine; 2-(benzhydryloxy)triethylamine; p-di-
<br /> alate. Formula I is 5 gallons ethanamine; N-ethyl-a-methylphenethylamine; N-ethyl ethylaminoethyl benzhydryl ether; 2-(benzhydryloxy)-N.N-
<br /> ed t 100 gal of 95% ethanol. phenylisopropylamine; 2-ethylamino-l-phenylpropane; diethylethylamine; benzhydryl 2-diethylaminoethyl ether;
<br /> e t led to 100 gal of 95%etha. ` Adiparthrol;Apetinil. CItH17N;mol wt 163.25. C 80.92%, etanautine. C19H25NO;mol wt 283.40. C 80.52%,H 8.897o,
<br /> mins 5 gal commercial meths- y H 10.50%,N 8.58%. Prepn: Keil,Dobke,Ger.pat.767,263 N 4.94%. O 5.65%. Prepn: Martin et al., U.S.pat. 2,397,-
<br /> gal pyridine bases,formula 12A (1952 to Theodor H. Temmler); Leonard et al., J. Am. 799(1946 to Geigy); Rieveschl,U.S.pat.2,421,714(1947 to
<br /> 10 gal ethyl ether.formula 19 4 Chem. Soc. 80, 4858 (1958). Separation of isomers: Brit. Parke, Davis).
<br /> nd gal kerosene.formula 20 5 F pat. 814,339(1959 to Sterling Drug).
<br /> rla TA 10 gal acetone,formula
<br /> 2f0.1 gal gasoline,formula 30 - HHS{ CH
<br /> 5 gal ethyl ether,formula 33 30 1 z 3
<br /> SA 5 gal ethyl acetate,formula �CH2CHCH3 C=H5
<br /> e: t�rmula 44 contains 20 gal /
<br /> CH-OCHZCHZ N
<br /> 7n ble formulas are given in g -
<br /> 3. ormulae for Completely and 6' bp,, 104.5-106'. rip 1.4986. \CZHS
<br /> pWlished by the U.S.Treasury d-Form hydrochloride, CItH1aC1N, mp 154-156'. [a]'
<br /> I Alcohol. Reprinted in N. A. +17.2^(c = 2 in water).
<br /> W .srtiv larly methanol.may modify I-Form hydrochloride, C,,H,,CIN, mp 155-156'. [a]p
<br /> -17.3'(c = 2 in water).
<br /> rs+ tsed by ingestion and expo- bp015 140-142'.
<br /> Note: This is a controlled substance (stimulant) listed in
<br /> ti+ the U.S. Code of Federal Regulations,Title 21 Part 1308.11 Hydrochloride, C19H26CINO,Antiparkin, Rigidyl. Prisms
<br /> anamine; monoethylamine; ami- (1985). from alcohol + ethyl acetate,mp 140'. Bitter taste. Freely
<br /> 0 n8. C 53.28`:'., H 15.656, N THERAP CAT: Anorexic. sol in water;sol in alcohol,acetone,chloroform;very slight-
<br /> ly sol in benzene, ether. pH of 1%aq soln about 5.5.
<br /> frt ethyliodide + liq ammonia: 3721. Ethyl Amyl Ketone. 5-Methyl-3-heptanone; amyl Methyl iodide, CmHmINO, Esyntin,Metropin. A quater-
<br /> So+ i9,836(1947); from ethanol ethyl ketone; EAK. CaH160; mol wt 128.21. C 74.94%, H nary ammonium deriv of the base covered in the Geigy pat.
<br /> 1..-W.S, pat. 2,609,394 (1952 to 12.58%, O 12.48%. Review: Buller, Ind. & Eng. Chem. 48, THERAP CAT: Hydrochloride as antiparkinsonian; methyl
<br /> pat. 3,022,349 (1962 to Union 1323 (1956). iodide as anticholinergic.
<br />.a or: strong alkaline reaction. 3725. Ethyl Benzoate. Benzoic acid ethyl ester. C9111002;di -80'. Miscible with water, CH3CH2CiHCH2CoCH2CH3 mol wt 150.17. C 71.987.. H 6.71%, O 21.31%. C6H5C00-
<br /> y,ved and in cold place. LDS0 CH CtH,.
<br /> 1. F.Smyth er al..Arch. Ind. Hyg. 3 Colorless,clear,refractive liq;aromatic odor;vapors cause
<br /> cough. du 1.050. by 211-213'. mp -34*. n' 1.506.
<br /> H '. crystals from ethanol + Liquid. Mild fruity odor. d20 0.820-0.824. One gallon Almost insol in water; miscible with alcohol, chloroform,
<br /> olt a in 0.4 part water;freely sol weighs 6.83 lbs at 20'. bp760 157-162`. Flash pt 59'(138'F). ether, petr ether. LD50 orally in rats: 6.48 g/kg, Smyth et
<br /> or Srm or acetone. Practically Evaporation rate 0.3 (n-butyl acetate = 1.0). np 1.4195. al.. Arch. Ind. Hyg. Occup. Med. 10,61 (1954).
<br />:lo Slightly miscible with water. Compatible with alcohols,ke- USE: In perfumery under the name Essence de Niobe; in
<br /> hygroscopic crystals.mp 188'. d tones, ethers, many other organic solvents. manuf of Peau d'Espagne,artificial fruit essence.
<br /> o* alcohol. Practically insol in USE: Solvent for nitrocellulose-alkyd,nitrocellulose-male- 3726. Ethyl Benzo lacetate. P-Oxobenzene ro anoic
<br />+el, ased and protected from light. ic, and vinyl resins. Caution: Narcotic in high concns. y y p p
<br /> acid ethyl ester. CIIHItOr mol wt 192.21. C 68.735/6, H
<br /> etc Prepn is a 5-6 solo with 2%o
<br /> 3722. Ethylaniline. N-Ethylbenzenamine; ethylphenyl- 6.29%, O 24.97%. C6HsCOCH=COOCZHs.
<br /> ..r amine. C,H11N; mol wt 121.18. C 79.29%, H 9.15%. N Liquid; pleasant odor; becomes yellow on exposure to air
<br /> stabilizer for rubber latex: inter- 11.56%. Produced by heating aniline hydrochloride and and light. dts 1.122. by 265-270'with decompn. Volatile
<br /> 3ieinals: in oil refining: in organic alcohol at 180'. with steam. n101.5338. Insol in water;miscible with alco-
<br /> ati to skin. mucous membranes, hol.ether. Keep protected from air and light.
<br /> �HC2H5
<br /> a 6.rosing agent. 3727. a-Ethylbenzyl Alcohol. a-Ethylbenzenemethano/;
<br /> tzoate. 4-.4mirtobrn oic acid ethyl / ethylbenzyl alcohol; I-phenyl-t-propanol; 1-phenylprop-
<br /> aine: Anestheino a noic acid
<br /> Ben- yl alcohol; ethyl phenyl carbinol; a-hydroxypropylbenzene;
<br />:sir C e NO;mol wt 165.19. - ( SH 261; Ejibil; Livonal: Phenycholon; Phenicol; Phenychol;
<br /> 19937`.'0. Prepd by the esterifi- Fenicol; Felicur; Felitrope. C9HIZ0; mol wt 136.19. C
<br /> fid: Salkowski. Ber. 28, 1921 79.37%, H 8.880, O 11.75%. Prepd from benzaldehyde or
<br />.r. Ann. 320, 135 (1902): by the Very refractive liquid;rapidly becomes brown on exposure from ethyl phenyl ketone: Norris, Cortese, J. Am. Chem.
<br /> benzoate: 20, 135Limpricht.902ibid3by the to light and air. Aniline-like odor. d25 0.958. by 204.5'. Soc. 49, 2640(1927).
<br /> C en. Org. Syn. colt. vol. I, 240 Solidifies below 80'. mp -63.5'. np 1.5559. Insol in water;
<br /> str, practice the reducin%Knt.is miscible with a1c. ether and many other organic solvents.
<br /> Keep well closed and protected from light. LD50 orally in rats: aOH I
<br /> it he presence of a 1.1 g/kg CHCH23
<br /> L. Ali in Analytr
<br /> 2,K. Florey, Ed.(Academic Press. 3723. Ethylbenzene. CsH10; mol wt 106.16. C 90.50%.
<br />.i('A H 9.50%. C6HICZHs. Prepn from acetophenone: Clemmen-
<br /> sen, Ber. 46, 1838 11913); Gattermann-Wieland, Praxis des Oily liquid. Weak,ester-like odor. Sweetish.slightly irri-
<br /> organischen Chemikers (de Gruyter. Berlin.40th ed., 1961) tating taste. bp7W 219'; bpls 107'; bps 78'. da 0.9915. np
<br /> TtnH5 P 332. By Huang-Minion modification of Wolff-Kishner 1.5169. uv max(methanol): 250,260 nm(e 173.114). Misc
<br /> reduction: A. I. Vogel, Practical Organic Chemistry(Long- with methanol, ethanol, ether, benzene, toluene, olive oil.
<br /> mans. 3rd ed., 1959) p 516. Physical properties: L. C. LD50 orally in rats: 1.6 ml/kg.O. Linet et al..Arzneimittel-
<br /> Gibbons et al.. J. Am. Chem- Soc. 68, 1130(1946). Manuf: Forsch. 12,347 (1962).
<br /> ni Faith, Keyes&Clark's Industrial Chemicals, F. A. Lowen- USE: As heat transfer medium;in perfumery.
<br /> rr heim, M.; K. Moran, Eds. (Wiley-Interscience, New York, THERAP CAT: Choleretic.
<br /> xtt2 4th ed., 1975) pp 365-370. Toxicity: H. F. Smyth et al..
<br /> Am. Ind. Hyg. Assoc J. 23,95 (1962). 3728.Ethylbenzylaniline. N-Ethyl-V-phenylbenzeneme-
<br /> 88-90'. Stable in air. One Colorless liquid; flammable. du 0.866. by 136.25'. mp thanamine;N-ethyl-N-phenylbenzylamine. CtsHt7N; mol wt
<br /> th+ m
<br /> 2 )ml water. 5 ml alcohol. 2 ml -95.01'. np 1.4932. Flash pt, closed cup: 64'F (18'C). 211.29. C 85.26%, H 8.11%, N 6.63%. Prepn: Martin.
<br /> Practically insol in water; misc with the usual organic sol- MacQueen.U.S.pat. 1,887,772(1933 to Dow); Burgstahler,
<br /> rn�"Kher, and in 30 to 50 ml of ex- vents. LD30 orally in rats: 5.46 g/kg(Smyth). J. Am. Chem. Soc. 73, 3021 (1951).
<br /> Consult the cross index before using this section. Page 595
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