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3500 - Local Oversight Program
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PR0541875
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Last modified
3/16/2020 3:49:54 PM
Creation date
3/16/2020 2:13:04 PM
Metadata
Fields
Template:
EHD - Public
ProgramCode
3500 - Local Oversight Program
File Section
WORK PLANS
RECORD_ID
PR0541875
PE
2960
FACILITY_ID
FA0024017
FACILITY_NAME
CHEVRON SITE 306415
STREET_NUMBER
437
Direction
E
STREET_NAME
MINER
STREET_TYPE
AVE
City
STOCKTON
Zip
95202
APN
1392417
CURRENT_STATUS
01
SITE_LOCATION
437 E MINER AVE
P_LOCATION
01
QC Status
Approved
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SJGOV\sballwahn
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EHD - Public
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v <br /> ARCAUIS GERAGHTY&MILLER <br /> retardation factor. This rate of migration must be further modified <br /> to account for the amount of attenuation of the compound due to <br /> dispersion and biodegradation. This series of calculations must be <br /> performed for each constituent of interest which is identified and <br /> quantified in the soil analysis. <br /> At each step of the calculation process, there are inherent and <br /> significant sources of error which ultimately make this <br /> quantification process highly uncertain. For example, the above- <br /> described partitioning calculations required the use of a partitioning <br /> coefficient. The value of the partitioning coefficient can only be <br /> obtained experimentally and varies significantly with soil type. In <br /> instances where experimentally determined partitioning coefficients <br /> are not available, they can be estimated using regression equations. <br /> The partition coefficient has been recognized as a key parameter in <br /> predicting the environmental fate of organic compounds. The <br /> uncertainty (error) associated with estimation of the partitioning <br /> coefficient, when one is not able to relate the site soil to one <br /> identified under carefully controlled laboratory conditions can be <br /> orders of magnitude (i.e. greater that a factor of 10). A second <br /> example of the uncertainty in predicting the potential impact on <br /> groundwater based on a soil sample is that the hydraulic <br /> conductivity of the medium must be know in order to predict the <br /> advective rate of transport. Since the value of hydraulic <br /> conductivity varies significantly with soil type and even spatially <br /> within a soil type, the error associated with a calculation dependent <br /> upon assuming a hydraulic conductivity value or spatially <br /> extrapolating a measured hydraulic conductivity value can also be <br /> orders of magnitude. Theses errors ultimately are multiplicative <br /> and can result a highly misleading assessment of the potential for <br /> future impact to downgradient groundwater. <br /> Because the task of hand-calculating predictions of future <br /> downgradient groundwater impact is so onerous, some <br /> investigators have utilized numerical computer models to ease the <br /> calculation work load. However, it is important to emphasize that <br /> while the burden of the onerous work load has been removed, the <br /> uncertainty attendant to the process described above has not been <br /> removed. To make matters worse, the uncertainty is hidden by the <br /> convenience of the automated calculation, unless a formal <br /> evaluation of the uncertainty is also included as part of the <br /> assessment. <br /> Some regulatory agencies have in the past used more simplified <br /> calculations than those described above to set soil concentration <br /> guidance levels which are designed to be protective of <br /> groundwater. These approaches have declined in usage and <br /> application as the knowledge of contaminant fate and transport has <br /> 3 <br />
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