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Joe Lentini - 2 - 8 April 2010 <br /> Shell Mountain House <br /> CRA installed 15 monitoring wells (MW-2 through MW-16) and one soil vapor well <br /> (SVP-1-6/16) in Neighborhoods C and D, and 19 monitoring wells (MW-1 through MW-19) in <br /> Neighborhood B. The monitoring wells were generally screened between 20 and 40 feet bgs. <br /> The Report states that the soil vapor well will be sampled during the first quarter. However, in <br /> verbal communication on 2 March 2010, CRA estimated that the sampling would be delayed <br /> to April 2010 to allow field conditions to dry out sufficiently. Shell concluded that the <br /> contaminants in soil have been vertically and laterally delineated since TPH in the deepest <br /> samples in all borings was below detection limits, including MW-6. Shell had previously <br /> excavated soil from this area to 18 feet bgs. <br /> Groundwater sampling was conducted in September 2009. Dept to static groundwater ranged <br /> from about 27 to 35 feet bgs. Samples were submitted for laboratory analysis of TPHd, TPHc, <br /> benzene, toluene, ethylbenzene, and total xylenes (collectively BTEX), naphthalene, sulfate <br /> and sulfur. No TPHc, TPHd, BTEX or naphthalene was detected in any of the groundwater <br /> samples. Maximum sulfur and sulfate concentrations included 78.8 milligrams per liter (mg/L) <br /> and 220 mg/L, respectively. The highest concentrations were detected in Neighborhoods C <br /> and D. Groundwater flow generally varied between the northeast and northwest at gradients <br /> that ranged from 0.002 to 0.006. As requested by Central Valley Water Board staff, Shell <br /> conducted a background analysis of the soil and groundwater sulfate and sulfur data to <br /> evaluate if the presence of this contaminant was attributable to the crude oil release. The <br /> comparisons show that sulfate and sulfur concentrations are similar between background and <br /> source area samples. <br /> The 26 March 2010 Groundwater Monitoring Report Fourth Quarter 2009 (Fourth QMR) <br /> summarized the results of groundwater monitoring conducted on 29 and 30 December 2009. <br /> Groundwater generally flowed to the northwest in Neighborhood B and to the north-northeast <br /> in Neighborhoods C and D at gradients ranging from 0.002 to 0.005 feet per foot. All <br /> groundwater samples from Neighborhoods B, C, and D were non-detect (ND) for petroleum <br /> hydrocarbons. Groundwater monitoring for sulfur and sulfate was not conducted. Due to <br /> access restriction caused by seasonal wet weather, SVP-1-6/16 could not be sampled. <br /> Our comments are presented below. <br /> 1. We concur that the groundwater monitoring results confirm that sulfur and sulfate are <br /> ubiquitous and naturally occurring in groundwater in this area. <br /> 2. The ND groundwater monitoring results appear to indicate that the most of the petroleum <br /> hydrocarbon pollution mass is either sorbed to the porous media solids or generally <br /> insoluble. We will require Shell to conduct monitoring and submit reports for at least four <br /> consecutive quarters. If monitoring results are consistently ND or below water quality <br /> objectives, Central Valley Water Board staff will consider developing a regulatory decision <br /> for this Site. <br /> 3. Page 2 of the Fourth QMR ends in an incomplete sentence that appears to have been <br /> addressing soil vapor sampling at SVP-1-6/16. Since this proposed sampling was delayed <br /> due to weather and field conditions, we anticipate that the sampling will be conducted <br /> some time during the second quarter when drier weather conditions prevail. <br />