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Shell Mountain House Pipeline - 3 - 3 November 2011 <br /> Mountain House Parkway and C A Line Road, Tracy <br /> Semi-Volatile Organic Compounds <br /> Phenol Naphth 2- 1- acenapht fluoranth <br /> alene methylna methylnaph hene fluorene phenanthrene ene pyrene chrysene <br /> htalene talene <br /> 1.5 15 26 20 2.5 8.9 14 1.3 2.8 2.4 <br /> Groundwater beneath the Site fluctuates from 27 to 34 feet bgs and generally flows to the <br /> northwest, but does fluctuate to the northeast, at a gradient that ranges from 0.002 to 0.018 <br /> foot per foot. Shell collected grab groundwater samples during 2005 from borings where there <br /> was field evidence of hydrocarbon impact. Shell initially observed LPH in a groundwater <br /> sample from Neighborhood B and concentrations of petroleum constituents that are indicative <br /> of LPH were reported in Neighborhoods C and D. The greatest dissolved phase petroleum <br /> constituent concentrations detected from groundwater sampling are shown on Table 2. <br /> Table 2 - Greatest Groundwater Concentrations in micrograms per liter(pg/L)] <br /> TPH-c TPH-d Benzene Toluene Ethyl- Total Naphthalene' Sulfate' Sulfur' <br /> benzene Xylenes <br /> 570,000 330,000 18 30 21 279 <10 220 78.8 <br /> TPH-c and TPH-d =total petroleum hydrocarbons as crude and as diesel <br /> ' Monitoring well data. <br /> Between February and May 2009 and after Shell completed the excavations, Shell installed <br /> fifteen groundwater monitoring wells (MW-2 through MW-16) to depths ranging from 35 to 40 <br /> feet bgs in Neighborhoods C and D. Shell also installed nineteen groundwater monitoring <br /> wells (MW-1 through MW-19) at depths ranging from 37 to 38 feet bgs in Neighborhood B. <br /> Shell began conducting quarterly groundwater monitoring on 21 September 2009 and <br /> petroleum constituents have only been detected during a single monitoring event. In March <br /> 2010, TPH-d was detected in seven of the thirty-three wells monitored (Well MW-10 in <br /> Neighborhood C and D was dry) at concentrations ranging from 54 to 79 micrograms per liter <br /> (pg/L), which is below the water quality objective of 100 pg/L for TPH-d. These spurious <br /> detections have since not been observed and petroleum hydrocarbon concentrations have <br /> since been non-detect in groundwater. The results of the most recent quarterly groundwater <br /> sampling event, conducted on 23 December 2010, were below the reporting limits for analyzed <br /> constituents in the 34 groundwater monitoring wells at the Site (Table 3). <br /> Table 3 - Most Recent Groundwater Anal tical Results (in pg/L) <br /> Well TPH-c TPH-d Benzene Toluene benzenEthyl- Xylenes <br /> Naphthalene <br /> MW-1(B) to MW-19(B) < 250 < 50 <0.50 <1.0 < 1.0 < 1.0 < 10 <br /> MW-2(C&D) to MW- < 250 < 50 <0.50 <1.0 < 1.0 < 1.0 < 10 <br /> 16 C&D <br /> Soil vapor samples were collected using direct push temporary soil gas probes within and <br /> adjacent to select backfill areas between 5 and 25 feet bgs, during December 2006 in <br /> Neighborhoods C and D and September 2007 in Neighborhood B. Results of the soil vapor <br /> sampling event are shown in Table 4. <br />