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Mr. Jeff Baker - 3 - 11• March 2009 <br /> Stockton Terminals TechnicalOmittee <br /> the STTC will prepare and submit a pilot study report, which will include evaluation of <br /> the data and recommendations. <br /> The STTC conducts monitoring at the Site pursuant to the requirements of Monitoring <br /> and Reporting Program (MRP) No. R5-2004-0823. Stantec conducted groundwater <br /> monitoring and sampling for the fourth quarter 2008 during November, and submitted <br /> the 31 January 2009 Fourth Quarter 2008 & Annual Groundwater Monitoring, and <br /> Remedial Summary Report (Annual Report). <br /> In the fall of 2004, the STTC began operation of two ozone sparge (OS) systems to <br /> clean up groundwater pollution migrating downgradient of the Site. The system is <br /> comprised of 57 A zone and 16 B zone wells connected to two five pounds-per-day <br /> (lbs/day) ozone generators. The OS system is divided into two portions. The west <br /> system is downgradient of Tesoro, and the east system is downgradient of BP. Between <br /> June and September 2008, the STTC estimates that the east system and west system <br /> had run times of 78 and 100 percent, respectively. The STTC is planning upgrades <br /> during the first quarter of 2009 with the objective of increasing system run times. <br /> The STTC monitors the ozone injection system using 12 A and B zone wells shown on <br /> the table on page 6.2 of the Annual Report. Six of the wells have been designated as <br /> remedial observation wells. A contingency plan is triggered if the concentration of <br /> benzene, toluene, ethylbenzene, and xylene (collectively BTEX) or methyl tertiary butyl <br /> ether (MTBE) in any of these wells, or TBA in the remedial observation wells, exceeds <br /> specified compliance limits. BTEX and MTBE concentrations in the ozone injection <br /> monitoring program wells were below compliance limits during the fourth quarter. <br /> Toluene, xylene, and TBA in remedial observation wells PS/MW-18 and AR/MW-18B <br /> exceeded compliance limits but not enough to warrant implementation of the <br /> contingency plan. <br /> The Annual Report also documented that, consistent with historical observations, <br /> separate phase hydrocarbon (SPH) sheen was observed in two A zone wells (TO/MW-1 <br /> and TS/MVV-2) on the Time Oil and Tesoro facilities. No STTC B, C, or D zone wells <br /> contained SPH. During the fourth quarter 2008, TS/MW-2 contained the highest <br /> concentrations of TPHg and TPHd at 240,000 micrograms per liter (pg/L) and <br /> 1,400,000 pg/L, iespeciively. Consistent with historical observations, the highest <br /> concentrations of BTEX were in BP tank farm monitoring well AR/MW-8A at 8,800 pg/L, <br /> 11,000 pg/L, 2,700 pg/L and 11,000 pg/L, respectively. TONT-2, located in the southwest <br /> entry area of the Time Oil and Tesoro facilities, typically contains the highest paired <br /> concentrations of TBA and MTBE. During the fourth quarter, however, the highest <br /> concentrations of MTBE and TBA were detected in BP tank farm wells AR/MW-50 and <br /> AR/MW-13C at 16,000 pg/L and 5,600 pg/L, respectively. <br /> The Annual Report contains monitoring results for the seven (PS/MW-20A through <br /> PS/MW-20D, OW-3CR, OW-3DR, and TS/MW-3D) newly-installed wells. The laboratory <br /> analytical results show the TPHg, TPHd, benzene and TBA concentrations in all new <br /> C and D zone wells exceed the WQOs for these constituents. Except for TBA, sample <br /> results for these constituents also exceeded the WQOs in the furthest downgradient <br /> D zone well, OW-5D. <br />