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Mr. Jeff Baker - 2 - 25 April 2008 <br /> Stockton Terminals Technicalomittee • ! <br /> up groundwater pollution migrating downgradient from the Site. The system is comprised of 57 A <br /> zone and 16 B zone wells connected to two 5-pounds-per-day (lbs/day) ozone generators. <br /> During the second, third and fourth quarters, depth to groundwater measurements ranged from <br /> about 1.4 feet below ground surface (bgs) in AR/MW-5A to 11.2 bgs in OW-1A. Monitoring well <br /> resurveying is proposed to resolve the A and B zone localized water table mounding typically <br /> present at wells PS/WC-1S and M and the radial inward flow at wells SP/WC-1S and M. <br /> Therefore, water elevations from these wells were not included in gradient calculations. During <br /> 2007, the direction of groundwater flow ranged from east-southeast in the A zone to the <br /> southeast in the B, C, and D zones. Horizontal gradients ranged from 0.002 foot per foot (ft/ft) in <br /> the C and D zones to 0.07 ft/ft in the A zone. <br /> The direction of the vertical gradient at the Site is predominantly downwards between the four <br /> hydrostratigraphic units. During 2007, the highest magnitudes of the downward gradients were <br /> 0.025 ft/ft between the A and B zones, 0.074 between the B and C zones, and 0.072 ft/ft <br /> between the C and D zones. Higher vertical gradients were calculated at the PS/WC=1 S and M <br /> well pair, but Regional Water Board staff understands the groundwater elevations from these <br /> wells should not be used until the proposed resurveying is completed. <br /> The highest COC concentrations typically underlie the BP and Time Oil facilities. As reported in <br /> the 1 February 2008 Fourth Quarter and Annual 2007 Site Status, Groundwater Monitoring and <br /> Remedial Summary Report (Annual Report), SPH or SPH sheen was observed in eleven A zone <br /> wells; 7 on the Arco Site, 4 on Time Oil, and one on Tesoro. Consistent with historical <br /> observations, no B, C, and D zone wells contained SPH. The highest COC concentrations <br /> observed in each hydrostratigraphic zone during the second, third, and fourth quarters of 2007, <br /> are tabulated below. <br /> Groundwater Zones <br /> A B C D <br /> cocs Maximum concentration (Ng/L)/Well ID <br /> TPHg 110,000/AR/MW-8A 16,000/AR/MW-11B 3,600/OW-9C 12,000/TS/MW-2D <br /> TPHd 160,000/TO/MW-1 18,100/AR/MW-1113 1,900/OW4C 2,200/TS/MW-2D <br /> benzene 9,600/TO/MW-1 9,400/AR/MW-11B 2,000/0W-9C 5,800/TS/MW-2D <br /> toluene 13,000/AR/MW-8A 110/AR/MW-11B 18/OW-9C 38/TS/MW-2D <br /> eth (benzene 4,300/AR/MW-10A 18/AR/MW-18B 5.1/OW-9C 4.3AR/MW-14D <br /> Total xylenes 16,000/AR/MW-10A 140/AR/MW-11B 23/OW-9C 59/TS/MW-2D <br /> MTBE 28,000/AR/MW-50 3,600/AR/MW-8B 200fTS/MW-1C 4.4/TS/MW-2D <br /> TBA 38,000/ MW-50 860/AR/MW-8B 400/TS/MW-1C 1,600 TS/MW-2D <br /> TAME 340/AR/MW-50 13/AR/MW-8B ND ND <br /> Explanation <br /> Ng/L micrograms per liter <br /> The OS system installed in 2004 is divided into two portions. The west OS system is <br /> downgradient of Tesoro and the east system is downgradient of BP. The STTC estimates that, <br /> collectively, the OS system has destroyed about 1,650 lbs of hydrocarbons since system <br /> operation commenced. This total represents an overestimation, however, since the lifetime <br />