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Mr. Jeff Baker - 3 - 17• February 2011 <br /> Stockton Terminals Technical 0mittee <br /> attributed to mechanical malfunctions. The STTC estimates that historically, about <br /> 10,200 pounds of ozone have been injected, and 3,370 pounds of hydrocarbons have <br /> been destroyed. <br /> The STTC monitors the OS system using an array of six remedial observation (RO) <br /> wells, two midpoint wells, and four trigger wells. A contingency plan is triggered if the <br /> concentration of BTEX, MTBE or TBA in any of these compliance wells exceeds the <br /> termsdescribed in the Revised Contingency Plan (Appendix L of the:Annual Report). <br /> During the fourth quarter, benzene concentrations exceeded the default 0.5 Ng/L <br /> compliance level in all four trigger wells (OW-2A, OW-2B, OW-4A, OW-413) for the first <br /> time. The STTC characterizes the detections as spurious. The Revised Contingency <br /> Plan requires the compliance level to be exceeded for three consecutive quarters <br /> before remedial actions are required. Therefore, no actions are necessary at this time. <br /> STTC member company Tesoro is conducting two pilot studies of remedial technologies. <br /> A 1-year, D-zone oxygen injection (01) pilot study proposed in the 27 January 2009 Pilot <br /> Study Work Plan and Revised Contingency Plan commenced on 25 January 2011. <br /> Instead of injecting oxygen, Tesoro is using a passive source of oxygen, the Waterloo <br /> EmitterTM (WE), a down-hole apparatus which is connected to pressurized pure oxygen. <br /> Tesoro anticipates that oxygen will be delivered via the WE at a rate of about 3.64 liters <br /> per day. Baseline groundwater monitoring was conducted for dissolved oxygen/ <br /> oxidation reduction potential(DO/ORP) and biodegradation parameters during <br /> November and December 2010 in TS/MW-3DR and TS/MW-4D. Quarterly groundwater <br /> monitoring data from TS/MW-2D, TS/MW-3D, TS/MW-3DR and TS/MW-4D <br /> represented baseline contaminant data. Bio Traps®deployed in TS/MW-2D, <br /> TS/MW-3DR, and TS/MW-4D in November 2010 were retrieved and analyzed. The <br /> results of the baseline monitoring are summarized in the 27 January 2011 Oxygen <br /> Injection Pilot Study Status and Implementation Report (Report). <br /> The results of baseline monitoring show that benzene, TPHg, and TPHd are the <br /> principal contaminants of concern in TS/MW-2D, TS/MW-3D, TS/MW-3DR and <br /> TS/MW-4D. There are minor concentrations of toluene, ethylbenzene, and xylene. <br /> Maximum concentrations of benzene, TPHg, and TPHd in baseline monitoring are <br /> 5,300 pg/L, 9,800 pg/L, and 2,800 pg/L, respectively, in TS/MW-3DR. These <br /> concentrations are consistent with historical results. <br /> Table 3 of the Report compares redox parameters observed in the center <br /> (TS/MW-3DR) with the fringe (TS/MW-4D) of the OI pilot study plume. The <br /> concentration ratios of electron acceptors to reduction products of nitrate/nitrite and <br /> sulfate/sulfide were low to non-detect in both wells. The respiration byproduct and <br /> ferrous iron (Fe ll) and the macronutrient orthophosphate were non-detect. Carbon <br /> dioxide (CO2), alkalinity and methane concentrations were higher in TS/MW-3DR than <br /> TS/MW-4D, providing evidence of higher microbial respiration in the center of the <br /> plume. The high concentrations of the waste product methane in both TS/MW-3DR and <br /> TS/MW-4D correlate with the absence of more thermodynamically efficient electron <br /> acceptors and suggest that biodegradation may be occurring via methanogenisis using <br /> CO2 as the electron acceptor. The BioTrap data indicate that the highest biomass and <br />