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Mr. Jeff Baker <br /> Stockton Terminals Technicommittee 2 • 16 June 2010 <br /> As shown in Tables D-1 through D-4, during the first quarter 2010, the highest COC <br /> concentrations generally occurred in A zone wells in the BP aboveground tank (AGT) <br /> area. In the deeper zones, maximum concentrations were encountered on the Tesoro <br /> property. The highest concentrations of TPHg and TPHd were in AR/MW-8A and <br /> AR/MW-10A, at 94,000 micrograms per liter (pg/L) and 210,000 pg/L, respectively. The <br /> highest concentration of benzene was detected in TO/WC-26 at 9,700 pg/L, The <br /> highest concentrations of MTBE and TBA were detected in AR/MW-50 at 9,700 pg/L <br /> and 7,800 pg/L, respectively. <br /> Groundwater at the BP facility is polluted with MBAs. BP believes the pollution <br /> originates from a November 2008 fire suppression foam release. The water quality <br /> to 10 well casing volumes from wells containing MBAs before <br /> objective (WQO) for MBAs is 500 pg/L, To address the concentrations, BP over-purges <br /> up sampling. BP <br /> describes over-purging as the process of removing 10 well casing volumes from a <br /> monitoring well prior to sampling. Table 6 shows that the maximum MBAs detection <br /> was 1,900 pg/L in AR/MW-9B. Until the fourth quarter 2009, there were 17 wells in <br /> Which MBAs was ever detected at or above 500 pg/L. During the first quarter 2010, this <br /> number increased to 22. MBAs concentrations exceeding 500 pg/L were observed for <br /> the first time in AR/MW-5B, AR/MW-50, AR/MW-8C, AR/MW-9B, AR/MW-10C, <br /> AR/MW-11C, and AR/MW-21 C. <br /> In the fall of 2004, the STTC began operation of two ozone sparge (OS) systems to <br /> clean up groundwater pollution migrating downgradient from the Site. The system is <br /> comprised of 57 A zone and 16 B zone wells connected to two 2 pounds-per-day <br /> (lbs/day) ozone generators. The OS system is divided into two portions. The west <br /> system is downgradient of Tesoro, and the east system is downgradient of BP. During <br /> the first quarter, the STTC estimates that the east system and west system had ozone <br /> sparge run times of about 90 and 75 percent, respectively. Run time difficulties are <br /> attributed to system malfunctions and maintenance activities for recent system <br /> upgrades. The STTC estimates that historically, about 8,500 pounds of ozone have <br /> been injected and 2,800 pounds of hydrocarbons have been destroyed. <br /> The STTC monitors the ozone injection system using an array of six remedial <br /> observation(RO) wells, two midpoint wells, and four trigger wells. A contingency plan is <br /> triggered if the concentration of BTEX, MTBE or TBA in any RO well exceeds <br /> compliance limits. Table 7 shows that the TBA concentration in RO well AR/MW-18B <br /> decreased from 49 pg/L to 44 pg/L during the first quarter. These concentrations <br /> exceed the compliance limit of 6.6 pg/L. Pursuant to the terms described on Page 3 of <br /> the Revised Contingency Plan (Appendix K of the First QMR), three consecutive <br /> exceedences of an order of magnitude greater than the compliance limit will trigger <br /> installation of a second ozone sparge array east of the RO wells. None of the <br /> concentrations measured so far has been an order of magnitude above the compliance <br /> limit. <br /> The Revised Contingency Plan also sets compliance limits consisting of the WQOs for <br /> BTEX and MTBE in four trigger wells located downgradient of the RO wells. Three <br /> consecutive exceedences of the WQO would trigger installation of another ozone <br /> sparge array east of the trigger wells that include OW-2A, OW-4A, OW-26, and <br />