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Mr. Jeff Baker -4 - 16.June 2010 <br /> Stockton Terminals Tech nic9ommittee • <br /> concentration reductions on the order of those that are currently being observed. <br /> These low concentrations later rebounded to elevated concentrations. As such, we <br /> do not concur with STTC's conclusions that (1) overall hydrocarbon concentration <br /> trends in groundwater beneath and downgradient of the Site appear relatively stable <br /> to decreasing, and (2) results from the ozone injection monitoring program indicate <br /> the East and West remedial systems are effectively mitigating off-site migration of <br /> petroleum hydrocarbons. Instead, our observations of the overall rising TBA <br /> concentrations in AR/MW-18B and TPHd in OW-4B and OW-4C both suggest that <br /> the perimeter ozonation system is not effective at controlling offsite migration, <br /> particularly in the lower water bearing zones. <br /> 2. Table 8 displays the four quarters of baseline data collected pursuant to Title 27 <br /> Section 20415(e)(6) to establish baseline conditions for the hydrogen peroxide <br /> study. However, Tesoro did not use the data to calculate the baseline <br /> concentrations for the five parameters prior to initiating the study in March. In order <br /> to expedite this task, we suggest that the overall mean for each compound should <br /> be calculated by dividing the sum of the concentrations for each parameter in the <br /> four wells by the sum of the total number of samples. Tesoro needs to submit the <br /> result of this baseline calculation by 7 July 2010. <br /> Title 27 Section 20415(e)(8)(A) through (E)7 provides a list of allowable data <br /> analytical methods for determining measurably significant changes to baseline <br /> concentrations. Section (e)(7) requires the method chosen to be identified before it <br /> is implemented. However, Tesoro has implemented the pilot study before identifying <br /> the statistical method. By 7 July 2010, Tesoro needs to submit its selection of a <br /> hypothesis testing method, pursuant to Section (e)(7), for our approval. <br /> 3. Our 11 March 2010 letter required BP to submit the evaluation of alternate remedial <br /> technologies referenced in its 29 October 2009 Helium Tracer Study for Biosparging <br /> Feasibility Report by 1 May 2010. Our letter stated that the evaluation must also <br /> include a method for mitigating MBAS based on groundwater monitoring data which <br /> show that WAS is widely distributed throughout the ARCO facility. That evaluation <br /> has not been submitted. However, since STTC intends to expand MBAS sampling to <br /> the wells downgradient of the BP facility, the 1 May 2010 deadline will be extended <br /> to allow the collection of four quarters of MBAS data in downgradient wells. <br /> Therefore, the evaluation of alternate remedial technologies is now due 1 May 2011. <br /> In summary, by 7 July 2010, please submit the results of the baseline metals <br /> calculations and the proposed statistical method to evaluate changes in the baseline <br /> values. If you have any questions regarding this letter, you may contact me at <br /> (916) 464-4811 orb mail at betaylor@waterboards.ca.gov. <br /> BRIAN TA .- OR, P.G. <br /> Engineering Geologist <br /> cc list on next page <br />