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Montgomery Wards / Unocal Station #5098 - 5 - 12 April 2012 <br /> 5400 / 5606 Pacific Avenue <br /> Stockton, San Joaquin County <br /> benzene (6.57 mg/kg) at Wards. And prior to remediation by over-excavation in 1988 at <br /> Unocal, residual soil contamination failed the ESLs for TPHg (700 mg/kg) and benzene <br /> (9.2 mg/kg) for gross contamination and direct exposure at 49' bgs at Unocal. Prior to <br /> upgrades to the SVE/AS in 2008, soil at 50' bgs (below water table) failed the ESLs for <br /> TPHg (gross contamination and direct exposure), (gross contamination and direct <br /> exposure), benzene (direct exposure), toluene (direct exposure), ethylbenzene (direct <br /> exposure), and xylenes (gross contamination and direct exposure). Declining <br /> groundwater concentrations since 2008 show that leaching, if occurring, is not <br /> exceeding the rate of natural attenuation of the plume. Both sites residual soil <br /> contamination are below normal construction worker exposure depths, and Wards <br /> residual soil contamination is below the water table (34' bgs in 2010). Post remediation <br /> confirmation soil sampling was not conducted. In addition to declining groundwater <br /> concentration trends, natural attenuation of petroleum hydrocarbons was confirmed by <br /> specific groundwater analyses (nitrate, sulfide, sulfate, ferrous iron, total inorganic <br /> carbon, dissolved oxygen, and oxidation-reduction potential) conducted during routine <br /> monitoring in July 2008. Residual petroleum hydrocarbons in Site soil, soil vapor, and <br /> groundwater pose a minimal threat to human health or the environment. Land use <br /> (commercial) is not expected to change in the foreseeable future. <br /> Sensitive Receptor Survey <br /> In 2001, the RIW well (approximately 350' southwest of Unocal, and 200' west of <br /> Wards) was properly abandoned and relocated over 3,300 feet from the commingled <br /> plume. A subsequent 2001 sensitive receptor survey identified no additional supply <br /> wells located within 2000' of the site. No wells are threatened by the petroleum <br /> hydrocarbons release at this site. <br /> Site Geology and Hydrogeology <br /> Site Iithology consists of clay, silt, and sand to 110' bgs, the maximum extent of <br /> investigations. Between 1993 and 2010, depth to water varied from 28' bgs to 60' bgs. <br /> Groundwater flow direction varied from southwest to southeast, and the gradient varied <br /> from 0.002 ft/ft/ to 0.004 ft/ft. <br /> Residual Mass Calculation <br /> The consultant did not estimate the mass removed by over-excavation at Unocal. The <br /> initial mass of TPHg in soil was approximately 12,000 pounds for Wards. SVE/AS <br /> removed 11,638 lbs of TPHg from soil. Approximately 356 lbs of TPHg remain in soil <br /> and groundwater at Wards. Groundwater will reach Water Quality Goals (WQGs) in <br /> 2039. <br />