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' Mr. James L. Barton <br /> April 8, 2009 <br /> ' Page 5 <br /> 1Q09 TPHg Mass(pounds) 1Q09 Benzene Mass(pounds) <br /> Groundwater Mass 53 0.3 <br /> ' Soil Mass 871 0.9 <br /> Total 924 1.2 <br /> ' The spreadsheet used for calculating the remaining mass as well as the assumptions used in the <br /> estimation is included as Attachment E. The mass removed from the soil vapor extraction system during <br /> the first quarter of 2009 is presented under the Soil Vapor Extraction System Status discussion. <br /> Remediation System Update <br /> Residual dissolved concentrations of petroleum hydrocarbons beneath the Site are volatilized, extracted, <br /> ' and treated through the operation of a combined air sparge (AS) and soil vapor extraction (SVE) <br /> remediation system. Vapors from the SVE system are vented through two 1,000 pound granulated <br /> ' activated carbon (GAC) vessels prior to discharging to the atmosphere in accordance with the San <br /> Joaquin Valley Air Pollution Control District(SJVAPCD) permit to operate number N-5879-1-1. Figure 9 <br /> depicts the location of the remediation compound and a plan layout of the remediation well network. <br /> ' Soil Vapor Extraction System Status <br /> Vapor samples were collected from the influent and effluent sample ports of the SVE system on <br /> 1 January 13, February 2, and March 10, 2009. Vapor samples were collected in 1-Liter Tedlar bags and <br /> submitted for analysis under COC protocols to Air Toxics LTD. of Folsom, California. The samples were <br /> analyzed for TPHg and BTEX by modified EPA Method TO-3. Vapor samples had initially been collected <br /> ' on March 3, 2009 for analysis; however, the laboratory reported insufficient volume in the Tedlar bag. <br /> Vapor samples were recollected on March 10, 2009. The samples from March 3, 2009 were not analyzed. <br /> Results of the vapor samples, as well as a summary of the SVE system operational parameters and vapor <br /> treatment efficiencies are presented in Table 1. Data validation was performed on the vapor analyses, <br /> and the checklists are included as Attachment B. The data validation found high surrogate recoveries <br /> due to matrix interferences for each of the influent vapor samples. These qualifications do not affect the <br /> ' integrity of the data reporting. The discharge to the atmosphere, as quantified by both the mass emission <br /> rate and the TPHg concentration of the effluent, was within the limits of the SJVAPCD permit. Copies of <br /> the operation and maintenance (O&M) field sheets documenting the collection of the vapor samples are <br /> ' included in Attachment F. Copies of the certified laboratory analytical reports with COC documentation are <br /> included in Attachment G. <br /> The SVE system operated continuously between O&M visits during the first quarter 2009. During O&M <br /> visits, the SVE system may have required a system shut-down for 4 to 6 hours at a time. The SVE system <br /> was not operating for approximately two weeks at the beginning of first quarter 2009. As documented in <br /> the AECOM report dated January 12, 2009 (Quarterly Groundwater Monitoring and Remediation Status <br /> Report and Updated Site Conceptual Model For the Fourth Quarter of 2008), the adsorptive capacity of the <br /> carbon in the GAC vessels had been reached on December 15, 2008, and the SVE system was shut down <br /> ' for the remainder of fourth quarter 2008, pending a GAC change-out scheduled for early January 2009. <br /> On January 13, 2009, the GAC was replaced in both GAC vessels, and the SVE system was restarted. <br /> ' AECOM Environment AECOM <br />