Laserfiche WebLink
AXOM <br /> Mr. James L. L. Barton <br /> Regional Water Quality Control Board—Central Valley <br /> October 27, 2010 <br /> Page 4 <br /> hydrostratigraphic cross-sections: one across the former Unocal site and one across the former <br /> Wards site. A cross-section location map and four geologic cross-sections termed A-A', B-B', C-C' <br /> and D-D' are included in Attachment E as Figures D-1 through D-5. Cross-sections have been <br /> updated with the groundwater monitoring data and analytical results for TPHg, benzene, and methyl <br /> tertiary butyl ether(MTBE)from the third quarter semi-annual event of 2010. Figure D-5 of <br /> Attachment E uses data from air sparge and vapor extraction wells. Cross-sections also include soil <br /> analytical data collected at the time of well installation. <br /> Remaining Contaminant Mass <br /> In a letter dated December 5, 2008, the CVWB requested "An evaluation of the effectiveness of <br /> cleanup activities and an estimate of pollutants treated versus pollutants remaining (may be <br /> submitted quarterly as an ancillary report)". Since the fourth quarter 2008, AECOM has provided <br /> these mass estimates to the CVW B to comply with the directive, however, AECOM cautions reliance <br /> on these estimates. The calculations are based solely on the areal extent of impacts depicted on an <br /> iso-concentration map (which is an interpretation of the approximate extent of impacts in a given <br /> hydrostratigraphic unit), and assumptions on the consistency of the vertical extent of impacts across <br /> the hydrostratigraphic unit (which could either underestimate or overestimate the mass at a given <br /> time). Spatial and temporal variations in the plume configuration, due to seasonal concentration <br /> fluctuations, can also provide misleading mass estimates. <br /> For third quarter 2010, the remaining mass was calculated in the same manner as the previous <br /> quarters. Estimates were calculated for the areal extent of the TPHg and benzene impacts in the <br /> shallow hydrostratigraphic A/B unit using the iso-concentration maps presented as Figures 6 and 7. <br /> Estimates for units C and D were not calculated because neither TPHg nor benzene was detected in <br /> the third quarter 2010 in monitoring wells screened in those hydrostratigraphic units. The estimated <br /> hydrocarbon mass remaining is shown in the table below and is compared to the estimated <br /> hydrocarbon mass calculated for the fourth quarter 2008 and the first quarter 2010. Since fourth <br /> quarter 2008, the estimated remaining hydrocarbon mass of TPHg and benzene has been reduced <br /> by 88.9% and 99.3°/x, respectively. <br /> 4Q08 4Q08 1Q10 1Q10 3010 3Q10 <br /> TPHg Benzene TPHg Benzene TPHg Benzene <br /> Mass Mass Mass Mass Mass Mass <br /> (pounds) (pounds) (pounds) (pounds) (pounds) (pounds) <br /> Groundwater Mass 102 1.5 20.5 0.03 2.3 0.01 <br /> Saturated Soil Mass 1,668 4.0 335.6 0.08 38.2 0.02 <br /> Total 1,770 5.5 356.1 0.11 40.5 0.03 <br /> The spreadsheet used for calculating the remaining mass, as well as the assumptions used in the <br /> estimation, is provided as Attachment F. <br />