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Kennedy/Jenks Consultants <br /> Appendix C: Groundwater Sampling and Analysis Plan <br /> This Groundwater Sampling and Analysis Plan (SAP)will be used as a guidance document for <br /> individuals responsible for conducting groundwater monitoring and sampling activities and will be <br /> used in conjunction with the Groundwater Well Installation Work Plan for Franzia Winery operated <br /> by The Wine Group. <br /> CA Analytical Methods, Sample Containers and Preservatives <br /> Each groundwater sample will be analyzed for the suite of constituents outlined in Table C.1. <br /> Table CA also outlines the analytical methods, associated reporting limits, sample containers and <br /> preservatives. <br /> TABLE CA — ANALYTICAL PROTOCOL <br /> Reporting Con- Sample Holding <br /> Constituent Test Method Limit(mg/1) tainer Volume Preservative(a) Time <br /> Nitrate-Nitrogen EPA 300.0 0.1 P 250 ml None 48 hours <br /> (NO3 as N) <br /> Ammonia—Nitrogen EPA 350.3 0.1 P 250 ml H2SO4 pH<2 28 days <br /> ` (NH4 as N) <br /> Total Kjeldahl Nitrogen EPA 351.4 1.0 P 1 Liter H2SO4 pH<2 28 days <br /> rTMN) <br /> Boron(B) EPA 60108 0.02 P 250 ml HNO3 pH<2 6 months <br /> Calcium(Ca) EPA 200J 0.5 P 250 ml HNO3 pH<2 6 months <br /> Chloride(CI) EPA 300.0 0.2 P 250 ml None 28 days <br /> Electrical Conductivity EPA 120.1 1 (pmhos/cm P 250 ml None 28 days <br /> (EC) @ 25C) <br /> �. Iron(Fe) EPA 6010B 0.1 P 250 ml HNO3 pH<2 6 months <br /> Magnesium(Mg) EPA 200.7 0.5 P 250 ml HNO3 pH<2 6 months <br /> �- Manganese(Mn) EPA 60108 0.01 P 250 ml HNO3 pH<2 6 months <br /> Phosphorus(P) EPA 365.2 0.03 P 250 ml H2SO4 pH<2 28 days <br /> pH EPA 0.1 unit P 250 ml None 24 hours <br /> 904013/9045C <br /> Sodium(Na) EPA 200.7 0.5 P 250 ml HNO3 pH<2 6 months <br /> Sulfate(SO4) EPA 300.0 5.0 P 250 ml None 28 days <br /> Total Dissolved Solids EPA 160.1 10 P 250 ml None 7 days <br /> ` <br /> (FDS) <br /> Total Alkalinity as EPA 310.1 1.0 P 250 ml None 14 days <br /> Calcium Carbonate <br /> (CaCO3) <br /> Bicarbonate(HCO3) EPA 310.1 1.0 P 250 ml None 14 days <br /> (a) All samples should be kept at 4 degrees Celsius from the time of collection until analysis. <br /> Notes: <br /> P=Polyethylene <br /> EPA=Environmental Protection Agency <br /> ml=milliliter <br /> Groundwater Protection Work Plan, The Wine Group C-1 <br /> Franzia Winery, Ripon, California <br /> 9U 9—pladmi*0.33012001_xinegroup109.epMslwodylan�appentlicesktsap d- <br />