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C-SHADRIFS.6/WPADD.9 <br /> 05/17/90 <br /> described by Gilbert (1987) at the site of the 109-ppm arsenic <br /> measurement. The purpose will be to verify that the sample is part of <br /> the entire population of SHAD soils. Seven boring locations will be <br /> sampled using split-spoon samples to a total depth of 15 ft. Samples <br /> ' will represent composites collected over 0- to 5-ft, 5- to 10-ft, and <br /> 10- to 15-ft intervals. The first boring location will be immediately <br /> adjacent to the original location at which the sample with 109-ppm <br /> ' arsenic concentration was collected. The remaining six sampling <br /> locations will be chosen as shown in Figure 1. The 25-ft interval <br /> between grid lines will yield a 95-percent confidence level, assuming <br /> that the arsenic concentration is at least 5 ft in diameter. <br /> Additional soil sampling will also be done to collect material <br /> containing high concentrations of arsenic so that the specific identity <br /> of the arsenic-bearing compounds can be determined. Arsenic <br /> concentrations do not correspond with the VOC contaminant plume, <br /> ' suggesting a separate source and/or mechanism for arsenic concentrations <br /> in the groundwater. High arsenic values have been measured only in <br /> ' certain wells along the western, southern, and eastern boundaries; one <br /> well in the South Balloon Area; three wells in the North Balloon Area; <br /> and a single well in the Central Depot Area (i.e. , from restricted <br /> ' locations) . With one exception, all of the elevated arsenic <br /> measurements are restricted to wells in the A-zone aquifer. <br /> The purpose of this section is to define the sampling locations and the <br /> ' number of samples required to define the mechanisms controlling this <br /> restricted anomalous arsenic concentration in the groundwater. To <br /> accomplish that, a model incorporating the subsurface geology, the <br /> ' surface water and groundwater systems, and the solid mineral phases <br /> buffering the high arsenic concentrations in the groundwater must be <br /> ' formulated. <br /> 1 9 <br />