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Mr. Jerry Lile <br /> October 2, 2001 <br /> Page 2 <br /> and Bruya, Inc. of Seattle Washington, a California-certified laboratory analyzed soil and grab <br /> groundwater samples for petroleum-related hydrocarbons. Forensic evaluation of the soil samples <br /> indicated that the petroleum hydrocarbons present in the soil likely represent degraded crude oil. <br /> Document Reviewed <br /> HERD reviewed 'Report of Additional Soil and Groundwater Investigation and results of the Up- <br /> dated Human Health Screening Evaluation, Ridgeway(former Burns] Property (APN 232-170-05), <br /> Tracy, California". This document, dated July 20, 2001, was prepared by Geomatrix Consultants, <br /> 2101 Webster Street, 12'h Floor, Oakland, California 94612, contractors to Chevron Environmental <br /> Management Company. <br /> Scope of Review <br /> The 'Report of Additional Soil and Groundwater Investigation and Results of the Updated Human <br /> Health Screening Evaluation, Ridgeway (former Bums] Property (APN 232-170-05), Tracy, Califor- <br /> nia"was reviewed for scientific content and sufficiency to support a risk-based clean closure of <br /> the site under the Voluntary Cleanup Program. Sampling details, analytical methodology, and <br /> technical approach were evaluated. <br /> General Comments <br /> A total of 10 soil samples and 4 grab groundwater sample were taken to define the vertical and <br /> horizontal extent of petroleum hydrocarbon affected soil and groundwater. Soil sample depth <br /> began at 8.5 feet bgs and advanced downward to 13- to 19 feet bgs. Surface soils were not <br /> affected and, presumably, the former pipeline was located approximately 5 feet below grade. <br /> The extent of petroleum hydrocarbon contamination in the soils and groundwater adjacent to the <br /> former pipeline right-of-way is limited vertically and horizontally. Levels of petroleum-related <br /> hydrocarbons ranged from ND to 14,000 mg/kg for TPH crude and from ND to 5,600 mg/kg for <br /> TPH diesel in soils. The PAHs acenaphthene, fluorene, and phenanthrene were detected in <br /> shallow groundwater at 0.1, 0.3, and 0.2 µg/L respectively. BTEX constituents were less than <br /> the detection level in soils. Low levels of PAHs (commonly associated with crude oils, fuel oils, <br /> and diesel) were detected up to 6.8 mg/kg for naphthalene, up to 5.7 mg/kg for phenanthrene, <br /> and up to 3.7 mg/kg for fluorene. Two PAHs, benz(a)anthrancene and chrysene (more notably <br /> associated with crude oil) were the only PAHs detected at the site that were potential carcino- <br /> gens (0.13 and 1.0 mg/kg respectively). None of the constituents identified above were from <br /> surface soil samples. Based on the levels of petroleum-related constituents identified at the <br /> site, the soils were not completed saturated with product and the product was only identified in <br /> the depth profile of from 8.5 to 11 feet bgs. <br /> The constituents of concern identified on the property included eight PAHs (acenaphthene, <br /> benz(a)anthracene, chrysene, fluoranthene, fluorene, naphthalene, phenanthrene, and pyrene) <br /> and and the volatile organics toluene and xylene 0.7 and 1.5 ug/L. The maximum concentra- <br /> tions of these constituents were used as source terms to estimate chronic daily and jifetime <br /> doses of constituents for estimating potential excess cancer risk and noncancer threshold ef- <br /> fects. <br />