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L v <br /> L4.0 Discussion and Request for Site Closure <br /> ure <br /> During the January 2010 monitoring event,low levels of TPHD were detected in groundwater <br /> samples collected from monitoring wells MW-1,MW-2,and MW-6 prior to silica gel cleanup. NCL <br /> reviewed the laboratory chromatograms and indicated in their analytical report(Appendix C)that <br /> Lthe samples contained material in the diesel range of molecular weights;however,the material did <br /> not exhibit the peak pattern typical of diesel. Upon processing the samples through a silica gel <br /> cleanup procedure and re-analyzing the samples,TPHMO and TPHD were nondetectable in the <br /> L groundwater samples collected from wells MW-1,MW-2,and MW-6. <br /> The purpose of performing a silica gel cleanup is to remove polar and semi-polar compounds that <br /> Lmay interfere with analytical results. Natural Organic Matter(NOM) may be present in site soils, <br /> due to natural or anthropogenic sources. NOM often consists of polar and semi-polar compounds <br /> that have similar molecular weights as diesel or motor oil range hydrocarbons. Biogenic <br /> Linterference is the term used to describe the NOM that is quantified and reported in the diesel or <br /> motor oil range of molecular weights. Generally,most fresh,non-biodegraded petroleum <br /> hydrocarbons are considered non-polar compounds (ADEC,May 2006). Therefore,the analytical <br /> L results obtained during the January 2010 monitoring event indicate that the low levels of material <br /> detected in groundwater samples collected from monitoring wells MW-1,MW-2,and MW-6 may <br /> be NOM. <br /> LSHN requests that the site be considered for closure based on the information provided in the <br /> following sections. <br /> 4.1 Site History <br /> LThe site is located in a mixed residential,light industrial,and agricultural area of Acampo, <br /> California. The historic operations at the site have been chronicled since 1955 and have consisted <br /> predominantly of asphalt related operations. The site was purchased by John and Mike Telfer in <br /> 1985,at which time WOS began operation. WOS has used the site for storage,dispensing,and <br /> mixing of asphalt and lignin-based road oil,which included the operation of several Aboveground <br /> Storage Tanks (ASTs). The site is currently being used as a transfer and storage facility of asphalt <br /> L and lignin-based road oil,which is transferred from a mobile AST into 55-gallon drums,and then <br /> stored on site prior to transportation. The site has historically been used to store liquid asphalt <br /> cutback,which is a petroleum product composed of diesel range hydrocarbons and heavy end <br /> V hydrocarbons. Five Underground Storage Tanks (USTs)were historically used to store liquid <br /> cutback asphalt,diesel,and gasoline. <br /> Eight ASTs are located within a bermed area on the central portion of the site;however,the ASTs <br /> are not currently in use. Four small ASTs were recently removed in the northeastern corner of the <br /> site(Figure 2). Prior to dismantling the ASTs,the underground distribution piping,which <br /> connected the two AST areas,was drained,flushed,and abandoned in place. <br /> On October 22,1987,WOS,at the request of the California Regional Water Quality Control Board, <br /> L Central Valley Region(RWQCB),removed five USTs from the site,consisting of two 20,000-gallon <br /> USTs that were used to store liquid cutback asphalt,one 2,000-gallon UST used to store diesel,one <br /> I <br /> \\Eureka\projects\2007\007152-WOS\PUBS\rpt\20100324-1stHalf2(T10GWMR&RFC.doc � <br /> 4 <br /> I <br />