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wHydrocarbon odor was present at the base of the aquifer at 65 feet and in the underlying aquitard at <br /> 70 and 75 feet (see boring log in Appendix A), but the single aquitard sample from 70 feet was <br /> below the laboratory detection limit of i mg/kg(Appendix B) We interpret the slight diesel odor as <br /> indicating that diesel fuel did not leach through the 151 Riverbank aquifer directly into the <br /> underlying aquitard, but when the water table dropped below 70 feet in the early 1990's, diesel may <br /> have been carried downward in the dissolved phase into the aquitard <br /> Two samples of the aquifer were collected from GT-8 in 1996, and the results were similar to those <br /> from GT-15 in 2004 The sample at 60 feet was below the diesel detection limit, but the sample at <br /> 65 feet had a concentration of 3620 mg/kg (Figure 4) In the 1996 Problem Assessment Report we <br /> concluded that this concentration indicated that diesel had leached to the base of the aquifer, at least <br /> locally The new data from GT-15 support that conclusion In retrospect, if GT-8 had been drilled �cs � <br /> into the underlying aquitard, it would probably have demonstrated that the underlying aquitard was 7 <br /> not impacted above the detection limit for soil , <br /> The same may be true for GT-4 and GT-10, neither of which reached the 151 Riverbank aquifer or <br /> the underlying aquitard The borings nearest to GT-15 that sampled the aquitard and/or the aquifer <br /> are TB-2 (drilled in 199 1) and GT-I I (drilled in 1999) (Figure 2) Hydrocarbon odors were not <br /> reported in TB-2, but concentrations of 24 and 25 mg/kg were detected in the lower portion of the <br /> aquifer between 65 and 70 feet (Table 1) These concentrations could represent the base of the <br /> leached diesel plume (in the unsaturated zone) or the top of the dissolved-phase plume (the depth to <br /> groundwater at the time was 74 feet) Moderate hydrocarbon odor was detected several years later <br /> in the aquifer samples from GT-11, but no samples were analyzed However, a concentration of 740 <br /> mg/kg was detected in the underlying agwtard at 71 feet (Figure 4) This concentration is probably <br /> above what would be expected as the result of downward movement of the water table, and <br /> therefore likely represents leaching within the unsaturated zone when the water table was below 70 <br /> feet Boring GT-11 was drilled through the UST cavity, which implies that diesel leached 5-10 feet <br /> deeper there than it did farther away at GT-15 <br /> One additional boring merits consideration Soil samples cannot be collected in CPT borings, but a <br /> groundwater sample was collected from the aquifer and analyzed in 2003 from boring CPT-1 <br /> (located between GT-1 I and GT-15) The laboratory reported a concentration of 670,000 000 Pg/1 <br /> (parts per billion—this is equivalent to 670 parts per million in soil) If correct, this result would <br /> imply that 15-20% of the diesel detected in the aquifer or 90% of that detected in the aquitard in <br /> GT-I i and GT-8 has dissolved in groundwater since 1999 in order to reach such an elevated <br /> concentration Due to diesel's low solubility, we view this as rather unlikely and therefore treat the <br /> groundwater result from CPT-1 with great skepticism (as discussed in the Fourth Quarter 2003 <br /> Report) The map illustrating diesel concentrations in groundwater disregards that result and utilizes <br /> only the newest data from GT-5, GT-6, and GT-9 (Figure 13) The map implies that the plume is <br /> centered east of the UST cavity in this aquifer This is consistent with earlier data from GT-10, <br /> where very high concentrations were detected in both the soil and groundwater at the top of this <br /> aquifer <br /> 10 <br />