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r <br /> • benzene, toluene, eth Ibenzene, and xylenes (BTEX) EPA Method 8020 The samples were <br /> also analyzed for methyl t-butyl ether (MTBE) by EPA Method 8020 The analytical results for <br /> the samples are presented in boldface type in Table 1, along with previous data The laboratory <br /> analytical report and chain-of-custody documentation are included in Appendix B <br /> Detectable concentrations of TPH-g in the groundwater samples ranged from 63 µg/L (MW 10) to <br /> 270,000µg/L (V2) The concentration of TPH-g in the groundwater sample collected from <br /> MW8, located upgradient of the site and adjacent to the Shell service station, was 35,000,ug/L <br /> Detectable benzene concentrations ranged from 2 1 kig/L (MW 10) to 12,000µg/L (UVB-MW2) <br /> MTBE was detected in groundwater samples at concentrations ranging from 11 µglL(P2) to <br /> 1,300µg/L (UVB-MW2) Groundwater sample analytical results are shown in Figure 1 <br /> 3. GROUNDWATER TREATMENT SYSTEM <br /> A vacuum vaporizer well system, known as UVB (Unterdruck Verdampfer Brunnen) has been <br /> operating at the site since 6 February 1997 A description of the UVB system is included in an <br /> installation report issued in June 1997 The UVB system was not in operation from 9 July 1997 <br /> to 11 September 1997 due to a quarterly maintenance of the air stripper components for the well <br /> The vapor extraction system (VES) was operated while the UVB system was shut down The <br /> VES and UVB cannot be run concurrently <br /> Since the start-up of the UVB system, approximately 342 pounds of TPH-g have been stripped <br /> from the groundwater Table 2 provides a summary of field data and laboratory analytical results <br /> for the UVB system A graphic representation of the UVB system performance to date is shown <br /> in Figure 3 <br /> Twice since the start-up of the UVB system, on 28 February 1997 and on 8 May 1997, the <br /> influent (UVB-MWI) and effluent (UVB-MW2) monitoring wells were sampled for TPH-g, <br /> BTEX, and MTBE analysis, along with the other wells on the site, to determine the stripping <br /> efficiency of the UVB system On 8 May 1997, the stripping efficiency for TPH-g was 99 9 <br /> percent, for BTEX the stripping efficiency was 100 percent As can be seen in Table 1, effluent <br /> (UVB-MW2) samples typically have TPH-g and BTEX concentrations at least one order of <br /> magnitude lower than the corresponding concentrations in influent (UVB-MW 1) samples The <br /> analytical results for influent (UVB-MW 1) and effluent (UVB-MW2) samples collected on 26 <br /> August 1997 are surprising, because they indicate that TPH-g and BTEX concentrations in the <br /> effluent are higher than in the influent It is possible that the current results for UVB-MW 1 and <br /> UVB-MW2 are a result of sample mislabeling The UVB system was not in operation when the <br /> samples were collected In order to verify the analytical results in question for UVB-MW I and <br /> UVB-MW2, grab samples were collected from the two wells on 2 October 1997 and submitted <br /> for TPH-g, BTEX, and MTBE analysis by EPA Methods 8015/8020 The grab sample analytical <br /> results indicate that influent and effluent concentrations were 17,000µg/L and below the <br /> reporting limit (50,ug/L) for TPH-g, correspondingly The Iaboratory analytical report and chain- <br /> of-custody documentation for the grab samples are presented in Appendix B <br /> WP61 73942 Q597 TX 4 2 <br />