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7.1 NATURAL ATTENUATION <br />' The natural attenuation remedial option is not a technology, rather it refers to naturally occurring <br /> subsurface processes, such as dilution, volatilization, biodegradation, adsorption, and chemical <br />' reactions with subsurface materials, which result in reductions in contaminant concentrations <br /> Selection of natural attenuation as a remedial option would require groundwater modeling and an <br /> evaluation of contaminant degradation rates, verified by long-terra sampling and analysis <br /> Natural attenuation is not considered an effective remedial option at former Exxon RS 7-3942, <br /> because volatilization and biodegradation processes are inhibited under the submerged source <br /> conditions at the site <br />' 7.2 VERTICAL BARRIER(CONTAINMENT <br />' The vertical bamer/containment remedial option consists of a trench filled with a slurry grout <br /> material The slurry, usually a mixture of bentonite and water, hydraulically shores the trench to <br /> prevent collapse and forms a filter cake to reduce groundwater flow There is a potential for <br /> slurry wall degradation over time The vertical barrier containment remedial option does not <br /> pass the screening, because it will not result in reduction or removal of the submerged <br /> hydrocarbon source at former Exxon RS 7-3942 The depth of petroleum hydrocarbons in the <br />' saturated zone extends to a depth beyond 30 feet bgs, therefore, constructing a 30 foot slurry <br /> barrier would require a high capital cost <br /> 7.3 AIR SPARGING <br /> Air sparging consists of infecting air at high flow rates into the saturated zone, creating an <br />' underground stripper which removes contaminants in groundwater and soil through <br /> volatilization Air sparging has been operating in tandem with soil vapor extraction at former <br /> Exxon RS 7-3942 and did not result in any discernible reductions in groundwater hydrocarbon <br />' concentrations The air sparging remedial option does not pass the screening because the rate of <br /> volatilization of dissolved contaminants from groundwater is lower than the rate of dissolution <br />' into groundwater from the submerged source at the site <br /> 7.4 PUMP AND TREAT <br /> tPump and treat as a remedial option consists of groundwater extraction and treatment by means <br /> of a number of technologies, including air stripping and carbon adsorption The pump and treat <br />' remedial option does not pass screening at former Exxon RS 7-3942, because it wiII require the <br /> discharge or infection of treated water, it will likely result in pulling hydrocarbons from offsite <br /> upgradient sources into the site, it has been shown in recent years to be ineffective for source <br /> reduction or removal, and it has high capital and O&M costs <br /> 7.5 PASSIVE TREATMENT ZONE <br /> The passive treatment zone remedial option entails the installation of a permeable zone across the <br /> flow path of the contaminant plume, allowing the plume to passively move through the zone <br /> The passive treatment zone would consist of closely packed Geoprobe borings grouted with <br />' WP61 73942 WPI 096 TX 5 13 <br />